Exam 17: Additional Aspects of Equilibria

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A 25.0 mL sample of an HCl solution is titrated with a 0.139 M NaOH solution. The equivalence point is reached with 15.4 mL of base. The concentration of HCl is M.

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B

Calculate the pH of a solution prepared by dissolving 0.750 mol of NH3 and 0.250 mol of NH4Cl in water sufficient to yield 1.00 L of solution. The Kb of ammonia is 1.77 × 10- 4.

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C

Which below best describe(s) the behavior of an amphoteric hydroxide in water?

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D

A 50.0 mL sample of an aqueous H2SO4 solution is titrated with a 0.375 M NaOH solution. The equivalence point is reached with 62.5 mL of the base. The concentration of H2SO4 is _ _ M.

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In which of the following aqueous solutions would you expect AgBr to have the highest solubility?

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For any buffer system, the buffer capacity depends on the amount of acid and base from which the buffer is made.

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A solution of NaF is added dropwise to a solution that is 0.0144 M in Ba2+. When the concentration of F- exceeds M, BaF2 will precipitate. Neglect volume changes. For BaF2, Ksp = 1.7 × 10- 6.

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Human blood is .

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Calculate the pH of a solution prepared by dissolving 0.150 mol of benzoic acid (HBz) and 0)300 mol of sodium benzoate in water sufficient to yield 1.00 L of solution. The Ka of benzoic acid is 6.50 × 10- 5.

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Calculate the pH of a buffer that contains 0.270 M hydrofluoric acid (HF) and 0.180 M cesium fluoride (CsF). The Ka of hydrofluoric acid is 6.80 × 10- 4.

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Which one of the following pairs cannot be mixed together to form a buffer solution?

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A 25.0 mL sample of 0.150 M nitrous acid is titrated with a 0.150 M NaOH solution. What is the pH at the equivalence point? The Ka of nitrous acid is 4.50 × 10- 4.

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Of the following solutions, which has the greatest buffering capacity?

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A 25.0- mL sample of 0.150 M butanoic acid is titrated with a 0.150 M NaOH solution. What is the pH before any base is added? The Ka of butanoic acid is 1.5 × 10- 5.

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The pH of a solution prepared by mixing 45 mL of 0.183 M KOH and 65 mL of 0.145 M HCl is )

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A 25.0 mL sample of a solution of a monoprotic acid is titrated with a 0.115 M NaOH solution. The titration curve above was obtained. The concentration of the monoprotic acid is about mol/L.

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In which of the following aqueous solutions would you expect AgBr to have the lowest solubility?

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The molar solubility of _ is not affected by the pH of the solution.

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Which of the following could be added to a solution of potassium fluoride to prepare a buffer?

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Which of the following could be added to a solution of acetic acid to prepare a buffer? sodium acetate sodium hydroxide nitric acid hydrofluoric acid

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