Exam 19: Ionic Equilibria in Aqueous Systems

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Use the following information to calculate the solubility product constant, Ksp, for PbCl2. A saturated solution of PbCl2 in water was prepared and filtered. From the filtrate, 1.0 L was measured out into a beaker and evaporated to dryness. The solid PbCl2 residue recovered in the beaker amounted to 0.0162 moles.

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Calculate the solubility of silver oxalate, Ag2C2O4, in pure water. Ksp = 1.0 × 10-11

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A popular buffer solution consists of carbonate (CO32-) and hydrogen carbonate (HCO3-) conjugate acid-base pair. Which, if any, of the following such buffers can neutralize the greatest amount of added hydrochloric acid, while remaining within its buffer range?

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Buffer solutions with the component concentrations shown below were prepared. Which of them should have the lowest pH?

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What is the pKa for the acid HA if a solution of 0.65 M HA and 0.85 M NaA has a pH of 4.75?

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Which one of the following aqueous solutions, when mixed with an equal volume of 0.10 mol L-1 aqueous NH3, will produce a buffer solution?

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A change in pH will significantly affect the solubility of which, if any, of the following compounds?

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A buffer is prepared by adding 150 mL of 1.0 M NaOH to 250 mL of 1.0 M NaH2PO4. How many moles of HCl must be added to this buffer solution to change the pH by 0.18 units? If necessary, assume the total volume remains unchanged at 400 mL.

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A solution is prepared by adding 4.50 mol of sodium hydroxide to 1.00 L of 1.00 M Co(NO3)2. What is the equilibrium concentration of cobalt ions? Kf = 5.0 × 109 for Co(OH)42-

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The solubility of silver chromate is 0.0287 g/1.0 L of solution. What is the Ksp for Ag2CrO4?

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Calculate the solubility of silver phosphate, Ag3PO4, in pure water. Ksp = 2.6 × 10-18

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A 20.0-mL sample of 0.50 M H2C6H6O6 (ascorbic acid, a diprotic acid) was titrated with 0.50 M NaOH. The following data were gathered during the titration. mL NaOH added 10.00 20.00 30.00 40.00 PH 4.17 5.21 11.55 12.89 What is Ka2 for ascorbic acid?

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Equal volumes of the following pairs of solutions are mixed. Which pair will produce a buffer solution?

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A popular buffer solution consists of carbonate (CO32-) and hydrogen carbonate (HCO3-) conjugate acid-base pair. Which, if any, of the following such buffers has the highest buffer capacity?

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The solubility of salt MX (solubility product constant Ksp) in water will always be greater than that of salt MX3 (solubility product constant K'sp) provided that Ksp > K'sp.

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Use the following information to calculate the solubility product constant, Ksp, for CuCl. A saturated solution of CuCl in water was prepared and filtered. From the filtrate, 1.0 L was measured out into a beaker and evaporated to dryness. The solid CuCl residue recovered in the beaker was found to weigh 0.041g.

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Calculate the molar solubility of silver carbonate in 1.0 M sodium carbonate solution. (Ksp for Ag2CO3 = 8.1 x 10-12)

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What is the maximum amount of sodium sulfate that can be added to 1.00 L of 0.0020 M Ca(NO3)2 before precipitation of calcium sulfate begins? Ksp = 2.4 × 10-5 for calcium sulfate.

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An acetate buffer has a pH of 4.40. Which of the following changes will cause the pH to decrease?

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A 35.0-mL sample of 0.20 M LiOH is titrated with 0.25 M HCl. What is the pH of the solution after 23.0 mL of HCl have been added to the base?

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