Exam 16: Aqueous Acidbase Equilibriums

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A(n) _____ takes place when atoms or groups of atoms in a molecule other than those to which H is bonded induces a change in the distribution of electrons within the molecule.

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inductive effect

A buffer solution contains 0.150 M HCO2H and 0.225M HCO2Na and has a pH of 3.75. What is the final pH if 5.00 mL of 1.00M HCl are added to 100.0 mL of this solution?

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E

The analytical concentration of an acid or a base is the final concentration.

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False

The percent ionization in a solution of a weak acid increases as the analytical concentration decreases.

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_____ are solutions that maintain a relatively constant pH when an acid or a base is added.

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An acid-base equilibrium always favors the side with the stronger acid and base.

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An acid-base reaction involves the reaction of a proton with a hydroxide ion to form _____.

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The most important parameter for predicting the effect of a metal ion on the acidity of coordinated water molecules is the _____ of the metal ion.

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If the pKb of a conjugate base is equal to 10.9 at 45.0C45.0 ^ { \circ } \mathrm { C } , the value of its Kb is _____.

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The pH at the midpoint of the titration of a weak acid is equal to the pKa of the weak acid.

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_____ is the only common oxoacid in which a hydrogen atom is bonded to the central atom rather than oxygen.

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In the reaction HCl+H2OfH3O++Cl\mathrm { HCl } + \mathrm { H } _ { 2 } \mathrm { Of } \quad \mathrm { H } _ { 3 } \mathrm { O } ^ { + } + \mathrm { Cl } ^ { - } , the number of conjugate acid-base pairs is ____.

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The amount of excess CH3CO2H after 6.00 mL of 0.300 M NaOH has been added to 20.0 mL of 0.100M CH3CO2H is _____ mmol CH3CO2H.

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The pKa\mathrm { p } K _ { a } of hydrochloric acid is _____, if the pKb\mathrm { p } K _ { b } of its conjugate base is 8.56 at 25C25 ^ { \circ } \mathrm { C } .

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The shape of the titration curve involving a strong acid and a strong base depends only on their identities, not their concentrations.

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Which of the following acids will most likely be the strongest?

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The larger the atom to which hydrogen is bonded, the stronger the bond.

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If the KwK _ { w } for water at 80C80 ^ { \circ } \mathrm { C } is 5.60×10115.60 \times 10 ^ { - 11 } , the pKw\mathrm { p } K _ { w } for water at the same temperature is _____.

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The pH of any neutral solution is equal to the solution's pKw\mathrm { p } K _ { w } at that temperature.

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Electron delocalization in the conjugate base decreases acid strength.

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