Exam 20: Thermodynamics: Entropy, free Energy, and the Direction of Chemical Reactions

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Calculate Δ\Delta S° for the reaction SiCl4(g)+ 2Mg(s) \to 2MgCl2(s)+ Si(s)  Calculate  \Delta S° for the reaction SiCl<sub>4</sub>(g)+ 2Mg(s)  \to  2MgCl<sub>2</sub>(s)+ Si(s)

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B

The temperature at which the following process reaches equilibrium at 1.0 atm is the normal boiling point of hydrogen peroxide. H2O2(l) The temperature at which the following process reaches equilibrium at 1.0 atm is the normal boiling point of hydrogen peroxide. H<sub>2</sub>O<sub>2</sub>(l)   H<sub>2</sub>O<sub>2</sub>(g) Use the following thermodynamic information at 298 K to determine this temperature.  H2O2(g) Use the following thermodynamic information at 298 K to determine this temperature. The temperature at which the following process reaches equilibrium at 1.0 atm is the normal boiling point of hydrogen peroxide. H<sub>2</sub>O<sub>2</sub>(l)   H<sub>2</sub>O<sub>2</sub>(g) Use the following thermodynamic information at 298 K to determine this temperature.

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Which of the following pairs has the member with the greater molar entropy listed first? All systems are at 25°C.

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The water-gas shift reaction plays an important role in the production of clean fuel from coal. CO(g)+ H2O(g) The water-gas shift reaction plays an important role in the production of clean fuel from coal. CO(g)+ H<sub>2</sub>O(g)    CO<sub>2</sub>(g)+ H<sub>2</sub>(g) Use the following thermodynamic data to determine the equilibrium constant K<sub>p</sub> at 700.K.   CO2(g)+ H2(g) Use the following thermodynamic data to determine the equilibrium constant Kp at 700.K. The water-gas shift reaction plays an important role in the production of clean fuel from coal. CO(g)+ H<sub>2</sub>O(g)    CO<sub>2</sub>(g)+ H<sub>2</sub>(g) Use the following thermodynamic data to determine the equilibrium constant K<sub>p</sub> at 700.K.

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Which relationship or statement best describes Δ\Delta S° for the following reaction? 2H2S(g)+ 3O2(g) \to 2H2O(g)+ 2SO2(g)

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Which,if any,of the following processes is spontaneous under the specified conditions?

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In tables of thermodynamic data provided in chemistry books,one finds Δ\Deltaf , Δ\Deltaf and S° listed.Briefly,explain why the entropy data are supplied as S°,while the enthalpy and free energy data are in the form of Δ\Deltaf and Δ\Deltaf,respectively.

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Sulfuryl dichloride is formed when sulfur dioxide reacts with chlorine.The data refer to 298 K. SO2(g)+ Cl2(g) \to SO2Cl2(g)  Sulfuryl dichloride is formed when sulfur dioxide reacts with chlorine.The data refer to 298 K. SO<sub>2</sub>(g)+ Cl<sub>2</sub>(g)  \to  SO<sub>2</sub>Cl<sub>2</sub>(g)   What is the value of  \Delta G° for this reaction at 600 K? What is the value of Δ\Delta G° for this reaction at 600 K?

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Which relationship or statement best describes Δ\Delta S° for the following reaction? Pb(s)+ Cl2(g) \to PbCl2(s)

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Which of the following is necessary for a process to be spontaneous?

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Calculate Δ\Delta S° for the reaction 4Cr(s)+ 3O2(g) \to 2Cr2O3(s)  Calculate  \Delta S° for the reaction 4Cr(s)+ 3O<sub>2</sub>(g) \to  2Cr<sub>2</sub>O<sub>3</sub>(s)

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Consider the figure below which shows Δ\Delta G° for a chemical process plotted against absolute temperature.Which one of the following is an incorrect conclusion,based on the information in the diagram?  Consider the figure below which shows  \Delta G° for a chemical process plotted against absolute temperature.Which one of the following is an incorrect conclusion,based on the information in the diagram?

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Which relationship or statement best describes Δ\Delta S° for the following reaction? HgS(s)+ O2(g) \to Hg(l)+ SO2(g)

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Elemental boron can be formed by reaction of boron trichloride with hydrogen. BCl3(g)+ 1.5H2(g) \to B(s)+ 3HCl(g) Calculate Δ\Delta G° for the reaction.  Elemental boron can be formed by reaction of boron trichloride with hydrogen. BCl<sub>3</sub>(g)+ 1.5H<sub>2</sub>(g)  \to  B(s)+ 3HCl(g) Calculate  \Delta G° for the reaction.

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Photosynthesis can be represented by the equation 6CO2(g)+ 6H2O(l) \to C6H12O6(s)+ 6O2(g) a.Calculate Δ\Delta S° for this process,given the following data:  Photosynthesis can be represented by the equation 6CO<sub>2</sub>(g)+ 6H<sub>2</sub>O(l)  \to C<sub>6</sub>H<sub>12</sub>O<sub>6</sub>(s)+ 6O<sub>2</sub>(g) a.Calculate  \Delta S° for this process,given the following data:     b.Given that  \Delta H° for the reaction is 2802 kJ,calculate  \Delta G° at 25°C. b.Given that Δ\Delta H° for the reaction is 2802 kJ,calculate Δ\Delta G° at 25°C.

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Consider the figure below which shows Δ\Delta G° for a chemical process plotted against absolute temperature.From this plot,it is reasonable to conclude that:  Consider the figure below which shows  \Delta G° for a chemical process plotted against absolute temperature.From this plot,it is reasonable to conclude that:

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For a reaction at equilibrium, Δ\Delta Suniv = 0.

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The free energy of a perfect crystal at absolute zero,is zero.

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A certain process has Δ\Delta Suniv > 0 at 25°C.What does one know about the process?

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Which relationship or statement best describes Δ\Delta S° for the following reaction? K2SO4(s) \to 2K+(aq)+ SO42-(aq)

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