Exam 15: Chemical Equilibrium
Exam 1: Introduction: Matter and Measurement118 Questions
Exam 2: Atoms, Molecules, and Ions201 Questions
Exam 3: Stoichiometry: Calculations With Chemical Formulas and Equations134 Questions
Exam 4: Aqueous Reactions and Solution Stoichiometry147 Questions
Exam 6: Electronic Structure of Atoms161 Questions
Exam 7: Periodic Properties of the Elements149 Questions
Exam 8: Basic Concepts of Chemical Bonding116 Questions
Exam 10: Gases146 Questions
Exam 11: Intermolecular Forces, Liquids, and Solids103 Questions
Exam 12: Modern Materials47 Questions
Exam 13: Properties of Solutions121 Questions
Exam 14: Chemical Kinetics110 Questions
Exam 15: Chemical Equilibrium58 Questions
Exam 16: Acid-Base Equilibria97 Questions
Exam 17: Additional Aspects of Equilibria88 Questions
Exam 18: Chemistry of the Environment105 Questions
Exam 19: Chemical Thermodynamics101 Questions
Exam 20: Electrochemistry90 Questions
Exam 21: Nuclear Chemistry128 Questions
Exam 22: Chemistry of the Nonmetals176 Questions
Exam 23: Metals and Metallurgy112 Questions
Exam 24: Chemistry of Coordination Compounds124 Questions
Exam 25: The Chemistry of Life: Organic and Biological Chemistry115 Questions
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The Kp for the reaction below is 1.49 × 108 at 100 °C: CO (g) + Cl2 (g) -COCl2 (g)
In an equilibrium mixture of the three gases, PCO = PCl2 = 8.60 × 10- 4 atm. The partial pressure of the product, phosgene (COCl2), is atm.
Free
(Multiple Choice)
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Correct Answer:
C
At 200 °C, the equilibrium constant (Kp) for the reaction below is 2.40 × 103.
2NO (g)
N2 (g) + O2 (g)
A closed vessel is charged with 36.1 atm of NO. At equilibrium, the partial pressure of O2 is
Atm)

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(Multiple Choice)
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Correct Answer:
C
In an exothermic equilibrium reaction, increasing the reaction temperature favors the formation of reactants.
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Correct Answer:
True
The number obtained by substituting starting reactant and product concentrations into an equilibrium- constant expression is known as the .
(Short Answer)
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In the coal- gasification process, carbon monoxide is converted to carbon dioxide via the following reaction:
CO (g) + H2O (g)
CO2 (g) + H2 (g)
In an experiment, 0.35 mol of CO and 0.40 mol of H2O were placed in a 1.00- L reaction vessel. At equilibrium, there were 0.19 mol of CO remaining. Keq at the temperature of the experiment is
)

(Multiple Choice)
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The equilibrium constant for the gas phase reaction N2 (g) + 3H2 (g)
2NH3 (g)
Is Keq = 4.34 × 10- 3 at 300 °C. At equilibrium, _ _.

(Multiple Choice)
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A sealed 1.0 L flask is charged with 0.500 mol of I2 and 0.500 mol of Br2. An equilibrium reaction ensues:
I2 (g) + Br2 (g)
2IBr (g)
When the container contents achieve equilibrium, the flask contains 0.84 mol of IBr. The value of Keq is _ .

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A reaction vessel is charged with hydrogen iodide, which partially decomposes to molecular hydrogen and iodine:
2HI (g)
H2(g) + I2(g)
When the system comes to equilibrium at 425 °C, PHI = 0.708 atm, and PH2 = PI2
= 0)0960 atm. The value of Kp at this temperature is .

(Multiple Choice)
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At elevated temperatures, molecular hydrogen and molecular bromine react to partially form hydrogen bromide:
H2 (g) + Br2 (g)
2HBr (g)
A mixture of 0.682 mol of H2 and 0.440 mol of Br2 is combined in a reaction vessel with a volume of 2.00 L. At equilibrium at 700 K, there are 0.566 mol of H2 present. At equilibrium, there are
Mol of Br2 present in the reaction vessel.

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The value of Keq for the equilibrium
H2 (g) + I2 (g)
2 HI (g)
Is 794 at 25 °C. At this temperature, what is the value of Keq for the equilibrium below?
HI (g) 1/2 H2 (g) + 1/2 I2 (g)



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The equilibrium- constant expression depends on the of the reaction.
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Exactly 3.5 moles if N2O4 is placed in an empty 2.0- L container and allowed to reach equilibrium described by the equation
N2O4 (g) "2NO2 (g)
If at equilibrium the N2O4 is 25% dissociated, what is the value of the equilibrium constant for the reaction?
(Short Answer)
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For the endothermic reaction
CaCO3 (s)
CaO (s) + CO2 (g)
Le Cha^telier's principle predicts that _ will result in an increase in the number of moles of CO2.

(Multiple Choice)
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Consider the following reaction at equilibrium:
2NH3 (g)
N2 (g) + 3H2 (g) OH° = +92.4 kJ
Le Cha^telier's principle predicts that adding N2 (g) to the system at equilibrium will result in

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The Keq for the equilibrium below is 7.52 × 10- 2 at 480 °C.



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The Keq for the equilibrium below is 0.112 at 700 °C. SO2 (g) + 1 O2


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At constant temperature, reducing the volume of a gaseous equilibrium mixture causes the reaction to shift in the direction that increases the number of moles of gas in the system.
(True/False)
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Le Chatelier's principle states that if a system at equilibrium is disturbed, the equilibrium will shift to minimize the disturbance.
(True/False)
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In which of the following reactions would increasing pressure at constant temperature not change the concentrations of reactants and products, based on Le Cha^telier's principle?
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