Exam 14: Solutions and Their Behavior

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A solution is prepared by dissolving 5.88 g of an unknown nonelectrolyte in enough water to make 0.355 L of solution.The osmotic pressure of the solution is 1.21 atm at 27 °C.What is the molar mass of the solute? (R = 0.08206 L⋅atm/mol⋅K)

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For the following gas-aqueous liquid equilibrium for a closed system at a constant temperature, N2(g) D N2(aq) What is the effect on the equilibrium composition of the liquid when the partial pressure of N2 gas above the liquid is decreased?

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What is the definition of molality?

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If an egg's shell is carefully dissolved using an acid,the egg white and yolk will remain intact inside a membrane.If the egg is then placed in distilled water,it will slowly expand until it bursts.Why?

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A 3.0 g sample of a small protein having a molecular weight of 42,000 g/mol is dissolved in 52.8 mL of water at 21°C.What is the osmotic pressure of the solution? (R = 0.0821 L · atm/K·mol,1 atm = 760 mmHg)

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If a 15.6-g sample of a nonelectrolyte is dissolved in 100.0 g of water,the resulting solution will freeze at -0.93°C.What is the molar mass of the nonelectrolyte? (Kfp for water is 1.858°C/m.)

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Which of the following favor(s)the solubility of an ionic solid in a liquid solvent?

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If 27.9 g LiCl is dissolved in 175 g H2O,what is the weight percent of LiCl in the solution?

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What partial pressure of oxygen gas is required in order for 0.00284 g of the gas to dissolve in 15.9 mL of pure water? The Henry's law constant for oxygen gas is 1.3 × 10-3 M atm-1.

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What is the vapor pressure at 20°C of an ideal solution prepared by the addition of 4.50 g of the nonvolatile solute urea,CO(NH2)2,to 22.7 g of methanol,CH3OH? The vapor pressure of pure methanol at 20°C is 89.0 mmHg.

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A concentrated nitric acid solution has a density of 1.41 g/mL at 25°C and is 15.8 M.What is the percent by mass of HNO3 in the solution?

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Which of the following statements about soaps and detergents is false?

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The solubility of 1-pentanol in water is 2.7 g per 100 g of water at 25°C.What is the maximum amount of 1-pentanol that will dissolve in 2.1 g of water at 25°C?

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What is the boiling-point change for a solution containing 0.251 mol of naphthalene (a nonvolatile,nonionizing compound)in 250.g of liquid benzene? (Kbp = 2.53°C/m for benzene)

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The vapor pressure of water at 90°C is 0.692 atm.What is the vapor pressure (in atm)of a solution made by dissolving 2.91 mole(s)of CsF(s)in 1.00 kg of water? Assume that Raoult's law applies.

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If the concentration of sodium carbonate in water is 12.8 ppm,what is the molarity of Na2CO3(aq)? The molar mass of Na2CO3 is 106.0 g/mol.Assume the density of the solution is 1.00 g/mL.

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Which of the following equations illustrates the formation of an aqueous solution of KF from its elements in their standard states?

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Henry's law states that the solubility of a gas in a liquid is directly proportional to its pressure above the liquid.This law holds accurate for gases such as nitrogen and oxygen.However,Henry's law does not hold accurate for hydrogen chloride gas.Why?

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Colloids represent a state intermediate between a solution and a suspension.

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