Exam 15: Applications of Aqueous Equilibria

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The following pictures represent solutions of CuS,which may also contain ions other than Cu2+ and S2- which are not shown.Gray spheres represent Cu2+ ions and dotted spheres represent S2- ions. The following pictures represent solutions of CuS,which may also contain ions other than Cu<sup>2+</sup> and S<sup>2-</sup> which are not shown.Gray spheres represent Cu<sup>2+</sup> ions and dotted spheres represent S<sup>2-</sup> ions.   -If solution (1)is a saturated solution of CuS,which of solutions (2)-(4)are saturated? -If solution (1)is a saturated solution of CuS,which of solutions (2)-(4)are saturated?

(Multiple Choice)
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The following pictures represent solutions that contain a weak acid HA (pKa = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA (pK<sub>a</sub> = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+ </sup>initially present,OH<sup>- </sup>initially present and solvent water molecules have been omitted for clarity. )   -Which picture represents the equilibrium state of the solution after addition of one OH<sup>-</sup> ion to the solution shown in picture (1)? -Which picture represents the equilibrium state of the solution after addition of one OH- ion to the solution shown in picture (1)?

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The pH of a solution of HIO3 (Ka = 1.7 × 10-1)and KIO3 is 1.00.What is the molarity of KIO3 if the molarity of HIO3 is 0.025 M?

(Short Answer)
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The equivalence point pH of the titration of four weak bases is given.Which is the strongest base?

(Multiple Choice)
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The following pictures represent solutions at various stages in the titration of a weak diprotic acid H2A with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A2- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity). The following pictures represent solutions at various stages in the titration of a weak diprotic acid H<sub>2</sub>A with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A<sup>2-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup> initially present,OH<sup>-</sup> initially present and solvent water molecules have been omitted for clarity).   -Which picture represents the system with the lowest pH? -Which picture represents the system with the lowest pH?

(Multiple Choice)
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Which is a net ionic equation for the neutralization of a strong acid with a strong base?

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Formic acid (HCO2H,Ka = 1.8 × 10-4)is the principal component in the venom of stinging ants.What is the molarity of a formic acid solution if 25.00 mL of the formic acid solution requires 29.80 mL of 0.0567 M NaOH to reach the equivalence point?

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What is the pH of a solution made by mixing 30.00 mL of 0.10 M acetic acid with 50.00 mL of 0.100 M KOH? Assume that the volumes of the solutions are additive.Ka = 1.8 × 10-5 for CH3CO2H.

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0.10 M potassium chromate is slowly added to a solution containing 0.20 M AgNO3 and 0.20 M Ba(NO3)2.What is the Ag+ concentration when BaCrO4 just starts to precipitate? Ksp for Ag2CrO4 and BaCrO4 are 1.1 × 10-12 and 1.2 × 10-10,respectively.

(Multiple Choice)
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Addition of 0.0125 mol KOH to 150 mL of a 0.150 M formic acid/0.100 M sodium formate buffer results in a pH = ________? The Ka of formic acid is 1.8 × 10-4.

(Short Answer)
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The following pictures represent solutions at various points in the titration of a weak acid HA with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity). The following pictures represent solutions at various points in the titration of a weak acid HA with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup> initially present,OH<sup>-</sup> initially present and solvent water molecules have been omitted for clarity).   -Which picture represents the solution after the equivalence point? -Which picture represents the solution after the equivalence point?

(Multiple Choice)
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What is the molar solubility of lead(II)chromate in 0.10 M HNO3 if the Ksp for PbCrO4 is 2)8 × 10-13? and the Ka2 for H2CrO4 is 3.0 × 10-7? Note that H2CrO4 is considered to be a strong acid.

(Multiple Choice)
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What is the pH of a solution made by mixing 25.00 mL of 0.100 M HCl with 40.00 mL of 0.100 M KOH? Assume that the volumes of the solutions are additive.

(Multiple Choice)
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The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup>,OH<sup>-</sup>,and solvent H<sub>2</sub>O molecules have been omitted for clarity. )   -Which solution has the lowest pH? -Which solution has the lowest pH?

(Multiple Choice)
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What is the pH of a solution made by mixing 30.00 mL of 0.10 M HCl with 40.00 mL of 0.10 M KOH? Assume that the volumes of the solutions are additive.

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What is the molar solubility of AgCl in 0.10 M NH3? Ksp for AgCl is 1.8 × 10-10 and the Kf for Ag(NH3)2+ is 1.7 × 107.

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What is the pH of a solution prepared by mixing 50.00 mL of 0.10 M NH3 with 25.00 mL of 0.10 M NH4Cl? Assume that the volume of the solutions are additive and that Kb = 1.8 × 10-5 for NH3.

(Multiple Choice)
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The following plot shows two titration curves,each representing the titration of 50.00 mL of 0.100 M acid with 0.100 M NaOH. The following plot shows two titration curves,each representing the titration of 50.00 mL of 0.100 M acid with 0.100 M NaOH.   -Which point a-d represents the equivalence point for the titration of a weak acid? -Which point a-d represents the equivalence point for the titration of a weak acid?

(Multiple Choice)
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The pH of a solution of ethylamine,C2H5NH2 (Kb = 6.4 × 10-4)and ethylammium bromide,C2H5NH3Br is 11.00.What is the molarity of C2H5NH3Br if the molarity of C2H5NH2 is 0.025 M?

(Short Answer)
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The following pictures represent solutions of CaCO3,which may also contain ions other than Ca2+ and CO32- which are not shown.Gray spheres represent Ca2+ ions and unshaded spheres represent CO32- ions. The following pictures represent solutions of CaCO<sub>3</sub>,which may also contain ions other than Ca<sup>2+</sup> and CO<sub>3</sub><sup>2-</sup> which are not shown.Gray spheres represent Ca<sup>2+</sup> ions and unshaded spheres represent CO<sub>3</sub><sup>2-</sup> ions.   -If solution (1)is a saturated solution of CaCO<sub>3</sub>,which of solutions (1)-(4)represents the solution after a small amount of HNO<sub>3</sub> is added and equilibrium is restored? -If solution (1)is a saturated solution of CaCO3,which of solutions (1)-(4)represents the solution after a small amount of HNO3 is added and equilibrium is restored?

(Multiple Choice)
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