Exam 16: A Macroscopic Description of Matter

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The figure shows a pV diagram for 8.3 g of nitrogen gas (N2) in a sealed container. The temperature T1 of the gas in state 1 is 79°C. What are (a) the pressure p1 of the gas in state 1 and (b) the temperature T2 of the gas in state 2? The ideal gas constant is R = 8.314 J/mol ∙ K = 0.0821 L ∙ atm/mol ∙ K, and the ATOMIC weight of nitrogen is 14 g/mol. The figure shows a pV diagram for 8.3 g of nitrogen gas (N<sub>2</sub>) in a sealed container. The temperature T<sub>1</sub> of the gas in state 1 is 79°C. What are (a) the pressure p<sub>1</sub> of the gas in state 1 and (b) the temperature T<sub>2</sub> of the gas in state 2? The ideal gas constant is R = 8.314 J/mol ∙ K = 0.0821 L ∙ atm/mol ∙ K, and the ATOMIC weight of nitrogen is 14 g/mol.

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A

The interior of a refrigerator has a volume of 0.600 m3. The temperature inside the refrigerator in 282 K, and the pressure is 101 kPa. If the molecular weight of air is 29 g/mol, what is the mass of air inside the refrigerator? The ideal gas constant is R = 8.314 J/mol•K = 0.0821 L ∙ atm/mol ∙ K.

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A bag of potato chips contains 2.00 L of air when it is sealed at sea level at a pressure of 1.00 atm and a temperature of 20.0°C. What will be the volume of the air in the bag if you take it with you, still sealed, to the mountains where the temperature is 7.00°C and atmospheric pressure is 70.0 kPa? Assume that the bag behaves like a balloon and that the air in the bag is in thermal equilibrium with the outside air. (1 atm = 1.01 × 105 Pa)

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A 3.2-L volume of neon gas (Ne) is at a pressure of 3.3 atm and a temperature of 330 K. The atomic mass of neon is 20.2 g/mol, Avogadro's number is 6.022 × 1023 molecules/mol, and the ideal gas constant is R = 8.314 J/mol · K = 0.0821 L · atm/mol · K. The mass of the neon gas is closest to

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The figure shows a 50-kg frictionless cylindrical piston that floats on 0.68 mol of compressed air at 30°C. How far does the piston move if the temperature is increased to 300°C? The figure shows a 50-kg frictionless cylindrical piston that floats on 0.68 mol of compressed air at 30°C. How far does the piston move if the temperature is increased to 300°C?

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A hot air balloon has a volume of 2.00 × 103 m3 when fully inflated, and the air inside the balloon is always at atmospheric pressure of 1.01 × 105 Pa because of the large opening used to fill the balloon and heat the air inside it. What is the mass of hot air inside the balloon if its temperature is 120°C? The universal gas constant is 8.314 J/mol•K. (Assume a molecular weight of 28.8 g/mol for air.)

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If a certain sample of an ideal gas has a temperature of 109°C and exerts a pressure of 1.2 x 104 Pa on the walls of its container, how many gas molecules are present in each cubic centimeter of volume? The ideal gas constant is 8.314 J/mol · K and Avogadro's number is 6.022 × 1023 molecules/mol.

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For a fixed amount of gas, if the absolute temperature of the gas is doubled, what happens to the pressure of the gas?

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A 25-L container holds ideal hydrogen (H2) gas at a gauge pressure of 0.25 atm and a temperature of 0°C. What mass of hydrogen gas is in this container? The ATOMIC mass of hydrogen is 1.0 g/mol, the ideal gas constant is R = 8.314 J/mol•K = 0.0821 L ∙ atm/mol ∙ K, and 1.00 atm = 101 kPa.

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A sealed 26- m3 tank is filled with 2000 moles of oxygen gas (O2) at an initial temperature of 270 K. The gas is heated to a final temperature of 460 K. The ATOMIC mass of oxygen is 16.0 g/mol, and the ideal gas constant is R = 8.314 J/mol · K = 0.0821 L · atm/mol · K. The final pressure of the gas is closest to

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How many moles of water (H2O) molecules are in a 4.00 m3 container at a pressure 8.00 × 105 N/m2 and temperature 600°C? The ideal gas constant is R = 8.314 J/mol•K = 0.0821 L ∙ atm/mol ∙ K.

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A vertical tube that is closed at the upper end and open at the lower end contains an air pocket. The open end of the tube is under the water of a lake, as shown in the figure. When the lower end of the tube is just under the surface of the lake, where the temperature is 37°C and the pressure is 1.0 × 105 Pa, the air pocket occupies a volume of 630 cm3. Suppose now that the lower end of the tube is at a depth of 86 m in the lake, where the temperature is 7.0°C. What is the volume of the air pocket under these conditions? The density of the water in the lake is 1000 kg/m3. A vertical tube that is closed at the upper end and open at the lower end contains an air pocket. The open end of the tube is under the water of a lake, as shown in the figure. When the lower end of the tube is just under the surface of the lake, where the temperature is 37°C and the pressure is 1.0 × 10<sup>5</sup> Pa, the air pocket occupies a volume of 630 cm<sup>3</sup>. Suppose now that the lower end of the tube is at a depth of 86 m in the lake, where the temperature is 7.0°C. What is the volume of the air pocket under these conditions? The density of the water in the lake is 1000 kg/m<sup>3</sup>.

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Which contains more moles of material: 80 grams of helium gas (He, having atomic weight 4.0 g/mol) or 400 grams of argon gas (Ar, having atomic weight 40 g/mol)?

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An ideal gas is at a pressure 1.00 × 105 N/m2 and occupies a volume 2.00 m3. If the gas is compressed to a volume 1.00 m3 while the temperature remains constant, what will be the new pressure in the gas?

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A fixed amount of ideal gas is held in a rigid container that expands negligibly when heated. At 20°C the gas pressure is p. If we add enough heat to increase the temperature from 20°C to 40°C, the pressure will be

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(a) Internal human body temperature is often stated to be normal at 98.6°F. What is this temperature on the Celsius and Kelvin scales? (b) Gallium boils at 2205°C. What is the corresponding temperature in the Fahrenheit and Kelvin scales? (c) The boiling point of liquid nitrogen is 77.0 K. What is the corresponding temperature in the Fahrenheit and Celsius scales?

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The figure shows a pV diagram for 0.0066 mol of gas that undergoes the process 1 → 2 → 3. What is the pressure p2. The ideal gas constant is R = 8.314 J/mol ∙ K = 0.0821 L ∙ atm/mol ∙ K. The figure shows a pV diagram for 0.0066 mol of gas that undergoes the process 1 → 2 → 3. What is the pressure p<sub>2</sub>. The ideal gas constant is R = 8.314 J/mol ∙ K = 0.0821 L ∙ atm/mol ∙ K.

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What is the mass density of argon gas at pressure 1.00 × 105 N/m2 and at temperature 300 K? The mean atomic mass of argon is 39.948 g/mol and the ideal gas constant is R = 8.314 J/mol•K = 0.0821 L ∙ atm/mol ∙ K.

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A sealed 89-m3 tank is filled with 6000 moles of oxygen gas (O2) at an initial temperature of 270 K. The gas is heated to a final temperature of 350 K. The ATOMIC mass of oxygen is 16.0 g/mol, and the ideal gas constant is R = 8.314 J/mol · K = 0.0821 L · atm/mol · K. The initial pressure of the gas is closest to

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The figure (not to scale) shows a pV diagram for 1.8 g of helium gas (He) that undergoes the process 1 → 2 → 3. Find the value of V3. The ideal gas constant is R = 8.314 J/mol ∙ K = 0.0821 L ∙ atm/mol ∙ K, and the atomic weight of helium is 4.0 g/mol. The figure (not to scale) shows a pV diagram for 1.8 g of helium gas (He) that undergoes the process 1 → 2 → 3. Find the value of V<sub>3</sub>. The ideal gas constant is R = 8.314 J/mol ∙ K = 0.0821 L ∙ atm/mol ∙ K, and the atomic weight of helium is 4.0 g/mol.

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