Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions

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If 35.0 g H2O at 22.7 \circ C is combined with 65.0 g H2O at 87.5 \circ C,what is the final temperature of the mixture? The specific heat capacity of water is 4.184 J/g.K.

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When 10.0 g KOH is dissolved in 100.0 g of water in a coffee-cup calorimeter,the temperature rises from 25.18 \circ C to 47.53 \circ C.What is the enthalpy change per gram of KOH dissolved in the water? Assume that the solution has a specific heat capacity of 4.18 J/g.K.

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In thermodynamics,a(n)________ is defined as the object,or collection of objects,being studied.The surroundings include everything else.

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If 46.1 g Cu at 11.6 \circ C is placed in 85.0 g H2O at 72.4 \circ C,what is the final temperature of the mixture? The specific heat capacities of copper and water are 0.385 J/g.K and 4.184 J/g.K,respectively.

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Which of the following statements is/are CORRECT? 1)A system is defined as an object or collection of objects being studied. 2)Surroundings are defined as the entire universe,including the system. 3)In an endothermic reaction,heat is transferred from the system to the surroundings.

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The thermochemical equation for the combustion of methanol is shown below. CH3OH(  The thermochemical equation for the combustion of methanol is shown below.  CH<sub>3</sub>OH(   )+ 3/2 O<sub>2</sub>(g) \to CO<sub>2</sub>(g)+ 2 H<sub> 2</sub>O(g)  \Delta <sub>r</sub>H<sup> \circ </sup>= -638.7 kJ/mol-rxn What is the enthalpy change for the combustion of 8.59 g CH<sub>3</sub>OH? )+ 3/2 O2(g) \to CO2(g)+ 2 H 2O(g) Δ\Delta rH \circ = -638.7 kJ/mol-rxn What is the enthalpy change for the combustion of 8.59 g CH3OH?

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The energy stored in a fuel is called _____.

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A bomb calorimeter has a heat capacity of 2.47 kJ/K.When a 0.123-g sample of ethylene (C2H4)was burned in this calorimeter,the temperature increased by 2.50 K.Calculate the enthalpy change per mole of ethylene combusted.

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How much heat is liberated at constant pressure if 0.834 g of calcium carbonate reacts with 48.9 mL of 0.668 M hydrochloric acid? CaCO3(s)+ 2HCl(aq) \to CaCl2(aq)+ H2O(l)+ CO2(g); Δ\Delta rH° = -15.2 kJ/mol-rxn

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It is relatively easy to change the temperature of a substance that

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Calculate Δ\Delta rH \circ for the combustion of ammonia, 4 NH3(g)+ 7 O2(g) \to 4 NO2(g)+ 6 H2O(  Calculate  \Delta <sub>r</sub>H<sup> \circ </sup> for the combustion of ammonia, 4 NH<sub>3</sub>(g)+ 7 O<sub>2</sub>(g) \to  4 NO<sub>2</sub>(g)+ 6 H<sub>2</sub>O(   ) Using standard molar enthalpies of formation.   ) Using standard molar enthalpies of formation.  Calculate  \Delta <sub>r</sub>H<sup> \circ </sup> for the combustion of ammonia, 4 NH<sub>3</sub>(g)+ 7 O<sub>2</sub>(g) \to  4 NO<sub>2</sub>(g)+ 6 H<sub>2</sub>O(   ) Using standard molar enthalpies of formation.

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The standard molar enthalpy of formation of NH3(g)is -45.9 kJ/mol.What is the enthalpy change if 9.51 g N2(g)and 1.96 g H2(g)react to produce NH3(g)?

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When 66.0 g of an unknown metal at 28.5 \circ C is placed in 83.0 g H2O at 78.5 \circ C,the water temperature decreases to 75.9 \circ C.What is the specific heat capacity of the metal? The specific heat capacity of water is 4.184 J/g.K.

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CaO(s)reacts with water to form Ca(OH)2(aq).If 6.50 g CaO is combined with 99.70 g H2O in a coffee cup calorimeter,the temperature of the resulting solution increases from 21.7 \circ C to 43.1 \circ C.Calculate the enthalpy change for the reaction per mole of CaO.Assume that the specific heat capacity of the solution is 4.18 J/g.K.

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Many homes are heated using natural gas.The combustion of natural gas converts

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Exactly 212.2 J will raise the temperature of 10.0 g of a metal from 25.0 °C to 60.0 °C.What is the specific heat capacity of the metal?

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Combustion of 7.21 g of liquid benzene (C6H6)causes a temperature rise of 50.3°C in a constant-pressure calorimeter that has a heat capacity of 5.99 kJ/°C.What is Δ\Delta H for the following reaction? C6H6(l)+  Combustion of 7.21 g of liquid benzene (C<sub>6</sub>H<sub>6</sub>)causes a temperature rise of 50.3°C in a constant-pressure calorimeter that has a heat capacity of 5.99 kJ/°C.What is  \Delta H for the following reaction? C<sub>6</sub>H<sub>6</sub>(l)+   O<sub>2</sub>(g) \to  6CO<sub>2</sub>(g)+ 3H<sub>2</sub>O(l) O2(g) \to 6CO2(g)+ 3H2O(l)

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Determine the heat of evaporation of carbon disulfide, Determine the heat of evaporation of carbon disulfide,   Given the enthalpies of reaction below.  Given the enthalpies of reaction below. Determine the heat of evaporation of carbon disulfide,   Given the enthalpies of reaction below.

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The specific heat capacity of copper is 0.384 J/g. \circ C.What is the molar specific heat capacity of this substance? The molar mass of copper is 63.54 g/mol.

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What quantity,in moles,of oxygen is consumed when 369.3 kJ of energy is evolved from the combustion of a mixture of H2(g)and O2(g)? H2(g)+  What quantity,in moles,of oxygen is consumed when 369.3 kJ of energy is evolved from the combustion of a mixture of H<sub>2</sub>(g)and O<sub>2</sub>(g)? H<sub>2</sub>(g)+   O<sub>2</sub>(g) \to H<sub>2</sub>O(l);  \Delta <sub>r</sub>H° = -285.8 kJ/mol-rxn O2(g) \to H2O(l); Δ\Delta rH° = -285.8 kJ/mol-rxn

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