Exam 15: Applications of Aqueous Equilibria

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What is the magnitude of the change in pH when 0.005 moles of HCl is added to 0.100 L of a buffer solution that is 0.100 M in CH3CO2H and 0.100 M NaCH3CO2? The Ka for acetic acid is1.8 × 10-5.

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The following pictures represent solutions of AgCl,which may also contain ions other than Ag+ and Cl- which are not shown.Gray spheres represent Ag+ ions and dotted spheres represent Cl- ions. The following pictures represent solutions of AgCl,which may also contain ions other than Ag<sup>+</sup> and Cl<sup>-</sup> which are not shown.Gray spheres represent Ag<sup>+</sup> ions and dotted spheres represent Cl<sup>-</sup> ions.   -If solution (1)is a saturated solution of AgCl,which of solutions (1)-(4)represents the solution after a small amount of HNO<sub>3</sub> is added and equilibrium is restored? -If solution (1)is a saturated solution of AgCl,which of solutions (1)-(4)represents the solution after a small amount of HNO3 is added and equilibrium is restored?

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Selenous acid,H2SeO3 has acid dissociation constants Ka1 = 3.5 × 10-2 and Ka2 = 5 × 10-8.When 25.00 mL of 0.100 M selenous acid is titrated with 0.200 M NaOH the first equivalence point occurs at pH = ________.

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The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup>,OH<sup>-</sup>,and solvent H<sub>2</sub>O molecules have been omitted for clarity. )   -Which solution has the greatest buffer capacity? -Which solution has the greatest buffer capacity?

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The half equivalence point in the titration of 0.100 M CH3NH2 (Kb = 3.7 × 10-4)with 0.250 M HCl occurs at pH = ________.

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Precipitation of an ionic compound will occur upon mixing of desired reagents if the initial ion product is ________.

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What is the pH of a buffer system prepared by dissolving 10.70 grams of NH4Cl and 25.00 mL of 12 M NH3 in enough water to make 1.000 L of solution? Kb = 1.80 × 10-5 for NH3.

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In which of the following solutions would solid PbCl2 be expected to be the least soluble at 25°C?

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What is the molar solubility of AgCl in 0.10 M NaCN if the colorless complex ion Ag(CN)2- forms? Ksp for AgCl is 1.8 × 10-10 and Kf for Ag(CN)2- is What is the molar solubility of AgCl in 0.10 M NaCN if the colorless complex ion Ag(CN)<sub>2</sub><sup>-</sup> forms? K<sub>sp</sub> for AgCl is 1.8 × 10<sup>-10</sup> and K<sub>f</sub> for Ag(CN)<sub>2</sub><sup>-</sup> is

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A buffer solution is prepared by dissolving 27.22 g of KH2PO4 and 3.37 g of KOH in enough water to make 0.100 L of solution.What is the pH of the H2PO4-/HPO42- buffer if the Ka2 = 6.2 × 10-8?

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The balanced net ionic equation for the neutralization reaction involving equal molar amounts of HNO3 and KOH is ________.

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What volume of 0.100 M NaOH is needed to make 100.0 mL of a buffer solution with a pH of 6.00 if one starts with 50.0 mL of 0.100 M potassium hydrogen phthalate? The Ka2 for potassium hydrogen phthalate is 3.1 × 10-6.

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Which of the following combinations of chemicals could be used to make a buffer solution?

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The pH of a 0.150 M formic acid/0.250 M sodium formate buffer = ________? The Ka of formic acid is 1.8 × 10-4.

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What is the percent dissociation of acetic acid if the solution has a pH = 4.74 and a pKa = 4.74?

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What is the pH of the solution formed when 25 mL of 0.173 M NaOH is added to 35 mL of 0.342 M HCl?

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Which of these neutralization reactions has a pH = 7 when equal molar amounts of acid and base are mixed?

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The following pictures represent solutions of CaCO3,which may also contain ions other than Ca2+ and CO32- which are not shown.Gray spheres represent Ca2+ ions and unshaded spheres represent CO32- ions. The following pictures represent solutions of CaCO<sub>3</sub>,which may also contain ions other than Ca<sup>2+</sup> and CO<sub>3</sub><sup>2-</sup> which are not shown.Gray spheres represent Ca<sup>2+</sup> ions and unshaded spheres represent CO<sub>3</sub><sup>2-</sup> ions.   -If solution (1)is a saturated solution of CaCO<sub>3</sub>,which of solutions (1)-(4)represents the solution after a small amount of NaOH is added and equilibrium is restored? -If solution (1)is a saturated solution of CaCO3,which of solutions (1)-(4)represents the solution after a small amount of NaOH is added and equilibrium is restored?

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The following pictures represent solutions of CaCO3,which may also contain ions other than Ca2+ and CO32- which are not shown.Gray spheres represent Ca2+ ions and unshaded spheres represent CO32- ions. The following pictures represent solutions of CaCO<sub>3</sub>,which may also contain ions other than Ca<sup>2+</sup> and CO<sub>3</sub><sup>2-</sup> which are not shown.Gray spheres represent Ca<sup>2+</sup> ions and unshaded spheres represent CO<sub>3</sub><sup>2-</sup> ions.   -If solution (1)is a saturated solution of CaCO<sub>3</sub>,which of solutions (1)-(4)represents the solution after a small amount of K<sub>2</sub>CO<sub>3</sub> is added and equilibrium is restored? -If solution (1)is a saturated solution of CaCO3,which of solutions (1)-(4)represents the solution after a small amount of K2CO3 is added and equilibrium is restored?

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Calculate the solubility (in g/L)of silver chromate in water at 25°C if the Ksp for Ag2CrO4 is 1)1 × 10-12.

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