Exam 11: Solutions: Properties and Behavior

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The normal temperature range of the liquid phase of pure water is 0C to 100C. Which of the following solutions will have the largest temperature range for the liquid state?

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Which of the following will require the greatest energy input to separate the ions?

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A colligative property does not depend on ________

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The vapor pressure of an aqueous solution is found to be 24.9 mm Hg at 25C. What is the mole fraction of solute in this solution? The vapor pressure of water is 25.756 mm Hg at 25C.

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Which has the higher vapor pressure at a given temperature, pure water or salty seawater? Explain.

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Determine the energy change for the reaction Determine the energy change for the reaction   from the following data: Lattice energy of LiCl <font face=symbol></font> <font face=symbol></font>861 kJ/mol Energy to vaporize Li <font face=symbol></font> 159 kJ/mol Ionization energy of Li <font face=symbol></font> 520 kJ/mol Cl<sub>2</sub> bond energy: 240 kJ/mol Electron affinity of Cl: <font face=symbol></font>349 kJ/mol from the following data: Lattice energy of LiCl 861 kJ/mol Energy to vaporize Li 159 kJ/mol Ionization energy of Li 520 kJ/mol Cl2 bond energy: 240 kJ/mol Electron affinity of Cl: 349 kJ/mol

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Write out the steps of the Born-Haber cycle for formation of solid magnesium iodide from its elements. Label what energy each step corresponds to. Also, describe how you would calculate the lattice energy for the compound using the diagram.

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Which graph best describes how the vapor pressure of a solution varies according to Raoult's law as a nonvolatile solute is added to a liquid? The vapor pressure of the solution is plotted on the y-axis, and the mole fraction of solvent is plotted on the x-axis. The origin (0, 0) is not necessarily located where the axes cross. Which graph best describes how the vapor pressure of a solution varies according to Raoult's law as a nonvolatile solute is added to a liquid? The vapor pressure of the solution is plotted on the y-axis, and the mole fraction of solvent is plotted on the x-axis. The origin (0, 0) is not necessarily located where the axes cross.

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Which of the following will have the smallest lattice energy?

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Calculate the molality of a solution containing 0.355 mol sodium hydrogen carbonate (baking soda) and 245 g of water.

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Which of the following would be most effective in melting ice on a sidewalk?

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A 15.0 mg sample of a protein was dissolved in water to produce 5.00 mL of solution at 25.1C. The osmotic pressure of this solution was measured and found to be 6.50 torr. What is the molar mass of this protein?

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The interaction energy of LiF is 1.14 1018 J. What is the distance between the Li and F ions?

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Given the same number of moles of each of the following substances, which one would be most effective in melting ice on a sidewalk?

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Which graph best describes how the vapor pressure of a solution varies according to Raoult's law as a nonvolatile solute is added to a liquid? The vapor pressure of the solution is plotted on the y-axis, and the mole fraction of solute is plotted on the x-axis. The origin (0, 0) is not necessarily located where the axes cross. Which graph best describes how the vapor pressure of a solution varies according to Raoult's law as a nonvolatile solute is added to a liquid? The vapor pressure of the solution is plotted on the y-axis, and the mole fraction of solute is plotted on the x-axis. The origin (0, 0) is not necessarily located where the axes cross.

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Indicate which aqueous solution has the highest vapor pressure.

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Caryophyllene, a nonelectrolyte, is one of the compounds responsible for the flavor of cloves. A 207 mg sample of caryophyllene was dissolved in 1.00 g of chloroform (Kb 3.63C/m), increasing the boiling point of chloroform by 3.68C. What is the molar mass of caryophyllene?

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Calculate the minimum pressure that must be applied to achieve reverse osmosis of 0.504 M NaCl at 22C.

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Calculate the molality of a solution containing 0.755 mol glucose and 1.75 kg of water.

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Which of the following requires the smallest energy to separate the ions?

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