Exam 15: Applications of Aqueous Equilibria

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What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous formic acid requires 29.80 mL of 0.3567 M NaOH? Ka =1.8 × 10-4 What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous formic acid requires 29.80 mL of 0.3567 M NaOH? K<sub>a</sub> =1.8 × 10<sup>-4</sup>   For formic acid. For formic acid.

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The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H2A with NaOH. The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H<sub>2</sub>A with NaOH.   -Which point a-d represents the HX<sup>-</sup>/X2<sup>-</sup> buffer region? -Which point a-d represents the HX-/X2- buffer region?

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The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H2A with NaOH. The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H<sub>2</sub>A with NaOH.   -Which point a-d represents the first equivalence point? -Which point a-d represents the first equivalence point?

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Which of the following metal hydroxides are amphoteric?

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What is the approximate value of the equilibrium constant,Kn,for the neutralization of pyridine with hydrochloric acid,shown in the equation below? The Kb for pyridine is 1.8 × 10-9. HCl(aq)+ C5H5N(aq)⇌ C5H5NHCl(aq)

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The following pictures represent solutions of CuS,which may also contain ions other than Cu2+ and S2- which are not shown.Gray spheres represent Cu2+ ions and dotted spheres represent S2- ions. The following pictures represent solutions of CuS,which may also contain ions other than Cu<sup>2+</sup> and S<sup>2-</sup> which are not shown.Gray spheres represent Cu<sup>2+</sup> ions and dotted spheres represent S<sup>2-</sup> ions.   -If solution (1)is a saturated solution of CuS,which of solutions (2)-(4)are supersaturated? -If solution (1)is a saturated solution of CuS,which of solutions (2)-(4)are supersaturated?

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What is the Ka of the amino acid glutamine if it is 33.0% dissociated at pH = 8.82?

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The following pictures represent solutions at various stages in the titration of a weak diprotic acid H2A with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A2- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity). The following pictures represent solutions at various stages in the titration of a weak diprotic acid H<sub>2</sub>A with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A<sup>2-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup> initially present,OH<sup>-</sup> initially present and solvent water molecules have been omitted for clarity).   -Which picture represents the system with the highest pH? -Which picture represents the system with the highest pH?

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What is the molar solubility of AgCl in 0.20 M NH3? Ksp for AgCl is 1.8 × 10-10 and Kf for Ag(NH3)2+ is 1.7 × 107.

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The following pictures represent solutions at various points in the titration of a weak acid HA with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity). The following pictures represent solutions at various points in the titration of a weak acid HA with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup> initially present,OH<sup>-</sup> initially present and solvent water molecules have been omitted for clarity).   -Which picture represents the solution before the equivalence point? -Which picture represents the solution before the equivalence point?

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What is the pH at the equivalence point of a weak acid-strong base titration?

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What is the most soluble salt of the following set?

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What is the molar solubility of Mg(OH)2 in a basic solution with a pH of 12.50? Ksp for Mg(OH)2 is 5.61 × 10-12.

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What is the hydronium ion concentration in a solution prepared by mixing 50.00 mL of 0.10 M HCN with 50.00 mL of 0.030 M NaCN? Assume that the volumes of the solutions are additive and that Ka = 4.9 × 10-10 for HCN.

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The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup>,OH<sup>-</sup>,and solvent H<sub>2</sub>O molecules have been omitted for clarity. )   -Which solution has the largest percent dissociation of HA? -Which solution has the largest percent dissociation of HA?

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Which of the following titrations result in a basic solution at the equivalence point?

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The neutralization constant Kn for the neutralization of penicillin V (C16H18N2O5S)and erythromycin (C37H67NO13)is 1.3 × 106.The acid dissociation constant Ka for penicillin V is 2.0 × 10-3.What is the base dissociation constant Kb for erythromycin?

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What volume of 5.00 × 10-3 M HNO3 is needed to titrate 80.00 mL of 5.00 × 10-3 M Ca(OH)2 to the equivalence point?

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The following pictures represent solutions that contain a weak acid HA (pKa = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA (pK<sub>a</sub> = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+ </sup>initially present,OH<sup>- </sup>initially present and solvent water molecules have been omitted for clarity. )   -Which picture represents the equilibrium state of the solution after addition of one H<sub>3</sub>O<sup>+</sup> ion to the solution shown in picture (1)? -Which picture represents the equilibrium state of the solution after addition of one H3O+ ion to the solution shown in picture (1)?

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At what pH is the amino acid glycine with a Ka of 2.51 × 10-10 sixty-six (66%)percent dissociated?

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