Exam 19: Ionic Equilibria in Aqueous Systems

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Barium sulfate (BaSO4) is a slightly soluble salt, with Ksp = 1.1 × 10-10. What mass of Ba2+ ions will be present in 1.0 L of a saturated solution of barium sulfate?

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The equivalence point in a titration is defined as the point when the indicator changes color.

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A lab technician adds 0.20 mol of NaF to 1.00 L of 0.35 M cadmium nitrate, Cd(NO3)2. Which of the following statements is correct? Ksp = 6.44 × 10-3 for CdF2.

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A sample of a monoprotic acid (HA) weighing 0.384 g is dissolved in water and the solution is titrated with aqueous NaOH. If 30.0 mL of 0.100 M NaOH is required to reach the equivalence point, what is the molar mass of HA?

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When a strong acid is titrated with a weak base, the pH at the equivalence point

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Citric acid has an acid dissociation constant of 8.4 × 10-4. It would be most effective for preparation of a buffer with a pH of

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What is the pH of a buffer that consists of 0.20 M NaH2PO4 and 0.40 M Na2HPO4? For NaH2PO4, Ka = 6.2 × 10-8

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Which of the following has the highest buffer capacity?

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A solution is prepared by adding 100 mL of 0.2 M hydrochloric acid to 100 mL of 0.4 M sodium formate. Is this a buffer solution, and if so, what is its pH?

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What is the [H3O+] in a solution that consists of 1.5 M NH3 and 2.5 NH4Cl? Kb = 1.8 × 10-5

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A 20.0-mL sample of 0.30 M HBr is titrated with 0.15 M NaOH. What is the pH of the solution after 40.3 mL of NaOH have been added to the acid?

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Assuming that the total volume does not change after 0.200 g of KCl is added to 1.0 L of a saturated aqueous solution of AgCl, calculate the number of moles of Ag+ ion in the solution after equilibrium has been reestablished. For AgCl, Ksp = 1.8 × 10-10.

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Calculate the solubility of magnesium sulfate, MgSO4, when placed into a 0.10 M MgCl2 solution. Ksp = 5.9 × 10-3

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The salts X(NO3)2 and Y(NO3)2 (where X+ and Y+ are metal ions) are dissolved in water to give a solution which is 0.1 M in each of them. Using the Ksp values listed below, decide which aqueous reagent, if any, will definitely precipitate X+ before precipitating Y+ from solution. Given Ksp values: XCl2, 1 × 10-5 YCl2, 1 × 10-10 X(OH)2, 1 × 10-10 Y(OH)2, 1 × 10-5

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The end point in a titration is defined as the point when the indicator changes color.

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Which of the following substances has the greatest solubility in water?

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A buffer is prepared by adding 100 mL of 0.50 M sodium hydroxide to 100 mL of 0.75 M propanoic acid. Is this a buffer solution, and if so, what is its pH?

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Which one of the following pairs of 0.100 mol L-1 solutions, when mixed, will produce a buffer solution?

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The concentration of the complex ion in each of following solutions is 1.00 M. In which of the solutions will the concentration of the uncomplexed metal ion be the greatest? Hg(CN)42- Kf = 9.3 × 1038 Be(OH) 42- Kf = 4.0 × 1018 Zn(OH) 42- Kf = 3.0 × 1015 Cu(NH3)42+ Kf = 5.6 × 1011 CdI42- Kf = 1.0 × 106

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Which, if any, of the following aqueous mixtures would be a buffer system?

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