Exam 22: The Transition Elements and Their Coordination Compounds

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Apply the valence bond theory to predict the electronic structure and hybridization pattern of chromium in the complex ion Cr(NH3)63+.

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The three d electrons of the Cr(III)will occupy three 3d orbitals,singly.The remaining two 3d orbitals will be hybridized with the 4s and 4p orbitals,yielding six d2sp3 hybrid orbitals,which are used to accommodate the six lone pairs of the ammonia ligands.

In the spectrochemical series,which one of the following ligands has the strongest field?

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B

The ground state electron configuration of Cr2+ is

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C

Consider the following octahedral complex structures,each involving ethylene diamine and two different,unidentate ligands X and Y. Consider the following octahedral complex structures,each involving ethylene diamine and two different,unidentate ligands X and Y.   Which one of the following statements about these structures is incorrect? Which one of the following statements about these structures is incorrect?

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Of the 3d transition series of elements,scandium has the greatest atomic radius.

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Write the formula for sodium tetracyanonickelate(II).

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If M represents a transition element,which of the following oxides should be the least basic?

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Tetrahedral complexes can exhibit both optical and linkage isomerism.

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Which of the following species could exist as isomers?

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In the compound [Ni(en)2(H2O)2]SO4 (where en = ethylenediamine)the oxidation number and coordination number of nickel are,respectively:

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The crystal field splitting energy, Δ\Delta ,

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The compound Rh(CO)(H)(PH3)2 forms cis and trans isomers.Use this information to predict the geometry of this complex,and draw the geometric isomers.

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Which of the following transition elements will form an ion with the largest oxidation number?

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In a coordination compound involving a complex ion of square planar geometry,which of the following types of isomerism is/are never possible?

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Which of the following ions could exist in only the high-spin state in an octahedral complex?

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Which of the following will be the strongest oxidizing agent?

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What is the coordination number of cobalt in the complex ion [Co(en)Cl4]-? (en = ethylenediamine)

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According to valence bond theory,what would be the set of hybrid orbitals used when a Period 4 transition metal forms a tetrahedral complex?

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The oxidation and coordination numbers of cobalt in the compound [Co(NH3)5Cl]Cl2 are,respectively:

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What geometry is particularly common for complexes of d10 metal ions?

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