Exam 17: Equilibrium the Extent of Chemical Reactions

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The following reaction is at equilibrium in a sealed container. N2(g) + 3H2(g) The following reaction is at equilibrium in a sealed container. N<sub>2</sub>(g) + 3H<sub>2</sub>(g)   2NH<sub>3</sub>(g) ΔH°<sub>rxn</sub> < 0 Which, if any, of the following actions will increase the value of the equilibrium constant, K<sub>c</sub>? 2NH3(g) ΔH°rxn < 0 Which, if any, of the following actions will increase the value of the equilibrium constant, Kc?

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For a solution equilibrium, a change in concentration of a reactant or product does not change Kc.

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The following reaction is at equilibrium at a pressure of 1 atm, in a closed container. NaOH(s) + CO2(g) The following reaction is at equilibrium at a pressure of 1 atm, in a closed container. NaOH(s) + CO<sub>2</sub>(g)   NaHCO<sub>3</sub>(s) ΔH°<sub>rxn</sub> < 0 Which, if any, of the following actions will decrease the concentration of CO<sub>2</sub> gas present at equilibrium? NaHCO3(s) ΔH°rxn < 0 Which, if any, of the following actions will decrease the concentration of CO2 gas present at equilibrium?

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For a gas-phase equilibrium, a change in the pressure of any single reactant or product will affect the amounts of other substances involved in the equilibrium.

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The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N2(g) + O2(g) The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N<sub>2</sub>(g) + O<sub>2</sub>(g)   2NO(g) At 2000°C, the equilibrium constant, K<sub>c</sub>, has a value of 4.10 × 10<sup>-4</sup>. What is the value of K<sub>p</sub>? 2NO(g) At 2000°C, the equilibrium constant, Kc, has a value of 4.10 × 10-4. What is the value of Kp?

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An equilibrium is established in which both the forward (fwd) and the reverse (rev) reactions are elementary. If the equilibrium constant Kc = 1.6 × 10-2 and the rate constant kfwd = 8.0 × 10-7 s-1 what is the value of krev?

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In order to write the correct mass-action expression for a reaction one must

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Hydrogen sulfide will react with water as shown in the following reactions. H2S(g) + H2O(l) Hydrogen sulfide will react with water as shown in the following reactions. H<sub>2</sub>S(g) + H<sub>2</sub>O(l)   H<sub>3</sub>O<sup>+</sup>(aq) + HS<sup>-</sup>(aq) K<sub>1</sub> = 1.0 × 10<sup>-7</sup> HS<sup>-</sup>(aq) + H<sub>2</sub>O(l)   H<sub>3</sub>O<sup>+</sup>(aq) + S<sup>2-</sup>(aq) K<sub>2</sub> = ? H<sub>2</sub>S(g) + 2H<sub>2</sub>O(l)   2H<sub>3</sub>O<sup>+</sup>(aq) + S<sup>2-</sup>(aq) K<sub>3</sub> = 1.3 × 10<sup>-20</sup> What is the value of K<sub>2</sub>? H3O+(aq) + HS-(aq) K1 = 1.0 × 10-7 HS-(aq) + H2O(l) Hydrogen sulfide will react with water as shown in the following reactions. H<sub>2</sub>S(g) + H<sub>2</sub>O(l)   H<sub>3</sub>O<sup>+</sup>(aq) + HS<sup>-</sup>(aq) K<sub>1</sub> = 1.0 × 10<sup>-7</sup> HS<sup>-</sup>(aq) + H<sub>2</sub>O(l)   H<sub>3</sub>O<sup>+</sup>(aq) + S<sup>2-</sup>(aq) K<sub>2</sub> = ? H<sub>2</sub>S(g) + 2H<sub>2</sub>O(l)   2H<sub>3</sub>O<sup>+</sup>(aq) + S<sup>2-</sup>(aq) K<sub>3</sub> = 1.3 × 10<sup>-20</sup> What is the value of K<sub>2</sub>? H3O+(aq) + S2-(aq) K2 = ? H2S(g) + 2H2O(l) Hydrogen sulfide will react with water as shown in the following reactions. H<sub>2</sub>S(g) + H<sub>2</sub>O(l)   H<sub>3</sub>O<sup>+</sup>(aq) + HS<sup>-</sup>(aq) K<sub>1</sub> = 1.0 × 10<sup>-7</sup> HS<sup>-</sup>(aq) + H<sub>2</sub>O(l)   H<sub>3</sub>O<sup>+</sup>(aq) + S<sup>2-</sup>(aq) K<sub>2</sub> = ? H<sub>2</sub>S(g) + 2H<sub>2</sub>O(l)   2H<sub>3</sub>O<sup>+</sup>(aq) + S<sup>2-</sup>(aq) K<sub>3</sub> = 1.3 × 10<sup>-20</sup> What is the value of K<sub>2</sub>? 2H3O+(aq) + S2-(aq) K3 = 1.3 × 10-20 What is the value of K2?

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A container was charged with hydrogen, nitrogen, and ammonia gases at 120°C and the system was allowed to reach equilibrium. What will happen if the volume of the container is increased at constant temperature? 3H2(g) + N2(g) A container was charged with hydrogen, nitrogen, and ammonia gases at 120°C and the system was allowed to reach equilibrium. What will happen if the volume of the container is increased at constant temperature? 3H<sub>2</sub>(g) + N<sub>2</sub>(g)   2NH<sub>3</sub>(g) 2NH3(g)

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At 25°C, the equilibrium constant Kc for the reaction 2A(g) At 25°C, the equilibrium constant K<sub>c</sub> for the reaction 2A(g)   B(g) + C(g) Is 0.035. A mixture of 8.00 moles of B and 12.00 moles of C in a 20.0 L container is allowed to come to equilibrium. What is the equilibrium concentration of A? B(g) + C(g) Is 0.035. A mixture of 8.00 moles of B and 12.00 moles of C in a 20.0 L container is allowed to come to equilibrium. What is the equilibrium concentration of A?

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Write the mass-action expression, c, for the following chemical reaction. 2Cu2+(aq) + 4I-(aq) Write the mass-action expression, c, for the following chemical reaction. 2Cu<sub>2+</sub>(aq) + 4I<sup>-</sup>(aq)   2CuI(s) + I<sub>2</sub>(aq) 2CuI(s) + I2(aq)

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Magnesium carbonate dissociates to magnesium oxide and carbon dioxide at elevated temperatures. MgCO3(s) Magnesium carbonate dissociates to magnesium oxide and carbon dioxide at elevated temperatures. MgCO<sub>3</sub>(s)   MgO(s) + CO<sub>2</sub>(g) A reaction vessel contains these compounds in equilibrium at 300°C. What will happen if the volume of the container is reduced by 25% at 300°C? MgO(s) + CO2(g) A reaction vessel contains these compounds in equilibrium at 300°C. What will happen if the volume of the container is reduced by 25% at 300°C?

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The reaction system POCl3(g) The reaction system POCl<sub>3</sub>(g)   POCl(g) + Cl<sub>2</sub>(g) Is at equilibrium. Which of the following statements describes the behavior of the system if POCl is added to the container? POCl(g) + Cl2(g) Is at equilibrium. Which of the following statements describes the behavior of the system if POCl is added to the container?

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Write the mass-action expression, Write the mass-action expression,   c, for the following chemical reaction. Sn<sup>2+</sup>(aq) + ½O<sub>2</sub>(g) + 3H<sub>2</sub>O(l)   SnO<sub>2</sub>(s) + 2H<sub>3</sub>O<sup>+</sup>(aq) c, for the following chemical reaction. Sn2+(aq) + ½O2(g) + 3H2O(l) Write the mass-action expression,   c, for the following chemical reaction. Sn<sup>2+</sup>(aq) + ½O<sub>2</sub>(g) + 3H<sub>2</sub>O(l)   SnO<sub>2</sub>(s) + 2H<sub>3</sub>O<sup>+</sup>(aq) SnO2(s) + 2H3O+(aq)

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Consider the reactions of cadmium with the thiosulfate anion. Cd2+(aq) + S2O32-(aq) Consider the reactions of cadmium with the thiosulfate anion. Cd<sup>2+</sup>(aq) + S<sub>2</sub>O<sub>3</sub><sup>2-</sup>(aq)   Cd(S<sub>2</sub>O<sub>3</sub>)(aq) K<sub>1</sub> = 8.3 × 10<sup>3</sup> Cd(S<sub>2</sub>O<sub>3</sub>)(aq) + S<sub>2</sub>O<sub>3</sub><sup>2-</sup>(aq)   Cd(S<sub>2</sub>O<sub>3</sub>)<sub>2</sub><sup>2-</sup>(aq) K<sub>2</sub> = 2.5 × 10<sup>2</sup> What is the value for the equilibrium constant for the following reaction? Cd<sup>2+</sup>(aq) + 2S<sub>2</sub>O<sub>3</sub><sup>2-</sup>(aq)   Cd(S<sub>2</sub>O<sub>3</sub>)<sub>2</sub><sup>2-</sup>(aq) Cd(S2O3)(aq) K1 = 8.3 × 103 Cd(S2O3)(aq) + S2O32-(aq) Consider the reactions of cadmium with the thiosulfate anion. Cd<sup>2+</sup>(aq) + S<sub>2</sub>O<sub>3</sub><sup>2-</sup>(aq)   Cd(S<sub>2</sub>O<sub>3</sub>)(aq) K<sub>1</sub> = 8.3 × 10<sup>3</sup> Cd(S<sub>2</sub>O<sub>3</sub>)(aq) + S<sub>2</sub>O<sub>3</sub><sup>2-</sup>(aq)   Cd(S<sub>2</sub>O<sub>3</sub>)<sub>2</sub><sup>2-</sup>(aq) K<sub>2</sub> = 2.5 × 10<sup>2</sup> What is the value for the equilibrium constant for the following reaction? Cd<sup>2+</sup>(aq) + 2S<sub>2</sub>O<sub>3</sub><sup>2-</sup>(aq)   Cd(S<sub>2</sub>O<sub>3</sub>)<sub>2</sub><sup>2-</sup>(aq) Cd(S2O3)22-(aq) K2 = 2.5 × 102 What is the value for the equilibrium constant for the following reaction? Cd2+(aq) + 2S2O32-(aq) Consider the reactions of cadmium with the thiosulfate anion. Cd<sup>2+</sup>(aq) + S<sub>2</sub>O<sub>3</sub><sup>2-</sup>(aq)   Cd(S<sub>2</sub>O<sub>3</sub>)(aq) K<sub>1</sub> = 8.3 × 10<sup>3</sup> Cd(S<sub>2</sub>O<sub>3</sub>)(aq) + S<sub>2</sub>O<sub>3</sub><sup>2-</sup>(aq)   Cd(S<sub>2</sub>O<sub>3</sub>)<sub>2</sub><sup>2-</sup>(aq) K<sub>2</sub> = 2.5 × 10<sup>2</sup> What is the value for the equilibrium constant for the following reaction? Cd<sup>2+</sup>(aq) + 2S<sub>2</sub>O<sub>3</sub><sup>2-</sup>(aq)   Cd(S<sub>2</sub>O<sub>3</sub>)<sub>2</sub><sup>2-</sup>(aq) Cd(S2O3)22-(aq)

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The equilibrium constant, Kp, for the reaction H2(g) + I2(g) The equilibrium constant, Kp, for the reaction H<sub>2</sub>(g) + I<sub>2</sub>(g)   2HI(g) Is 55.2 at 425°C. A rigid cylinder at that temperature contains 0.127 atm of hydrogen, 0.134 atm of iodine, and 1.055 atm of hydrogen iodide. Is the system at equilibrium? 2HI(g) Is 55.2 at 425°C. A rigid cylinder at that temperature contains 0.127 atm of hydrogen, 0.134 atm of iodine, and 1.055 atm of hydrogen iodide. Is the system at equilibrium?

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When a chemical system is at equilibrium,

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The reaction system CS2(g) + 4H2(g) The reaction system CS<sub>2</sub>(g) + 4H<sub>2</sub>(g)   CH<sub>4</sub>(g) + 2H<sub>2</sub>S(g) Is at equilibrium. Which of the following statements describes the behavior of the system if the partial pressure of carbon disulfide is reduced? CH4(g) + 2H2S(g) Is at equilibrium. Which of the following statements describes the behavior of the system if the partial pressure of carbon disulfide is reduced?

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At 25°C, the equilibrium constant Kc for the reaction 2A(aq) At 25°C, the equilibrium constant Kc for the reaction 2A(aq)   B(aq) + C(aq) Is 65. If 2.50 mol of A is added to enough water to prepare 1.00 L of solution, what will the equilibrium concentration of A be? B(aq) + C(aq) Is 65. If 2.50 mol of A is added to enough water to prepare 1.00 L of solution, what will the equilibrium concentration of A be?

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Nitrogen dioxide decomposes according to the reaction 2NO2(g) Nitrogen dioxide decomposes according to the reaction 2NO<sub>2</sub>(g)   2NO(g) + O<sub>2</sub>(g) Where K<sub>p</sub> = 4.48 × 10<sup>-13</sup> at 25°C. What is the value for K<sub>c</sub>? 2NO(g) + O2(g) Where Kp = 4.48 × 10-13 at 25°C. What is the value for Kc?

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