Exam 10: The Shapes of Molecules

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Draw Lewis structures which obey the octet rule, for the following atoms, molecules, and ions, showing all valence electrons. Central atoms are shown in bold. a. NH3 b. O3 (Hint: O3 is not cyclic) c. HCN d. SO3

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Using SO2 as an example, describe the sort of experimental data which might suggest that no single Lewis structure is an accurate representation of its bonding.

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Select the correct Lewis structure for NOCl, a reactive material used as an ionizing solvent.

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Which one of the following molecules contains a double bond?

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Use VSEPR theory to predict the electron group arrangement around iodine, the central atom in the ion IF2-.

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The molecule AX2, where A and X are different elements, will have a dipole moment if the molecule is bent.

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What is the molecular shape of BCl3 as predicted by the VSEPR theory?

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Predict the ideal bond angles around nitrogen in N2F2 using the molecular shape given by the VSEPR theory. (The two N atoms are the central atoms.)

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Predict the smallest actual bond angle in BrF3 using the VSEPR theory.

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In which one of the following molecules are all the bonds single?

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Select the correct Lewis structure for TeBr2.

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Predict the ideal bond angles in FNO using the molecular shape given by the VSEPR theory.

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Select the Lewis structure for XeO2F2 which correctly minimizes formal charges.

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In the following Lewis structure for ClO3F, chlorine has a formal charge of ____ and an oxidation number of ____. In the following Lewis structure for ClO<sub>3</sub>F, chlorine has a formal charge of ____ and an oxidation number of ____.

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Which one of the following Lewis structures is definitely incorrect? Which one of the following Lewis structures is definitely incorrect?

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What is the molecular shape of XeO2F2 as predicted by the VSEPR theory? What is the molecular shape of XeO<sub>2</sub>F<sub>2 </sub>as predicted by the VSEPR theory?

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What is the molecular shape of ClF2- as predicted by the VSEPR theory?

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a. Draw and name three molecular shapes for molecules having the VSEPR formulas AX3, AX3E, and AX3E2, respectively. b. If the three X groups in the above formulas are identical, which of the three shapes would result in a molecule with a dipole moment?

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Oxygen difluoride is a powerful oxidizing and fluorinating agent. Select its Lewis structure.

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The formal charge on Cl in the structure shown for the perchlorate ion is The formal charge on Cl in the structure shown for the perchlorate ion is

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