Exam 17: Equilibrium: the Extent of Chemical Reactions

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a. State Le Chatelier's principle b. The following reaction is at equilibrium in a closed container: 2Fe(OH)3(s) a. State Le Chatelier's principle b. The following reaction is at equilibrium in a closed container: 2Fe(OH)<sub>3</sub>(s)   Fe<sub>2</sub>O<sub>3</sub>(s) + 3H<sub>2</sub>O(g) <font face=symbol></font>H°<sub>rxn</sub> > 0 What effects, if any, will the following actions have on the position of equilibrium? In each case, state the direction of any shift in equilibrium, and give your reasons in one sentence. (i) adding more Fe(OH)<sub>3</sub> (ii) raising the temperature (iii) adding a catalyst Fe2O3(s) + 3H2O(g) rxn > 0 What effects, if any, will the following actions have on the position of equilibrium? In each case, state the direction of any shift in equilibrium, and give your reasons in one sentence. (i) adding more Fe(OH)3 (ii) raising the temperature (iii) adding a catalyst

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Consider the equilibrium: A(s) Consider the equilibrium: A(s)   B(s) + C(g) <font face=symbol></font>H°<sub>rxn</sub> > 0 Predict and explain how or whether the following actions would affect this equilibrium. a. adding more solid A b. lowering the temperature c. increasing the pressure on the system by reducing its volume d. adding helium gas to increase the total pressure B(s) + C(g) rxn > 0 Predict and explain how or whether the following actions would affect this equilibrium. a. adding more solid A b. lowering the temperature c. increasing the pressure on the system by reducing its volume d. adding helium gas to increase the total pressure

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The following reaction is at equilibrium in a sealed container. N2(g) + 3H2(g) The following reaction is at equilibrium in a sealed container. N<sub>2</sub>(g) + 3H<sub>2</sub>(g)   2NH<sub>3</sub>(g) <font face=symbol></font>H°<sub>rxn</sub> < 0 Which, if any, of the following actions will increase the value of the equilibrium constant, K<sub>c</sub>? 2NH3(g) rxn < 0 Which, if any, of the following actions will increase the value of the equilibrium constant, Kc?

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In order to write the correct mass-action expression for a reaction one must

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The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N2(g) + O2(g) The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N<sub>2</sub>(g) + O<sub>2</sub>(g)   2NO(g) At 2000°C, the equilibrium constant, K<sub>c </sub>, has a value of 4.10 × 10<sup>-4</sup>. What is the value of K<sub>p</sub>? 2NO(g) At 2000°C, the equilibrium constant, Kc , has a value of 4.10 × 10-4. What is the value of Kp?

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Consider the equilibrium reaction: H2(g) + Br2(g) Consider the equilibrium reaction: H<sub>2</sub>(g) + Br<sub>2</sub>(g)   2HBr(g) Which of the following correctly describes the relationship between K<sub>c</sub> and K<sub>p</sub> for the reaction? 2HBr(g) Which of the following correctly describes the relationship between Kc and Kp for the reaction?

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Which of the following has an effect on the magnitude of the equilibrium constant?

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The reaction quotient for a gas phase reaction has a value of 2000. If the number of moles of reactants in the reaction equation is equal to that of the products, which of the following statements is definitely true?

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For a gas-phase equilibrium, a change in the pressure of any single reactant or product will affect the amounts of other substances involved in the equilibrium.

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The reaction system POCl3(g) The reaction system POCl<sub>3</sub>(g)   POCl(g) + Cl<sub>2</sub>(g) Is at equilibrium. Which of the following statements describes the behavior of the system if POCl is added to the container? POCl(g) + Cl2(g) Is at equilibrium. Which of the following statements describes the behavior of the system if POCl is added to the container?

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Once a reaction system reaches equilibrium, the concentrations of reactions and products no longer change.

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A container was charged with hydrogen, nitrogen, and ammonia gases at 120°C and the system was allowed to reach equilibrium. What will happen if the volume of the container is increased at constant temperature? 3H2(g) + N2(g) A container was charged with hydrogen, nitrogen, and ammonia gases at 120°C and the system was allowed to reach equilibrium. What will happen if the volume of the container is increased at constant temperature? 3H<sub>2</sub>(g) + N<sub>2</sub>(g)   2NH<sub>3</sub>(g) 2NH3(g)

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Write the mass-action expression, Qc , for the following chemical reaction. MgO(s) + SO2(g) + Write the mass-action expression, Q<sub>c </sub>, for the following chemical reaction. MgO(s) + SO<sub>2</sub>(g) +   O<sub>2</sub>(g)   MgSO<sub>4</sub>(s) O2(g) Write the mass-action expression, Q<sub>c </sub>, for the following chemical reaction. MgO(s) + SO<sub>2</sub>(g) +   O<sub>2</sub>(g)   MgSO<sub>4</sub>(s) MgSO4(s)

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Methanol can be synthesized by combining carbon monoxide and hydrogen. CO(g) + 2H2(g) Methanol can be synthesized by combining carbon monoxide and hydrogen. CO(g) + 2H<sub>2</sub>(g)   CH<sub>3</sub>OH(g) <font face=symbol></font>H°<sub>rxn</sub> = -90.7 kJ A reaction vessel contains these compounds at equilibrium. What effect will be seen when equilibrium is re-established after decreasing the temperature by 45°C? CH3OH(g) rxn = -90.7 kJ A reaction vessel contains these compounds at equilibrium. What effect will be seen when equilibrium is re-established after decreasing the temperature by 45°C?

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At 25°C, the equilibrium constant Kc for the reaction 2A(aq) At 25°C, the equilibrium constant K<sub>c</sub> for the reaction 2A(aq)   B(aq) + C(aq) Is 65. If 2.50 mol of A is added to enough water to prepare 1.00 L of solution, what will the equilibrium concentration of A be? B(aq) + C(aq) Is 65. If 2.50 mol of A is added to enough water to prepare 1.00 L of solution, what will the equilibrium concentration of A be?

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N2(g) + O2(g) N<sub>2</sub>(g) + O<sub>2</sub>(g)   <sub> </sub> 2NO(g) K<sub>c</sub> = 4.8 × 10<sup>-31</sup> 2NOBr(g)   <sub> </sub> 2NO(g) + Br<sub>2</sub>(g) K<sub>c</sub> = 0.50 Given the above equilibrium constant data at 25 °C, what is the value of K<sub>c</sub> at this temperature for the reaction 2NOBr(g)   <sub> </sub> N<sub>2</sub>(g) + O<sub>2</sub>(g) + Br<sub>2</sub>(g)? 2NO(g) Kc = 4.8 × 10-31 2NOBr(g) N<sub>2</sub>(g) + O<sub>2</sub>(g)   <sub> </sub> 2NO(g) K<sub>c</sub> = 4.8 × 10<sup>-31</sup> 2NOBr(g)   <sub> </sub> 2NO(g) + Br<sub>2</sub>(g) K<sub>c</sub> = 0.50 Given the above equilibrium constant data at 25 °C, what is the value of K<sub>c</sub> at this temperature for the reaction 2NOBr(g)   <sub> </sub> N<sub>2</sub>(g) + O<sub>2</sub>(g) + Br<sub>2</sub>(g)? 2NO(g) + Br2(g) Kc = 0.50 Given the above equilibrium constant data at 25 °C, what is the value of Kc at this temperature for the reaction 2NOBr(g) N<sub>2</sub>(g) + O<sub>2</sub>(g)   <sub> </sub> 2NO(g) K<sub>c</sub> = 4.8 × 10<sup>-31</sup> 2NOBr(g)   <sub> </sub> 2NO(g) + Br<sub>2</sub>(g) K<sub>c</sub> = 0.50 Given the above equilibrium constant data at 25 °C, what is the value of K<sub>c</sub> at this temperature for the reaction 2NOBr(g)   <sub> </sub> N<sub>2</sub>(g) + O<sub>2</sub>(g) + Br<sub>2</sub>(g)? N2(g) + O2(g) + Br2(g)?

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A mixture of 0.600 mol of bromine and 1.600 mol of iodine is placed into a rigid 1.000-L container at 350°C. Br2(g) + I2(g) A mixture of 0.600 mol of bromine and 1.600 mol of iodine is placed into a rigid 1.000-L container at 350°C. Br<sub>2</sub>(g) + I<sub>2</sub>(g)   2IBr(g) When the mixture has come to equilibrium, the concentration of iodine monobromide is 1.190 M. What is the equilibrium constant for this reaction at 350°C? 2IBr(g) When the mixture has come to equilibrium, the concentration of iodine monobromide is 1.190 M. What is the equilibrium constant for this reaction at 350°C?

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The equilibrium constant, Kp, has a value of 6.5 × 10-4 at 308 K for the reaction of nitrogen monoxide with chlorine. 2NO(g) + Cl2(g) The equilibrium constant, K<sub>p</sub>, has a value of 6.5 × 10<sup>-4</sup> at 308 K for the reaction of nitrogen monoxide with chlorine. 2NO(g) + Cl<sub>2</sub>(g)   2NOCl(g) What is the value of K<sub>c</sub>? 2NOCl(g) What is the value of Kc?

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The reaction system POCl3(g) The reaction system POCl<sub>3</sub>(g)   POCl(g) + Cl<sub>2</sub>(g) Is at equilibrium. Which of the following statements describes the behavior of the system if the partial pressure of chlorine is reduced by 50%? POCl(g) + Cl2(g) Is at equilibrium. Which of the following statements describes the behavior of the system if the partial pressure of chlorine is reduced by 50%?

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The Haber process for ammonia synthesis is exothermic: N2(g) + 3H2(g) The Haber process for ammonia synthesis is exothermic: N<sub>2</sub>(g) + 3H<sub>2</sub>(g)   2NH<sub>3</sub>(g) <font face=symbol></font>H° = -92 kJ If the equilibrium constant K<sub>c</sub> for this process at 500.°C is 6.0 × 10<sup>-2</sup>, what is its value at 300.°C? 2NH3(g) H° = -92 kJ If the equilibrium constant Kc for this process at 500.°C is 6.0 × 10-2, what is its value at 300.°C?

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