Exam 15: Applications of Aqueous Equilibria

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0.10 M potassium chromate is slowly added to a solution containing 0.50 M AgNO3 and 0.50 M Ba(NO3)2.What is the Ag+ concentration when BaCrO4 just starts to precipitate? The Ksp for Ag2CrO4 and BaCrO4 are 1.1 × 10-12 and 1.2 × 10-10,respectively.

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State whether the solubility of Cu(OH)2 will increase or decrease upon the addition of aqueous solutions of a)HCl,b)NaOH,c)NH3.

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Addition of 0.0125 mol HCl to 150 mL of a 0.150 M formic acid/0.100 M sodium formate buffer results in a pH = ________? The Ka of formic acid is 1.8 × 10-4.

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Which is a net ionic equation for the neutralization reaction of a strong acid with a weak base?

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What is the silver ion concentration for a saturated solution of Ag2CO3 if the Ksp for Ag2CO3 is 8.4 × 10-12?

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Which of the following titrations result in an acidic solution at the equivalence point?

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Oxalic acid,H2C2O4 has acid dissociation constants Ka1 = 5.9 × 10-2 and Ka2 = 6.4 × 10-5. What is the pH after 20.00 mL of 0.0500 M NaOH is added to 5.00 mL of 0.2000 M H2C2O4?

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The following pictures represent solutions that contain a weak acid HA (pKa = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA (pK<sub>a</sub> = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup>,OH<sup>-</sup>,and solvent H<sub>2</sub>O molecules have been omitted for clarity. )   -For which of these solutions is pH = pK<sub>a</sub>? -For which of these solutions is pH = pKa?

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The artist's pigment cadmium yellow,CdS,has a water solubility of 0.13 g/L.The solubility product of CdS,Ksp = ________.

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What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous hydrofluoric acid requires 30.00 mL of 0.400 M NaOH? Ka = 6.76 × 10-4 for HF.

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The following pictures represent solutions of AgCl,which may also contain ions other than Ag+ and Cl- which are not shown.Gray spheres represent Ag+ ions and dotted spheres represent Cl- ions. The following pictures represent solutions of AgCl,which may also contain ions other than Ag<sup>+</sup> and Cl<sup>-</sup> which are not shown.Gray spheres represent Ag<sup>+</sup> ions and dotted spheres represent Cl<sup>-</sup> ions.   -If solution (1)is a saturated solution of AgCl,which of solutions (1)-(4)represents the solution after a small amount of HCl is added and equilibrium is restored? -If solution (1)is a saturated solution of AgCl,which of solutions (1)-(4)represents the solution after a small amount of HCl is added and equilibrium is restored?

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The following pictures represent solutions of CuS,which may also contain ions other than Cu2+ and S2- which are not shown.Gray spheres represent Cu2+ ions and dotted spheres represent S2- ions. The following pictures represent solutions of CuS,which may also contain ions other than Cu<sup>2+</sup> and S<sup>2-</sup> which are not shown.Gray spheres represent Cu<sup>2+</sup> ions and dotted spheres represent S<sup>2-</sup> ions.   -If solution (1)is a saturated solution of CuS,which of solutions (2)-(4)are unsaturated? -If solution (1)is a saturated solution of CuS,which of solutions (2)-(4)are unsaturated?

(Multiple Choice)
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What is the equation relating the equilibrium constant Kn for the neutralization of a weak acid with a weak base to the Ka of the acid,the Kb of the base and Kw?

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Use the graphs below to answer the following questions. Use the graphs below to answer the following questions.   -What is the characteristic pH-titrant curve for the titration of a strong acid by a strong base? -What is the characteristic pH-titrant curve for the titration of a strong acid by a strong base?

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Which metal ions can be precipitated out of solution as chlorides?

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The neutralization constant Kn for the neutralization of acetylsalicylic acid (C9H8O4)and codeine (C18H21NO3)is 4.8 × 104.The acid dissociation constant Ka for acetylsalicylic acid is 3.0 × 10-4.What is the base dissociation constant Kb for codeine?

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The following plot shows two titration curves,each representing the titration of 50.00 mL of 0.100 M acid with 0.100 M NaOH. The following plot shows two titration curves,each representing the titration of 50.00 mL of 0.100 M acid with 0.100 M NaOH.   -Which point a-d represents a buffer region? -Which point a-d represents a buffer region?

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What is the pH of a solution prepared by mixing 25.00 mL of 0.10 M CH3CO2H with 25.00 mL of 0.0 10 M CH3CO2Na? Assume that the volume of the solutions are additive and that Ka = 1.8 × 10-5 for CH3CO2H.

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Which metal sulfides can be precipitated from a solution that is 0.01 M in Mn2+,Zn2+,Pb2+ and Cu2+ and 0.10 M in H2S at a pH of 1.0? Which metal sulfides can be precipitated from a solution that is 0.01 M in Mn<sup>2+</sup>,Zn<sup>2+</sup>,Pb<sup>2+</sup> and Cu<sup>2+</sup> and 0.10 M in H<sub>2</sub>S at a pH of 1.0?

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The following pictures represent solutions that contain a weak acid HA (pKa = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. ) The following pictures represent solutions that contain a weak acid HA (pK<sub>a</sub> = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A<sup>-</sup> ions.(K<sup>+</sup>,H<sub>3</sub>O<sup>+</sup>,OH<sup>-</sup>,and solvent H<sub>2</sub>O molecules have been omitted for clarity. )   -Which of these solutions are buffers? -Which of these solutions are buffers?

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