Exam 17: Principles of Chemical Reactivity: Other Aspects of Aqueous Equilibria

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How many moles of HCl must be added to 1.0 L of 1.0 M NH3(aq)to make a buffer with a pH of 9.00? (pKa of NH4+ = 9.25)

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Which of the following mathematical expressions is the Henderson-Hasselbalch equation?

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Given the two equilibria below, Ag(NH3)2+(aq) Given the two equilibria below, Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq)+ 2NH<sub>3</sub>(aq); K<sub>d</sub> = 5.9 × 10<sup>-8</sup> AgCN(s)   Ag<sup>+</sup>(aq)+ CN−(aq); K<sub>sp</sub> =   what is K for the following equilibrium? AgCN(s)+ 2NH<sub>3</sub>(aq)   Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq)+ CN<sup>-</sup>(aq) Ag+(aq)+ 2NH3(aq); Kd = 5.9 × 10-8 AgCN(s) Given the two equilibria below, Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq)+ 2NH<sub>3</sub>(aq); K<sub>d</sub> = 5.9 × 10<sup>-8</sup> AgCN(s)   Ag<sup>+</sup>(aq)+ CN−(aq); K<sub>sp</sub> =   what is K for the following equilibrium? AgCN(s)+ 2NH<sub>3</sub>(aq)   Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq)+ CN<sup>-</sup>(aq) Ag+(aq)+ CN−(aq); Ksp = Given the two equilibria below, Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq)+ 2NH<sub>3</sub>(aq); K<sub>d</sub> = 5.9 × 10<sup>-8</sup> AgCN(s)   Ag<sup>+</sup>(aq)+ CN−(aq); K<sub>sp</sub> =   what is K for the following equilibrium? AgCN(s)+ 2NH<sub>3</sub>(aq)   Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq)+ CN<sup>-</sup>(aq) what is K for the following equilibrium? AgCN(s)+ 2NH3(aq) Given the two equilibria below, Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq)+ 2NH<sub>3</sub>(aq); K<sub>d</sub> = 5.9 × 10<sup>-8</sup> AgCN(s)   Ag<sup>+</sup>(aq)+ CN−(aq); K<sub>sp</sub> =   what is K for the following equilibrium? AgCN(s)+ 2NH<sub>3</sub>(aq)   Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq)+ CN<sup>-</sup>(aq) Ag(NH3)2+(aq)+ CN-(aq)

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Which of the following is the common name for iron(II)carbonate?

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What is the pH of a solution that is 0.044 M in HA and also 0.0044 M in NaA? (Ka = 4.7 × 10-6)

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If the ratio of acid to base in a buffer is increased by a factor of 10,the buffer pH decreases by ________.

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What is the molar solubility of Mn(OH)2(s)in a solution that is buffered at pH 8.00 at 25 °C? The Ksp of Mn(OH)2 is 1.9 × 10-13 at 25 °C.

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Consider the titration of 300.0 mL of 0.414 M NH3 (Kb = 1.8 ×10-5)with 0.500 M HNO3.After 150.0 mL HNO3 has been added,what is the pH of the solution?

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What is the value of the dissociation constant,Kdissociation,for the complex ion Zn(NH3)42+? (Kf = 2.9 × 109)

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A 50.0 mL sample of 0.155 M HNO2(aq)is titrated with 0.100 M NaOH(aq).What is the pH of a solution after the addition of 25.0 mL of NaOH? (Ka of HNO2 = 4.5 × 10-4)

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The Ksp of BaSO4 is 1.1 × 10-10 at 25 °C.What mass of BaSO4 will dissolve in 1.0 L of water at 25 °C? (molar mass = 233.4 g/mol)

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What is the molar solubility of solid iron(III)hydroxide,Fe(OH)3,in a solution that is buffered to a pH of 2.50 at 25 °C? The Ksp of Fe(OH)3 is 6.3 × 10-38 at 25 °C.

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The Ksp of Ca(OH)2 is 5.5 × 10-5 at 25 °C.What is the concentration of OH-(aq)in a saturated solution of Ca(OH)2(aq)?

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What color change is exhibited by phenolphthalein during a titration of aqueous acetic acid with aqueous sodium hydroxide?

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The solubility of strontium carbonate (SrCO3)in water at 25°C is The solubility of strontium carbonate (SrCO<sub>3</sub>)in water at 25°C is   g/L.What is the K<sub>sp</sub> of this sparingly soluble salt? g/L.What is the Ksp of this sparingly soluble salt?

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If 25 mL of 0.10 M NaOH is added to 40 mL of 0.20 M HC2H3O2,what is the pH of the resulting solution at 25°C? Ka for HC2H3O2 is 1.8 × 10-5 at 25°C.

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​Given the following equilibrium constants, Zn4IO3)2 Ksp = ​Given the following equilibrium constants, Zn4IO<sub>3</sub>)<sub>2</sub> K<sub>sp</sub> =   Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup> K<sub>f</sub> =   determine K for the dissolution of the sparingly soluble salt Zn(IO<sub>3</sub>)<sub>2</sub> in aqueous ammonia (shown below). Zn(IO<sub>3</sub>)<sub>2</sub>(s)+ 4NH<sub>3</sub>(aq)⇌ Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup>(aq)+ 2IO<sub>3</sub><sup>-</sup>(aq) Zn(NH3)42+ Kf = ​Given the following equilibrium constants, Zn4IO<sub>3</sub>)<sub>2</sub> K<sub>sp</sub> =   Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup> K<sub>f</sub> =   determine K for the dissolution of the sparingly soluble salt Zn(IO<sub>3</sub>)<sub>2</sub> in aqueous ammonia (shown below). Zn(IO<sub>3</sub>)<sub>2</sub>(s)+ 4NH<sub>3</sub>(aq)⇌ Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup>(aq)+ 2IO<sub>3</sub><sup>-</sup>(aq) determine K for the dissolution of the sparingly soluble salt Zn(IO3)2 in aqueous ammonia (shown below). Zn(IO3)2(s)+ 4NH3(aq)⇌ Zn(NH3)42+(aq)+ 2IO3-(aq)

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Which acid-base combination is depicted by this titration curve? The dot on the curve is located at the titrant volume where the titration solution pH equals 7. Which acid-base combination is depicted by this titration curve? The dot on the curve is located at the titrant volume where the titration solution pH equals 7.

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What is the minimum concentration of Cd2+ required to begin precipitating Cd(OH)2(s)in a solution buffered at pH 10.83? The Ksp of Cd(OH)2 is 5.3 × 10-15 and Kw = 1.01 × 10-14.

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How many moles of solid NaF would have to be added to 1.0 L of 1.85 M HF solution to achieve a buffer of pH 3.35? Assume there is no volume change.(Ka for HF = 7.2 × 10-4)

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