Exam 17: Equilibrium the Extent of Chemical Reactions
Exam 1: Keys to Studying Chemistry Definitions, Units, and Problem Solving71 Questions
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Exam 18: Acid-Base Equilibria100 Questions
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Consider the reversible reaction: 2NO2(g)
N2O4(g) If the concentrations of both NO2 and N2O4 are 0.016 mol L-1, what is the value of
c?


(Multiple Choice)
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Compounds A, B, and C react according to the following equation. 3A(g) + 2B(g)
2C(g)
At 100°C a mixture of these gases at equilibrium showed that [A] = 0.855 M, [B] = 1.23 M, and [C] = 1.75 M. What is the value of Kc for this reaction?
![Compounds A, B, and C react according to the following equation. 3A(g) + 2B(g) 2C(g) At 100°C a mixture of these gases at equilibrium showed that [A] = 0.855 M, [B] = 1.23 M, and [C] = 1.75 M. What is the value of K<sub>c</sub> for this reaction?](https://storage.examlex.com/TB7800/11eac68a_1c5f_fa96_a448_153f2af0638d_TB7800_11.jpg)
(Multiple Choice)
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At 850°C, the equilibrium constant Kp for the reaction C(s) + CO2(g)
2CO(g)
Has a value of 10.7. If the total pressure in the system at equilibrium is 1.000 atm, what is the partial pressure of carbon monoxide?

(Multiple Choice)
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Unless ΔH°rxn = 0, a change in temperature will affect the value of the equilibrium constant Kc.
(True/False)
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In water, the following equilibrium exists: H+(aq) + OH-(aq)
H2O(l)
In pure water at 25°C, the concentration of H+ ions is 1.00 × 10-7 mol/L. Calculate the value of the equilibrium constant for the reaction as written above.

(Multiple Choice)
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A chemical reaction will reach equilibrium when the limiting reactant is used up.
(True/False)
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At a certain temperature the reaction CO2(g) + H2(g)
CO(g) + H2O(g)2
Has Kc = 2.50. If 2.00 mol of carbon dioxide and 1.5 mol of hydrogen are placed in a 5.00 L vessel and equilibrium is established, what will be the concentration of carbon monoxide?

(Multiple Choice)
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Methanol can be synthesized by combining carbon monoxide and hydrogen. CO(g) + 2H2(g)
CH3OH(g) ΔH°rxn = -90.7 kJ
A reaction vessel contains these compounds at equilibrium. What effect will be seen when equilibrium is re-established after decreasing the temperature by 45°C?

(Multiple Choice)
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Write the mass-action expression,
c, for the following chemical reaction. Zn(s) + 2Ag+(aq)
Zn2+(aq) + 2Ag(s)


(Multiple Choice)
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The reaction quotient,
c, for a reaction has a value of 75 while the equilibrium constant, Kc, has a value of 195. Which of the following statements is accurate?

(Multiple Choice)
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The following reaction is at equilibrium at one atmosphere, in a closed container. NaOH(s) + CO2(g)
NaHCO3(s)
Which, if any, of the following actions will decrease the total amount of CO2 gas present at equilibrium?

(Multiple Choice)
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Write the mass-action expression,
c, for the following chemical reaction. NO(g) + ½Br2(g)
NOBr(g)


(Multiple Choice)
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The two equilibrium constants for the same reaction, Kc and Kp, will always equal one another when
(Multiple Choice)
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At high temperatures, carbon reacts with O2 to produce CO as follows: C(s) + O2(g)
2CO(g).
When 0.350 mol of O2 and excess carbon were placed in a 5.00-L container and heated, the equilibrium concentration of CO was found to be 0.060 M. What is the equilibrium constant, Kc, for this reaction?

(Multiple Choice)
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Consider the equilibrium reaction: N2O4(g)
2NO2(g) Which of the following correctly describes the relationship between Kc and Kp for the reaction?

(Multiple Choice)
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Nitric oxide is formed in automobile exhaust when nitrogen and oxygen in air react at high temperatures. N2(g) + O2(g)
2NO(g)
The equilibrium constant Kp for the reaction is 0.0025 at 2127°C. If a container is charged with 8.00 atm of nitrogen and 5.00 atm of oxygen and the mixture is allowed to reach equilibrium, what will be the equilibrium partial pressure of nitrogen?

(Multiple Choice)
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At 450°C, tert-butyl alcohol decomposes into water and isobutene. (CH3)3COH(g)
(CH3)2CCH2(g) + H2O(g)
A reaction vessel contains these compounds at equilibrium. What will happen if the volume of the container is reduced by 50% at constant temperature?

(Multiple Choice)
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Nitrogen dioxide can dissociate to nitric oxide and oxygen. 2NO2(g)
2NO(g) + O2(g) ΔH°rxn = +114 kJ
Under which reaction conditions would you expect to produce the largest amount of oxygen?

(Multiple Choice)
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At 500°C the equilibrium constant, Kp, is 4.00 × 10-4 for the equilibrium: 2HCN(g)
H2(g) + C2N2(g)
What is Kp for the following reaction?
H2(g) + C2N2(g)
2HCN(g)


(Multiple Choice)
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