Exam 17: Equilibrium in the Aqueous Phase
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Phosphoric acid is a triprotic acid, ionizing in the following sequential steps: H3PO4 + H2O
H2PO4- + H3O+
H2PO4- + H2O
HPO42- + H3O+
HPO42- + H2O
PO43- + H3O+
Which equilibrium is most important in determining the pH of a solution of sodium phosphate?






(Multiple Choice)
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Which of the following can be mixed together in water to produce a buffer solution?
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Phosphoric acid is a triprotic acid, ionizing in the following sequential steps: H3PO4 + H2O
H2PO4- + H3O+
H2PO4- + H2O
HPO42- + H3O+
HPO42- + H2O
PO43- + H3O+
What is the Kb expression for the base, dihydrogen phosphate?






(Multiple Choice)
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The acid ionization equilibrium constant, Ka, describes the reaction (where HA is a generic weak acid):
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In the following reaction in aqueous solution, the acid reactant is __________ and its conjugate base product is __________. CH3COOH + NH3
CH3COO- + NH4+

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The following titration curve is most likely to be associated with __________ 

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What is the pH of a 0.20 M solution of ammonia? The Kb value for ammonia is 1.8 10-5
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Three acids found in foods are lactic acid (in milk products), oxalic acid (in rhubarb), and malic acid (in apples). The pKa values are LA = 3.88, OA = 1.23, and MA = 3.40. Which list has the conjugate bases of these acids in order of decreasing strength?
(Multiple Choice)
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The first disinfectant used by Joseph Lister was called carbolic acid. This substance now is known as phenol, C6H5OH (pKa = 10.0). What is the pH of a 0.10 M solution of phenol?
(Multiple Choice)
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The Yucca Mountain repository in Nevada, which is intended for the long-term storage of nuclear waste, has long been mired in controversy. One ongoing concern is whether the stainless-steel alloy containers could be corroded by salts such as calcium fluoride. If the calcium ion concentration in water inside Yucca Mountain is 1.25 10-3 M, what is the maximum possible concentration of fluoride ion in this water? Assume calcium fluoride Ksp = 2.2 10-10 at the temperatures inside the nuclear waste depository.
(Multiple Choice)
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When values of Ka are small (e.g., 1 10-5) and concentrations of weak acids [HA] are relatively large (e.g., 0.10 M), the hydronium ion concentration of the solution can be calculated using which expression?
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The pH of a popular soft drink is 3.4; what is its hydronium ion concentration?
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The acidic ingredient in vinegar is acetic acid. The pH of vinegar is around 2.4, and the molar concentration of acetic acid in vinegar is around 0.85 M. Based on this information, determine the value of the acid ionization constant, Ka, for acetic acid.
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Acid-base indicators need to have very intense colors so that a very low concentration is visible. Could there be a problem in using too much indicator?
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