Exam 15: Applications of Aqueous Equilibria

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The dissociation equilibrium constants for the protonated form of alanine (a diprotic amino acid,H2X+)are Ka1 = 4.6 × 10-3 and Ka2 = 2.0 × 10-10.What is the pH of 50.00 mL of a 0.0500 M solution of alanine after 25.00 mL of 0.100 M NaOH has been added?

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What is the resulting pH when 0.005 moles of KOH is added to 0.100 L of a buffer solution that is 0.100 M in H2PO4- and 0.100 M HPO42- and the Ka2 = 6.2 × 10-8?

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What is the approximate value of the equilibrium constant,Kn,for the neutralization of nitrous acid with ammonia,shown in the equation below? The Ka for HNO2 is 4.5 × 10-4 and the Kb for NH3 is 1)8 × 10-5. HNO2(aq)+ NH3(aq)⇌ NH4NO2(aq)

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The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H2A with NaOH. The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H<sub>2</sub>A with NaOH.   -Which point a-d represents the second equivalence point? -Which point a-d represents the second equivalence point?

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The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H2A with NaOH. The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H<sub>2</sub>A with NaOH.   -What is the pH at the first equivalence point? -What is the pH at the first equivalence point?

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What volume of 5.00 × 10-3 M HNO3 is needed to titrate 100.00 mL of 5.00 × 10-3 M Ca(OH)2 to the equivalence point?

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What is the common ion in a solution prepared by mixing 0.10 M NaCH3CO2 with 0.10 M CH3CO2H?

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What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous formic acid requires 29.80 mL of 0.0567 M NaOH? Ka = 1.8 × 10-4 for formic acid.

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What is the pH of a buffer system made by dissolving 10.70 grams of NH4Cl and 20.00 mL of 12.0 M NH3 in enough water to make 1.000 L of solution? Kb = 1.8 × 10-5 for NH3.

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What is the molar solubility of CaF2 in 0.10 M NaF solution at 25°C? The Ksp for CaF2 is What is the molar solubility of CaF<sub>2</sub> in 0.10 M NaF solution at 25°C? The K<sub>sp</sub> for CaF<sub>2</sub> is

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What is the approximate value of the equilibrium constant,Kn,for the neutralization of acetic acid with sodium hydroxide,shown in the equation below? The Ka for acetic acid is 1.8 × 10-5. CH3CO2H(aq)+ NaOH(aq)⇌ H2O(l)+ NaCH3CO2(aq)

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When 50 mL of 0.10 M NH4Cl is added to 50 mL of 0.10 M NH3,relative to the pH of the 0.10 M NH3 solution the pH of the resulting solution will

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What is the equilibrium constant expression for the Ksp of Ca3(PO4)2?

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The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H2A+ with NaOH.Which point a-d represents the isoelectric point? The following plot shows a titration curve for the titration of 1.00 L of 1.00 M diprotic acid H<sub>2</sub>A<sup>+</sup> with NaOH.Which point a-d represents the isoelectric point?

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What is the chromium ion concentration for a saturated solution of Cr(OH)3 if the Ksp for Cr(OH)3 is 6.7 × 10-31?

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When equal molar amounts of the following sets of compounds are mixed in water,which will not form a buffer solution?

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What is the [CH3CO2-]/[CH3CO2H] ratio necessary to make a buffer solution with a pH of 4.34? Ka = 1.8 × 10-5 for CH3CO2H.

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Which of the following reactions are not consistent with the concept of acid base amphoterism?

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What is the most soluble salt of the following set?

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Formic acid (HCO2H,Ka = 1.8 × 10-4)is the principal component in the venom of stinging ants.What is the molarity of a formic acid solution if 25.00 mL of the formic acid solution requires 29.80 mL of 0.0567 M NaOH to reach the equivalence point?

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