Exam 15: Applications of Aqueous Equilibria
Exam 1: Chemistry: Matter and Measurement219 Questions
Exam 2: Atoms, molecules, and Ions257 Questions
Exam 3: Formulas, equations, and Moles208 Questions
Exam 4: Reactions in Aqueous Solutions174 Questions
Exam 5: Periodicity and the Atomic Structure of Atoms158 Questions
Exam 6: Ionic Bonds and Some Main-Group Chemistry173 Questions
Exam 7: Covalent Bonds and Molecular Structure232 Questions
Exam 8: Thermochemistry: Chemical Energy163 Questions
Exam 9: Gases: Their Properties and Behavior182 Questions
Exam 10: Liquids,solids,and Phase Changes186 Questions
Exam 11: Solutions and Their Properties192 Questions
Exam 12: Chemical Kinetics206 Questions
Exam 13: Chemical Equilibrium166 Questions
Exam 14: Aqueous Equilibria: Acids and Bases224 Questions
Exam 15: Applications of Aqueous Equilibria190 Questions
Exam 16: Thermodynamics: Entropy, free Energy, and Equilibrium144 Questions
Exam 17: Electrochemistry176 Questions
Exam 18: Hydrogen, oxygen, and Water175 Questions
Exam 19: The Main-Group Elements202 Questions
Exam 20: Transition Elements and Coordination Chemistry185 Questions
Exam 21: Metals and Solid-State Materials149 Questions
Exam 22: Nuclear Chemistry85 Questions
Exam 23: Organic and Biological Chemistry285 Questions
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The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. )
-Which of the solutions are buffer solutions?

(Multiple Choice)
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What is the Henderson-Hasselbalch equation for the acidic buffer HA/A-?
(Multiple Choice)
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What is the pH of the solution formed when 50 mL of 0.250 M NaOH is added to 50 mL of 0.120 M HCl?
(Short Answer)
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The following pictures represent solutions of AgCl,which may also contain ions other than Ag+ and Cl- which are not shown.Gray spheres represent Ag+ ions and dotted spheres represent Cl- ions.
-If solution (1)is a saturated solution of AgCl,which of solutions (1)-(4)represents the solution after a small amount of NH3 is added and equilibrium is restored?

(Multiple Choice)
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TRIS {(HOCH2)3CNH2} is one of the most common buffers used in biochemistry.A solution is prepared by adding enough TRIS and 12 M HCl(aq)to give 1.00 L of solution with [TRIS] = 0.30 M and [TRISH+] = 0.60 M.What is the pH of this buffered system if the pKb is 5.92?
(Multiple Choice)
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What is the Ka of the amino acid glycine if it is 75.0% dissociated at pH = 10.08?
(Short Answer)
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What is the [CH3CO2-]/[CH3CO2H] ratio necessary to make a buffer solution with a pH of 4.44? Ka = 1.8 × 10-5 for CH3CO2H.
(Multiple Choice)
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When 50 mL of 0.10 M NaF is added to 50 mL of 0.10 M HF,relative to the pH of the 0.10 M HF solution the pH of the resulting solution will
(Multiple Choice)
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Calculate the Ksp for silver sulfite if the solubility of Ag2SO3 in pure water is 4.6 × 10-3 g/L.
(Multiple Choice)
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Calculate the molar solubility of thallium(I)chloride in 0.40 M NaCl at 25°C.Ksp for TlCl is
1)7 × 10-4.
(Multiple Choice)
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The following pictures represent solutions that contain a weak acid HA (pKa = 5.0)and its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. )
-Which solution has the greatest buffer capacity?

(Multiple Choice)
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The following pictures represent solutions at various stages in the titration of a weak diprotic acid H2A with aqueous KOH.Unshaded spheres represent H atoms,black spheres represent oxygen atoms,and shaded spheres represent A2- ions.(K+,H3O+ initially present,OH- initially present and solvent water molecules have been omitted for clarity).
-Which picture represents the system halfway between the first and second equivalence points?

(Multiple Choice)
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Which is a net ionic equation for the neutralization reaction of a weak acid with a weak base?
(Multiple Choice)
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Which of these neutralization reactions has a pH < 7 when equal molar amounts of acid and base are mixed?
(Multiple Choice)
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A solution may contain the following ions Ag+,Cu2+,Cd2+,Mn2+,Ni2+ and Na+.A white precipitate formed when 0.10 M NaCl was added and after this was removed the solution was treated with H2S gas under acidic conditions and no precipitate formed.When the solution was made basic and again treated with H2S gas a dark colored precipitate formed.If no further tests were made then what conclusions can you draw?
(Multiple Choice)
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What is the pH at the equivalence point of a weak base-strong acid titration if 20.00 mL of NaOCl requires 28.30 mL of 0.50 M HCl? Ka = 3.0 × 10-8 for HOCl.
(Multiple Choice)
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What is the pH of a buffer solution made by mixing 50.0 mL of 0.100 M potassium hydrogen phthalate with 13.6 mL of 0.100 M NaOH and diluting the mixture to 100.0 mL with water? The Ka2 for hydrogen phthalate is 3.1 × 10-6.
(Multiple Choice)
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What is the pH of a solution made by mixing 10.00 mL of 0.10 M acetic acid with 10.00 mL of 0.10 M KOH? Assume that the volumes of the solutions are additive.Ka =1.8 × 10-5 for CH3CO2H.
(Multiple Choice)
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The following pictures represent solutions that contain a weak acid HA and/or its potassium salt KA.Unshaded spheres represent H atoms and shaded spheres represent A- ions.(K+,H3O+,OH-,and solvent H2O molecules have been omitted for clarity. )
-Which solution has the highest pH?

(Multiple Choice)
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The following plot shows two titration curves,each representing the titration of 50.00 mL of 0.100 M acid with 0.100 M NaOH.
-Which points a-d represent the half-equivalence point and the equivalence point,respectively,for the titration of a weak acid?

(Multiple Choice)
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