Exam 17: Equilibrium the Extent of Chemical Reactions
Exam 1: Keys to Studying Chemistry Definitions, Units, and Problem Solving71 Questions
Exam 2: The Components of Matter100 Questions
Exam 3: Stoichiometry of Formulas and Equations70 Questions
Exam 4: Three Major Classes of Chemical Reactions111 Questions
Exam 5: Gases and the Kinetic-Molecular Theory97 Questions
Exam 6: Thermochemistry Energy Flow and Chemical Change72 Questions
Exam 7: Quantum Theory and Atomic Structure69 Questions
Exam 8: Electron Configuration and Chemical Periodicity77 Questions
Exam 9: Models of Chemical Bonding61 Questions
Exam 10: The Shapes of Molecules98 Questions
Exam 11: Theories of Covalent Bonding48 Questions
Exam 12: Intermolecular Forces Liquids, Solids, and Phase Changes90 Questions
Exam 13: The Properties of Mixtures Solutions and Colloids96 Questions
Exam 14: Periodic Patterns in the Main-Group Elements102 Questions
Exam 15: Organic Compounds and the Atomic Properties of Carbon107 Questions
Exam 16: Kinetics Rates and Mechanisms of Chemical Reactions78 Questions
Exam 17: Equilibrium the Extent of Chemical Reactions97 Questions
Exam 18: Acid-Base Equilibria100 Questions
Exam 19: Ionic Equilibria in Aqueous Systems114 Questions
Exam 20: Thermodynamics Entropy, Free Energy, and Reaction Direction84 Questions
Exam 21: Electrochemistry Chemical Change and Electrical Work100 Questions
Exam 22: The Elements in Nature and Industry45 Questions
Exam 23: Transition Elements and Their Coordination Compounds82 Questions
Exam 24: Nuclear Reactions and Their Applications81 Questions
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The following reaction is at equilibrium in a sealed container. N2(g) + 3H2(g)
2NH3(g) ΔH°rxn < 0
Which, if any, of the following actions will increase the value of the equilibrium constant, Kc?

(Multiple Choice)
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For a solution equilibrium, a change in concentration of a reactant or product does not change Kc.
(True/False)
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The following reaction is at equilibrium at a pressure of 1 atm, in a closed container. NaOH(s) + CO2(g)
NaHCO3(s) ΔH°rxn < 0
Which, if any, of the following actions will decrease the concentration of CO2 gas present at equilibrium?

(Multiple Choice)
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For a gas-phase equilibrium, a change in the pressure of any single reactant or product will affect the amounts of other substances involved in the equilibrium.
(True/False)
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The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N2(g) + O2(g)
2NO(g)
At 2000°C, the equilibrium constant, Kc, has a value of 4.10 × 10-4. What is the value of Kp?

(Multiple Choice)
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An equilibrium is established in which both the forward (fwd) and the reverse (rev) reactions are elementary. If the equilibrium constant Kc = 1.6 × 10-2 and the rate constant kfwd = 8.0 × 10-7 s-1 what is the value of krev?
(Multiple Choice)
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In order to write the correct mass-action expression for a reaction one must
(Multiple Choice)
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Hydrogen sulfide will react with water as shown in the following reactions. H2S(g) + H2O(l)
H3O+(aq) + HS-(aq) K1 = 1.0 × 10-7
HS-(aq) + H2O(l)
H3O+(aq) + S2-(aq) K2 = ?
H2S(g) + 2H2O(l)
2H3O+(aq) + S2-(aq) K3 = 1.3 × 10-20
What is the value of K2?



(Multiple Choice)
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A container was charged with hydrogen, nitrogen, and ammonia gases at 120°C and the system was allowed to reach equilibrium. What will happen if the volume of the container is increased at constant temperature? 3H2(g) + N2(g)
2NH3(g)

(Multiple Choice)
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At 25°C, the equilibrium constant Kc for the reaction 2A(g)
B(g) + C(g)
Is 0.035. A mixture of 8.00 moles of B and 12.00 moles of C in a 20.0 L container is allowed to come to equilibrium. What is the equilibrium concentration of A?

(Multiple Choice)
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Write the mass-action expression, c, for the following chemical reaction. 2Cu2+(aq) + 4I-(aq)
2CuI(s) + I2(aq)

(Multiple Choice)
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Magnesium carbonate dissociates to magnesium oxide and carbon dioxide at elevated temperatures. MgCO3(s)
MgO(s) + CO2(g)
A reaction vessel contains these compounds in equilibrium at 300°C. What will happen if the volume of the container is reduced by 25% at 300°C?

(Multiple Choice)
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The reaction system POCl3(g)
POCl(g) + Cl2(g)
Is at equilibrium. Which of the following statements describes the behavior of the system if POCl is added to the container?

(Multiple Choice)
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Write the mass-action expression,
c, for the following chemical reaction. Sn2+(aq) + ½O2(g) + 3H2O(l)
SnO2(s) + 2H3O+(aq)


(Multiple Choice)
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Consider the reactions of cadmium with the thiosulfate anion. Cd2+(aq) + S2O32-(aq)
Cd(S2O3)(aq) K1 = 8.3 × 103
Cd(S2O3)(aq) + S2O32-(aq)
Cd(S2O3)22-(aq) K2 = 2.5 × 102
What is the value for the equilibrium constant for the following reaction?
Cd2+(aq) + 2S2O32-(aq)
Cd(S2O3)22-(aq)



(Multiple Choice)
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The equilibrium constant, Kp, for the reaction H2(g) + I2(g)
2HI(g)
Is 55.2 at 425°C. A rigid cylinder at that temperature contains 0.127 atm of hydrogen, 0.134 atm of iodine, and 1.055 atm of hydrogen iodide. Is the system at equilibrium?

(Multiple Choice)
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The reaction system CS2(g) + 4H2(g)
CH4(g) + 2H2S(g)
Is at equilibrium. Which of the following statements describes the behavior of the system if the partial pressure of carbon disulfide is reduced?

(Multiple Choice)
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At 25°C, the equilibrium constant Kc for the reaction 2A(aq)
B(aq) + C(aq)
Is 65. If 2.50 mol of A is added to enough water to prepare 1.00 L of solution, what will the equilibrium concentration of A be?

(Multiple Choice)
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Nitrogen dioxide decomposes according to the reaction 2NO2(g)
2NO(g) + O2(g)
Where Kp = 4.48 × 10-13 at 25°C. What is the value for Kc?

(Multiple Choice)
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