Exam 17: Additional Aspects of Equilibria

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Consider a solution containing 0.100 M fluoride ions and 0.126 M hydrogen fluoride. The concentration of fluoride ions after the addition of 5.00 mL of 0.0100 M HCl to 25.0 mL of this solution is __ M.

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Suppose you have just added 100.0 ml of a solution containing 0.5000 moles of acetic acid per liter to 400.0 ml of 0.5000 M NaOH. What is the final pH? The Ka of acetic acid is 1.770× 10- 5.

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Calculate the pH of a solution that is 0.295 M in sodium formate (NaHCO2) and 0.205 M in formic acid (HCO2H). The Ka of formic acid is 1.77 × 10- 4.

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Calculate the pH of a solution prepared by dissolving 0.370 mol of formic acid (HCO2H) and 0.230 mol of sodium formate (NaCO2H) in water sufficient to yield 1.00 L of solution. The Ka of formic acid is 1.77 × 10- 4.

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Consider the following table of Ksp values. Consider the following table of K<sub>sp </sub>values.   -Which compound listed below has the greatest molar solubility in water? -Which compound listed below has the greatest molar solubility in water?

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A 25.0 mL sample of 0.723 M HClO4 is titrated with a 0.273 M KOH solution. What is the [H+] (molarity) before any base is added?

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Which of the following could be added to a solution of sodium acetate to produce a buffer? acetic acid hydrochloric acid potassium acetate sodium chloride

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Which one of the following will cause hemoglobin to release oxygen?

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A 25.0 mL sample of a solution of a monoprotic acid is titrated with a 0.115 M NaOH solution. The titration curve above was obtained. Which of the following indicators would be best for this titration?

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Consider a solution containing 0.100 M fluoride ions and 0.126 M hydrogen fluoride. The concentration of hydrogen fluoride after addition of 5.00 mL of 0.0100 M HCl to 25.0 mL of this solution is __ M.

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What is the molar solubility of barium fluoride ( BaF2 ) in water? The solubility- product constant for BaF2 is 1.7 × 10- 6 at 25°C.

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The concentration of iodide ions in a saturated solution of lead (II) iodide is M. The solubility product constant of PbI2 is 1.4 × 10- 8.

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The Ksp for Zn(OH)2 is 5.0 × 10- 17. Determine the molar solubility of Zn(OH)2 in a buffer solution with a pH of 11.5.

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Calculate the percent ionization of formic acid (HCO2H) in a solution that is 0.219 M in formic acid. The Ka of formic acid is 1.77 × 10- 4.

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For which salt should the aqueous solubility be most sensitive to pH?

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A 25.0 mL sample of 0.150 M hypochlorous acid is titrated with a 0.150 M NaOH solution. What is the pH after 26.0 mL of base is added? The Ka of hypochlorous acid is 3.0 × 10- 8.

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The solubility of manganese (II) hydroxide (Mn(OH)2) is 2.2 × 10- 5 M. What is the Ksp of Mn (OH)2?

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The solubility of lead (II) chloride (PbCl2) is 1.6 × 10-2 M. What is the Ksp of PbCl2?

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The solubility product of a compound is numerically equal to the product of the concentration of the ions involved in the equilibrium, each multiplied by its coefficient in the equilibrium reaction.

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In which aqueous system is PbI2 least soluble?

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