Exam 23: The Transition Elements and Their Coordination Compounds

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Consider the following structures (1 and 2 are octahedral; 3 and 4 are square planar). Consider the following structures (1 and 2 are octahedral; 3 and 4 are square planar).   Which one of the following statements about the above structures is correct? Which one of the following statements about the above structures is correct?

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The ground state electronic configuration of Cr2+ is

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If M represents a transition element, which of the following oxides should be the least basic?

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Which of the following transition elements can have an oxidation number of +7?

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Which of the following ions could exist in only the high-spin state in an octahedral complex?

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The compound K3[Fe(CN)6] is used in calico printing and wool dyeing. Give its systematic name.

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Why is the +2 oxidation state so common among transition elements?

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What is the highest possible oxidation state for molybdenum, Mo?

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According to valence bond theory, what would be the set of hybrid orbitals used when a Period 4 transition metal forms a square planar complex?

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According to Valence Bond theory, in the square planar Ni(CN)42- complex ion, the orbital hybridization pattern is

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According to valence bond theory, what would be the set of hybrid orbitals used when a Period 4 transition metal forms a tetrahedral complex?

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In the spectrochemical series, which one of the following ligands has the strongest field?

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Aluminum reacts with oxygen in the air to form a protective oxide coating. Silver also reacts with compounds in air to form a black coating. What substance is formed?

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Which of the following ions is most likely to form colored compounds?

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All atoms of the first transition series of elements have the ground state electronic configuration [Ar]4s23dx, where x is an integer from 1 to 10.

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How many unpaired electrons are there in the Fe3+ ion?

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The dxy and the dx2-y2 orbitals both lie in the xy plane, yet for a metal ion in an octahedral complex the energy of the dxy orbital is lower than that of the dx2-y2orbital. Explain this using the arguments of crystal field theory.

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The most common oxidation state for ions of the transition elements is

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Which of the following will be diamagnetic?

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All the actinide series of transition elements are radioactive.

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