Exam 12: Solutions

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Calculate the mass of lactose, C12H22O11, contained in 500.0 mL of solution if the measured vapour pressure of the solution is 121.2 mbar at 50 °C. The vapour pressure of pure water at 50 °C is 123.3 mbar; assume no change in volume occurs upon dissolution.

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B

Calculate the total solution volume required to produce an osmotic pressure of 4.87 mbar using 8.21 mg of a protein with a molar mass of 4450 g mol-1 at 25.0 °C.

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D

Choose the aqueous solution below with the highest freezing point. These are all solutions of nonvolatile solutes and you should assume ideal van't Hoff factors where applicable.

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C

What mass of NaCl is contained in 24.88 g of a 15.00% by mass solution of NaCl in water?

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Identify the solute with the highest van't Hoff factor.

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Which of the following should have the largest Henry's law constant (kH) in water at 25 °C?

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A solution is prepared by adding 40.00 g of lactose (milk sugar) to 110.0 g of water at A solution is prepared by adding 40.00 g of lactose (milk sugar) to 110.0 g of water at   The partial pressure of water above the solution is ________ Torr. The vapour pressure of pure water at 55 °C is 0.1553 bar. The MW of lactose is  The partial pressure of water above the solution is ________ Torr. The vapour pressure of pure water at 55 °C is 0.1553 bar. The MW of lactose is A solution is prepared by adding 40.00 g of lactose (milk sugar) to 110.0 g of water at   The partial pressure of water above the solution is ________ Torr. The vapour pressure of pure water at 55 °C is 0.1553 bar. The MW of lactose is

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Which of the following should have the smallest Henry's law constant (kH) in water at 25 °C?

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Which of the following statements is TRUE?

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What molality of pentane is obtained by dissolving 15 g pentane, C5H12, in 245.0 g hexane, C6H14?

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Define osmosis.

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Calculate the molality of a solution that is prepared by mixing 25.5 mL of CH3OH (d = 0.792 g mL-1) and 387 mL of CH3CH2CH2OH (d = 0.811 g mL-1).

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Identify the gas that is dissolved in carbonated sodas.

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Determine the freezing point of a solution that contains 78.8 g of naphthalene (C10H8, molar mass = 128.16 g mol-1) dissolved in 722 mL of benzene (d = 0.877 g mL-1). Pure benzene has a melting point of 5.50 °C and a freezing point depression constant of 4.90 °C m-1.

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Give the preparation of rock candy.

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Calculate the boiling point of a solution of 500.0 g of ethylene glycol (C2H6O2) dissolved in 500.0 g of water. Kf = 1.86 °C m-1 and Kb = 0.512 °C m-1. Use 100 °C as the boiling point of water.

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Identify the classification of opal.

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The boiling point elevation of an aqueous sucrose solution is found to be 0.39 °C. What mass of sucrose (molar mass = 342.30 g mol-1) would be needed to dissolve in 500.0 g of water? Kb (water) = 0.512 °C m-1.

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When LiI is dissolved in water, the solution becomes hotter. Choose the situation below that best describes this change.

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Define the Tyndall effect.

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