Exam 14: Solutions and Their Behavior

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The Henry's law constant for O2 in water at 25 °C is 1.3 × 10-3 mol/kg⋅bar.What partial pressure of O2 (in atm)is necessary to achieve an equilibrium concentration of 2.9 × 10-3 mol/kg O2? (1 atm = 0.9869 bar)

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What is the mass percent of an aqueous sodium hydroxide solution in which the molality of NaOH is 10.7 m?

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What is the osmotic pressure of an aqueous solution that is 0.46% NaCl by weight at 36°C.Assume the density of the solution is 1.0 g/mL.Assume no ion pairing.(R = 0.0821 L · atm/K·mol)

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What is the freezing point of a solution containing 2.80 grams benzene (molar mass = 78.11 g/mol)dissolved in 43.0 grams paradichlorobenzene (molar mass = 147.0 g/mol)? The freezing point of pure paradichlorobenzene is 53.0 °C and the freezing point depression constant,Kfp,is -7.10 °C/m.

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If the solubility of O2 at 0.300 bar and 25°C is 12.5 g/100 g H2O,what is the solubility of O2 at a pressure of 1.64 bar and 25°C?

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Because ________ particles are relatively large (say,1000 nm in diameter)they scatter visible light,making the mixtures containing these particles appear cloudy.This scattering is known as the Tyndall effect.

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For the following gas-liquid equilibrium for an aqueous system at a constant partial pressure of CO2, CO2(g) D CO2(aq) What is the effect on the equilibrium composition of the liquid when the temperature of the liquid is increased?

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The standard enthalpy of formation of RbF(s)is -557.7kJ/mol and the standard enthalpy of formation of RbF(aq,1 m)is -583.8 kJ/mol.Determine the enthalpy of solution of RbF and indicate whether the solution temperature will increase or decrease when RbF is dissolved in water.

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What is the mole fraction of urea,CO(NH2)2,in a solution prepared by dissolving 4.8 g of urea in 30.3 g of methanol,CH3OH?

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A 15 meter by 12 meter pool of water has a depth of 2.2 meters.What mass of silver ion is present in the reservoir if the concentration of silver ion is 0.14 ppm? (1 m3 = 1000 L; assume the density of the solution is 1.00 g/mL)

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A surfactant used for cleaning is called a(n)________.

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The vapor pressure of pure water at 15 °C is 12.8 mm Hg.What is the equilibrium vapor pressure of water above a mixture of 72.0 g ethanol (CH3CH2OH,molar mass = 46.07 g/mol)and 22.0 g water?

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What mass of Zn(NO3)2 must be diluted to a mass of 1.00 kg with H2O to prepare 97 ppm Zn2+(aq)?

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Two nonpolar solvents,such as hexane and carbon tetrachloride,may be miscible even though the enthalpy of mixing of these liquids might be small.A reason that mixing occurs is that mixtures have a greater dispersal of energy relative to pure solvents.The tendency toward greater dispersal of energy is a thermodynamic function called ____.

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How many milliliters of 11.7 M H2SO4 are needed to prepare 600.0 mL of 0.10 M H2SO4?

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A 12.0% sucrose solution by mass has a density of 1.05 g/cm3.What mass of sucrose is present in a 53.0-mL sample of this solution?

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What is the mole fraction of calcium chloride in 3.35 m CaCl2(aq)? The molar mass of CaCl2 is 111.0 g/mol and the molar mass of water is 18.02 g/mol.

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A solution in which there is more dissolved solute than in a saturated solution is known as a(n)________ solution.

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The following equation is known as ________ law: The following equation is known as ________ law:   . .

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What type of colloid is formed when a liquid is dispersed in a gas?

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