Exam 12: Intermolecular Attractions and the Properties of Liquids and Solids

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An unknown solid is hard and brittle with a high melting point. It does not conduct electricity as a solid, but does as a liquid. What kind of crystal best describes this solid?

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Dioxane, C4H8O2, has an enthalpy of fusion of 145.8 J g-1 and its melting point temperature is 11.0°C. How much heat is required to transform 142 g of solid dioxane, into liquid dioxane, at 11.0°C?

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A unit cell of sodium chloride (face-centered cubic)consists of sodium and chloride ions. How many chloride ions are within this unit cell?

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Which compound is expected to exhibit hydrogen bonding?

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Which compound should have the highest boiling point?

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Why would the coffee purchased in a to-go cup with a lid at the fast food takeout shop remain hot much longer than the coffee you pour into your ceramic cup at home?

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The normal boiling point of 2,3,4-trimethypentane, C8H18, is 113.47°C, and its heat of vaporization is 37,600 J mol-1. What is its vapor pressure at 105.5°C?

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Arrange the following compounds in order of increasing viscosity: methylene chloride (CH2Cl2); glycerin (C3H5(OH)3); 1,1-ethandiol (C2H4(OH)2); and acetone (C3H6O). Explain your reasoning.

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A new compound, boganium sulfide, has been discovered. X-ray crystallographic studies reveal that it has a cubic unit cell with a sulfide ion at each of the corner lattice points, a sulfide ion at the geometric center of the unit cell, and a boganium ion in the center of each of the cube faces in the unit cell. Based on this structure, the formula for the compound should be

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A solid chemical substance whose triple point pressure is 4.60 atmospheres will normally ________ when it is heated to a sufficiently high temperature in the open laboratory.

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The temperature above which only a solid state and a non-solid exists for a substance is called the ________.

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A technique used for determining the structure of a crystalline substance is

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Describe the essential features of a hydrogen bond.

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Which of the following would be expected to have the lowest vapor pressure at room temperature?

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How many atoms are contained in one unit cell of metallic lanthanum, if it forms a body-centered cubic unit cell?

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A unit cell of sodium chloride (face-centered cubic)consists of sodium and chloride ions. How many sodium ions are within this unit cell?

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Which set of properties below best describes molecular crystalline substances?

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The following questions refer to the phase diagram below. Gas, liquid, and solid phases are all present, but not labeled. The following questions refer to the phase diagram below. Gas, liquid, and solid phases are all present, but not labeled.   -Starting at the temperature and pressure of b, if the temperature is increased at constant pressure, ultimately -Starting at the temperature and pressure of b, if the temperature is increased at constant pressure, ultimately

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The property that measures or describes the magnitude of resistance to flow in a liquid is called

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The following questions refer to the diagram below. The following questions refer to the diagram below.   -At what temperatures do the triple point and critical point occur? -At what temperatures do the triple point and critical point occur?

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