Exam 16: Aqueous Ionic Equilibrium

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A 25.0 mL sample of 0.150 mol L-1 butanoic acid is titrated with a 0.150 mol L-1 NaOH solution. What is the pH after 13.3 mL of base is added? The A 25.0 mL sample of 0.150 mol L<sup>-1</sup> butanoic acid is titrated with a 0.150 mol L<sup>-1</sup> NaOH solution. What is the pH after 13.3 mL of base is added? The   of butanoic acid is 1.5 × 10<sup>-5</sup>. of butanoic acid is 1.5 × 10-5.

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Define buffer capacity.

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Identify the expression for the solubility product constant for PbCl2.

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Describe the information necessary (and why) to choose a good indicator for a weak acid-strong base titration.

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Which of the following is the correct equation relating Q to Ksp for a supersaturated solution?

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For a strong acid titrated with a strong base, is the equivalence point acidic, basic, or neutral?

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A 100.0 mL sample of 0.18 mol L-1 HClO4 is titrated with 0.27 mol L-1 NaOH. Determine the pH of the solution after the addition of 66.67 mL of NaOH (this is the equivalence point).

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A 1.00 L buffer solution is 0.250 mol L-1 in HF and 0.250 mol L-1 in LiF. Calculate the pH of the solution after the addition of 0.150 moles of solid LiOH. Assume no volume change upon the addition of the base. The Ka for HF is 3.5 × 10-4.

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What is the pH at the equivalence point of a weak base-strong acid titration if 20.00 mL of NaOCl requires 28.30 mL of 0. 50 mol L-1 HCl for complete neutralization? Ka = 3.0 × 10-8 for HOCl.

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The molar solubility of Ag2S is 1.26 × 10-16 mol L-1 in pure water. Calculate the Ksp for Ag2S.

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A 25.0 mL sample of 0.150 mol L-1 acetic acid is titrated with a 0.150 mol L-1 NaOH solution. What is the pH after 26.0 mL of base is added? The A 25.0 mL sample of 0.150 mol L<sup>-1 </sup>acetic acid is titrated with a 0.150 mol L<sup>-1</sup> NaOH solution. What is the pH after 26.0 mL of base is added? The   of acetic acid is 1.8 × 10<sup>-5</sup>. of acetic acid is 1.8 × 10-5.

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A 100.0 mL sample of 0.10 mol L-1 NH3 is titrated with 0.10 mol L-1 HNO3. Determine the pH of the solution after the addition of 200.0 mL of HNO3. The Kb of NH3 is 1.8 × 10-5.

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You wish to prepare a buffer containing CH3COOH with a pH of 4.24. If the pKa of acetic acid is 4.74, what ratio of [CH3COO⁻]/[CH3COOH] must you use?

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Which of the following acids (listed with Ka values) and their conjugate base would be the best choice to make a buffer with a pH of 2.34?

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A solution contains 0.021 mol L-1 Cl⁻ and 0.017 mol L-1 I⁻. A solution containing copper(I) ions is added to selectively precipitate one of the ions. At what concentration of copper(I) ion will a precipitate begin to form? What is the identity of the precipitate? Ksp(CuCl) = 1.0 × 10-6, Ksp(CuI) = 5.1 × 10-12.

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What happens at low pH to aluminum hydroxide precipitate?

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Define a buffer.

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A 1.0 L buffer solution is 0.250 mol L-1 CH3COOH and 0.050 mol L-1 CH3COOLi. Which of the following actions will exceed the capacity of the buffer?

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Which of the following acids (listed with Ka values) and their conjugate base would be the best choice to make a buffer with a pH of 8.10?

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A solution contains 0.036 mol L-1 Cu2+ and 0.044 mol L-1 Fe2+. A solution containing sulfide ions is added to selectively precipitate one of the metal ions from solution. At what concentration of sulfide ion will a precipitate begin to form? What is the identity of the precipitate? Ksp(CuS) = 1.3 × 10-36, Ksp(FeS) = 6.3 × 10-18.

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