You are given pure samples of ethane,C2H6(g),and toluene,C7H8(l).What prediction would you make concerning their standard molar entropies at 298 K?

A) S°ethane > S°toluene B) S°ethane toluene C) S°ethane $\approx$ (S°toluene) $\div$ 3 D) S°ethane $\approx$ S°toluene E) Since toluene is much more complex than ethane,but ethane is in the gas phase while toluene is a liquid,none of these predictions can be confidently made without further information or calculations. A) S°ethane > S°toluene B) S°ethane toluene C) S°ethane $\approx$ (S°toluene) $\div$ 3 D) S°ethane $\approx$ S°toluene E) Since toluene is much more complex than ethane,but ethane is in the gas phase while toluene is a liquid,none of these predictions can be confidently made without further information or calculations.

Calculate $\Delta$G° for the reaction SiCl4(g)+ 2Mg(s) $\to$ 2MgCl2(s)+ Si(s)

A) 566.60 kJ B) 50.38 kJ C) 25.19 kJ D) -25.19 kJ E) -566.60 kJ A) 566.60 kJ B) 50.38 kJ C) 25.19 kJ D) -25.19 kJ E) -566.60 kJ

Exam 20: Thermodynamics: Entropy, free Energy, and the Direction of Chemical Reactions

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A reaction has a positive value of $\Delta$ H° and a positive value of $\Delta$ S°. Draw a neat,labeled schematic plot to show how $\Delta$ G° (y-axis)will depend on absolute temperature (x-axis).

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Question 21

Consider the following quantities used in thermodynamics: E,H,q,w,S,G.How many of them are state functions?

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Question 22

In which one of these pairs will the entropy of the first substance be greater than that of the second? Assume P and T are the same for each pair,unless stated otherwise.

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Question 23

Which relationship best describes $\Delta$ S° for the following reaction? 8H₂(g)+ S₈(s) $\to$ 8H₂S(g)

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Question 24

Which relationship or statement best describes $\Delta$ S° for the following reaction? O₃(g)+ NO(g) $\to$ O₂(g)+ NO₂(g)

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Question 25

For a chemical reaction to be non-spontaneous at any temperature,which of the following conditions must be met?

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Question 26

Which relationship or statement best describes $\Delta$ S° for the following reaction? BaCl₂(aq)+ Na₂SO₄(aq) $\to$ BaSO₄(s)+ 2NaCl(aq)

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Question 27

In a spontaneous process,the entropy of the system always increases.

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Question 28

Calculate the equilibrium constant at 25°C for the reaction of methane with water to form carbon dioxide and hydrogen.The data refer to 25°C. CH₄(g)+ 2H₂O(g) CO₂(g)+ 4H₂(g)

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Question 29

In order for a process to be spontaneous,

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Question 30

Which relationship or statement best describes $\Delta$ S° for the following reaction? CaO(s)+ CO₂(g) $\to$ CaCO₃(s)

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Question 31

Which of the following should have the greatest molar entropy at 298 K?

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Question 32

You are given pure samples of ethane,C₂H₆(g),and toluene,C₇H₈(l).What prediction would you make concerning their standard molar entropies at 298 K?

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Question 33

As a chemical reaction proceeds toward equilibrium,the free energy of the system decreases.

(True/False)

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Question 34

The higher the pressure of a gas sample,the greater is its entropy.

(True/False)

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Question 35

For a process with $\Delta$ S < 0,which one of the following statements is correct?

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Question 36

Calculate $\Delta$ G° for the reaction SiCl₄(g)+ 2Mg(s) $\to$ 2MgCl₂(s)+ Si(s) $Calculate \Delta G° for the reaction SiCl<sub>4</sub>(g)+ 2Mg(s) \to 2MgCl<sub>2</sub>(s)+ Si(s)$

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Question 37

Which of the following is true for a system at equilibrium?

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Question 38

For any reaction,if $\Delta$ G° > 0,then K < 1.

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Question 39

Compare one mole of ice with one mole of liquid water,both at 1.0 atm and 0°C.The melting point of ice at 1.0 atm is 0°C.For the process H₂O(s) $\to$ H₂O(l) under these conditions predict whether each of the following quantities will be greater than,less than,or equal to,zero .Explain each prediction in one sentence. a. $\Delta$ H° b. $\Delta$ S° c. $\Delta$ G°

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Question 40

Showing 21 - 40 of 84

Exam 20: Thermodynamics: Entropy, free Energy, and the Direction of Chemical Reactions

A reaction has a positive value of Δ\DeltaΔ H° and a positive value of Δ\DeltaΔ S°. Draw a neat,labeled schematic plot to show how Δ\DeltaΔ G° (y-axis)will depend on absolute temperature (x-axis).

Consider the following quantities used in thermodynamics: E,H,q,w,S,G.How many of them are state functions?

In which one of these pairs will the entropy of the first substance be greater than that of the second? Assume P and T are the same for each pair,unless stated otherwise.

Which relationship best describes Δ\DeltaΔ S° for the following reaction? 8H2(g)+ S8(s) →\to→ 8H2S(g)

Which relationship or statement best describes Δ\DeltaΔ S° for the following reaction? O3(g)+ NO(g) →\to→ O2(g)+ NO2(g)

For a chemical reaction to be non-spontaneous at any temperature,which of the following conditions must be met?

Which relationship or statement best describes Δ\DeltaΔ S° for the following reaction? BaCl2(aq)+ Na2SO4(aq) →\to→ BaSO4(s)+ 2NaCl(aq)

In a spontaneous process,the entropy of the system always increases.

Calculate the equilibrium constant at 25°C for the reaction of methane with water to form carbon dioxide and hydrogen.The data refer to 25°C. CH4(g)+ 2H2O(g) CO2(g)+ 4H2(g)

In order for a process to be spontaneous,

Which relationship or statement best describes Δ\DeltaΔ S° for the following reaction? CaO(s)+ CO2(g) →\to→ CaCO3(s)

Which of the following should have the greatest molar entropy at 298 K?

You are given pure samples of ethane,C2H6(g),and toluene,C7H8(l).What prediction would you make concerning their standard molar entropies at 298 K?

As a chemical reaction proceeds toward equilibrium,the free energy of the system decreases.

The higher the pressure of a gas sample,the greater is its entropy.

For a process with Δ\DeltaΔ S < 0,which one of the following statements is correct?

Calculate Δ\DeltaΔ G° for the reaction SiCl4(g)+ 2Mg(s) →\to→ 2MgCl2(s)+ Si(s)

Which of the following is true for a system at equilibrium?

For any reaction,if Δ\DeltaΔ G° > 0,then K < 1.

Keys to the Study of Chemistry

The Components of Matter

Stoichiometry of Formulas and Equations

Three Major Classes of Chemical Reactions

Gases and the Kinetic-Molecular Theory

Thermochemistry: Energy Flow and Chemical Change

Quantum Theory and Atomic Structure

Electron Configuration and Chemical Periodicity

Models of Chemical Bonding

The Shapes of Molecules

Theories of Covalent Bonding

Intermolecular Forces: Liquids,solids,and Phase Changes

The Properties of Solutions

The Main-Group Elements: Applying Principles of Bonding and Structure

Organic Compounds and the Atomic Properties of Carbon

Kinetics: Rates and Mechanisms of Chemical Reactions

Equilibrium: the Extent of Chemical Reactions

Acid-Base Equilibria

Ionic Equilibria in Aqueous Systems

Electrochemistry: Chemical Change and Electrical Work

The Transition Elements and Their Coordination Compounds

Nuclear Reactions and Their Applications

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A reaction has a positive value of $\Delta$ H° and a positive value of $\Delta$ S°. Draw a neat,labeled schematic plot to show how $\Delta$ G° (y-axis)will depend on absolute temperature (x-axis).

Which relationship best describes $\Delta$ S° for the following reaction? 8H₂(g)+ S₈(s) $\to$ 8H₂S(g)

Which relationship or statement best describes $\Delta$ S° for the following reaction? O₃(g)+ NO(g) $\to$ O₂(g)+ NO₂(g)

Which relationship or statement best describes $\Delta$ S° for the following reaction? BaCl₂(aq)+ Na₂SO₄(aq) $\to$ BaSO₄(s)+ 2NaCl(aq)

Calculate the equilibrium constant at 25°C for the reaction of methane with water to form carbon dioxide and hydrogen.The data refer to 25°C. CH₄(g)+ 2H₂O(g) CO₂(g)+ 4H₂(g)

Which relationship or statement best describes $\Delta$ S° for the following reaction? CaO(s)+ CO₂(g) $\to$ CaCO₃(s)

You are given pure samples of ethane,C₂H₆(g),and toluene,C₇H₈(l).What prediction would you make concerning their standard molar entropies at 298 K?

For a process with $\Delta$ S < 0,which one of the following statements is correct?

Calculate $\Delta$ G° for the reaction SiCl₄(g)+ 2Mg(s) $\to$ 2MgCl₂(s)+ Si(s) $Calculate \Delta G° for the reaction SiCl<sub>4</sub>(g)+ 2Mg(s) \to 2MgCl<sub>2</sub>(s)+ Si(s)$

For any reaction,if $\Delta$ G° > 0,then K < 1.