Exam 15: Applications of Aqueous Equilibria
Exam 1: Chemistry: Matter and Measurement219 Questions
Exam 2: Atoms, molecules, and Ions257 Questions
Exam 3: Formulas, equations, and Moles208 Questions
Exam 4: Reactions in Aqueous Solutions174 Questions
Exam 5: Periodicity and the Atomic Structure of Atoms158 Questions
Exam 6: Ionic Bonds and Some Main-Group Chemistry173 Questions
Exam 7: Covalent Bonds and Molecular Structure232 Questions
Exam 8: Thermochemistry: Chemical Energy163 Questions
Exam 9: Gases: Their Properties and Behavior182 Questions
Exam 10: Liquids,solids,and Phase Changes186 Questions
Exam 11: Solutions and Their Properties192 Questions
Exam 12: Chemical Kinetics206 Questions
Exam 13: Chemical Equilibrium166 Questions
Exam 14: Aqueous Equilibria: Acids and Bases224 Questions
Exam 15: Applications of Aqueous Equilibria190 Questions
Exam 16: Thermodynamics: Entropy, free Energy, and Equilibrium144 Questions
Exam 17: Electrochemistry176 Questions
Exam 18: Hydrogen, oxygen, and Water175 Questions
Exam 19: The Main-Group Elements202 Questions
Exam 20: Transition Elements and Coordination Chemistry185 Questions
Exam 21: Metals and Solid-State Materials149 Questions
Exam 22: Nuclear Chemistry85 Questions
Exam 23: Organic and Biological Chemistry285 Questions
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What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous formic acid requires 29.80 mL of 0.3567 M NaOH? Ka =1.8 × 10-4
For formic acid.

(Multiple Choice)
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The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H2A with NaOH.
-Which point a-d represents the HX-/X2- buffer region?

(Multiple Choice)
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The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H2A with NaOH.
-Which point a-d represents the first equivalence point?

(Multiple Choice)
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What is the approximate value of the equilibrium constant,Kn,for the neutralization of pyridine with hydrochloric acid,shown in the equation below? The Kb for pyridine is 1.8 × 10-9.
HCl(aq)+ C5H5N(aq)⇌ C5H5NHCl(aq)
(Multiple Choice)
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The following pictures represent solutions of CuS,which may also contain ions other than Cu2+ and S2- which are not shown.Gray spheres represent Cu2+ ions and dotted spheres represent S2- ions.
-If solution (1)is a saturated solution of CuS,which of solutions (2)-(4)are supersaturated?

(Multiple Choice)
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What is the Ka of the amino acid glutamine if it is 33.0% dissociated at pH = 8.82?
(Short Answer)
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The following pictures represent solutions at various stages in the titration of a weak diprotic acid H2A with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A2- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity).
-Which picture represents the system with the highest pH?

(Multiple Choice)
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What is the molar solubility of AgCl in 0.20 M NH3? Ksp for AgCl is 1.8 × 10-10 and Kf for Ag(NH3)2+ is 1.7 × 107.
(Multiple Choice)
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The following pictures represent solutions at various points in the titration of a weak acid HA with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity).
-Which picture represents the solution before the equivalence point?

(Multiple Choice)
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What is the pH at the equivalence point of a weak acid-strong base titration?
(Multiple Choice)
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What is the molar solubility of Mg(OH)2 in a basic solution with a pH of 12.50? Ksp for Mg(OH)2 is 5.61 × 10-12.
(Multiple Choice)
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What is the hydronium ion concentration in a solution prepared by mixing 50.00 mL of 0.10 M HCN with 50.00 mL of 0.030 M NaCN? Assume that the volumes of the solutions are additive and that
Ka = 4.9 × 10-10 for HCN.
(Multiple Choice)
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The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. )
-Which solution has the largest percent dissociation of HA?

(Multiple Choice)
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Which of the following titrations result in a basic solution at the equivalence point?
(Multiple Choice)
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The neutralization constant Kn for the neutralization of penicillin V (C16H18N2O5S)and erythromycin (C37H67NO13)is 1.3 × 106.The acid dissociation constant Ka for penicillin V is
2.0 × 10-3.What is the base dissociation constant Kb for erythromycin?
(Short Answer)
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What volume of 5.00 × 10-3 M HNO3 is needed to titrate 80.00 mL of 5.00 × 10-3 M Ca(OH)2 to the equivalence point?
(Multiple Choice)
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The following pictures represent solutions that contain a weak acid HA (pKa = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity. )
-Which picture represents the equilibrium state of the solution after addition of one H3O+ ion to the solution shown in picture (1)?

(Multiple Choice)
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At what pH is the amino acid glycine with a Ka of 2.51 × 10-10 sixty-six (66%)percent dissociated?
(Multiple Choice)
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