Exam 17: Solubility and Complexation Equilibriums

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If 13.5g of NiCl2.6H2O is added to 500mL of 1.50M aqueous ammonia, what is the equilibrium concentration of Ni2+(aq)? The complex formed is [Ni(NH3)6]2+\left[ \mathrm { Ni } \left( \mathrm { NH } _ { 3 } \right) _ { 6 } \right] ^ { 2 + } Given Kf = 5.5×108.

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If the Ksp for AgCl is equal to 4.65×10-9 and the Kf for AgCl2\mathrm { AgCl } _ { 2 } ^ { - } is equal to 8.7×105 at 35C35 ^ { \circ } \mathrm { C } , what is the solubility of AgCl in pure water at the same temperature?

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If the Ksp for Ca3(PO4)2 at 30C30 ^ { \circ } \mathrm { C } is 6.47×10-32, what is the aqueous solubility of Ca3(PO4)2 in terms of the mass of salt that dissolves in 100mL of water at the same temperature?

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The ion product describes concentrations that are not necessarily equilibrium concentrations.

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Adding a(n) _____ to detergents prevents the magnesium and calcium salts from precipitating because the equilibrium constant for complex-ion formation is large.

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