Exam 9: Molecular Structure

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What is the major type of force that must be overcome to allow each of the processes below? I. the evaporation of propanal (CH3CH2CH2OH) II. the boiling of liquid CH2Cl2 III. the melting of solid Br2 IV. the boiling of liquid BF3

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Which of the molecules below undergo extensive hydrogen bonding? Which of the molecules below undergo extensive hydrogen bonding?

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Which has the smallest bond angle?

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Which does not provide visual insight into the three-dimensional structure of a molecule?

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Which best describes the nature of the Si to Si bonds in a disilyne (Si2H2)?

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Which statement about a central atom that has six electron pairs is false?

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Which description of a pi bond is false?

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What is the major type of force that must be overcome to allow the boiling of carbon tetrachloride?

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London forces exist

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Use the VSEPR model to predict the X-A-X angles for the following compounds: CO2, GeF4, BCl3.

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Use the VSEPR model to predict the electron-pair geometry, the molecular geometry, and the smallest approximate F-Cl-F bond angle of ClF3.

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Samples of which substance experience only London intermolecular forces?

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Label the hybridization at C#1, C#2, C#3, and C#4 in the molecule. Label the hybridization at C#1, C#2, C#3, and C#4 in the molecule.   C1 C2 C3 C4 C1 C2 C3 C4

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Use the VSEPR model to predict the electron-pair geometry and the molecular geometry of CO2.

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Use the VSEPR model to predict the electron-pair geometry and bond angles of PF4+.

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Use the VSEPR model to predict the electron-pair geometry and the O-C-O bond angles for CO32-.

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The carbon-carbon bond in ethane, CH3CH3, results from the overlap of which of the following?

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Which accurately describes a molecule with all polar bonds?

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For which molecule will the electron-pair geometry be different than the molecular geometry?

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In a molecule with triangular bipyramidal electron-pair geometry, where are any lone pairs on the central atom preferentially placed?

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