Exam 17: Solubility and Complexation Equilibriums

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Incomplete dissociation of a molecular solute that is miscible with water can increase the solubility of the solute.

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Define the ion product of a salt and state the three possible conditions for an aqueous solution of an ionic solid.

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The _____ of a salt is the product of the concentrations of the ions in solution raised to the same powers as in the solubility product expression.

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If the Ksp of AgCl is equal to 3.89×10-10 and the Kf of AgCl2\mathrm { AgCl } _ { 2 } ^ { - } is 2.8×105, what is the equilibrium constant for the reaction?

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Which of the following cations is most likely to form insoluble carbonates?

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Explain the process of determining the solubility product of a salt.

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Silver sulfate (Ag2SO4) has a Ksp of 1.20×10-5 at 25C25 ^ { \circ } \mathrm { C } . If 20.0mL of 0.010M AgNO3 is added to 120mL of 6.75×10-3M Na2SO4, what is the ion product of silver sulfate?

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Which of the following cations is most likely to form insoluble phosphates?

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The reaction of weakly basic anions with H2O tends to make the actual solubility of many salts higher than predicted.

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_____ is a procedure for determining the identity of metal ions present in a mixture, rather than quantitative information about their amounts.

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Consecutive precipitation steps become progressively less selective until almost all of the metal ions are precipitated.

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The concentration of anions in solution can often be controlled by adjusting the pH, thereby allowing the selective precipitation of cations.

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The solubility product of barium sulfate (BaSO4) is 1.08×10-10 at 25C25 ^ { \circ } \mathrm { C } . If 15.0mL of 0.0040M Na2SO4 is added to 125mL of 6.4×10-4M BaCl2, what is the ion product of BaSO4?

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Ag+, Pb2+, and Hg22+ form chlorides that are soluble in water.

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The concentration of a pure solid appears explicitly in the equilibrium constant expression.

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Explain the application of complexing agents in the medical industry.

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Explain the formation of stalactites and stalagmites in caves.

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Which of the following is the chemical equation that describes the dissolution of aluminum hydroxide in an acid?

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How is the solubility of any sparingly soluble salt influenced by the common ion effect?

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A(n) _____ is a spire of limestone that grows upwards from the cave floor in the region where the droplets land when they fall from the ceiling.

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