Exam 17: Principles of Chemical Reactivity: Other Aspects of Aqueous Equilibria

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What is the pH of the buffer that results when 32 g sodium acetate (NaCH3CO2)is mixed with 500.0 mL of 1.0 M acetic acid (CH3CO2H)and diluted with water to 1.0 L? (Ka of CH3CO2H = 1.8 × 10-5)

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What molar ratio of acetic acid to sodium acetate is required to create a buffer solution having a pH of 4.88 at 25°C? Ka for HC2H3O2 is 1.8 × 10-5.

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What mass of sodium hydroxide must be added to 65.0 mL of 0.926 M acetic acid in order to create a buffer with a pH of 4.83? Ka for acetic acid is 1.8 × 10-5.

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Suppose 50.00 mL of 2.0 × 10-5 M Fe(NO3)3 is added to 50.00 mL of 2.0 ×10-4 M KIO3.Which of the following statements is true? For Fe(IO3)3,Ksp = 1.0 × 10-14.

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A 50.00-mL solution of 0.0426 M trimethylamine (Kb = 6.5 × 10-5)is titrated with a 0.0257 M solution of hydrochloric acid as the titrant.What is the pH of the base solution after 22.31 mL of titrant have been added? (Kw = 1.00 × 10-14)

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What is the pH at the equivalence point when a 25.0 mL sample of 0.200 M aqueous formic acid (HCO2H)is titrated with 0.100 M aqueous potassium hydroxide? (Ka of HCO2H = 1.8 × 10-4)

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Two important biological buffer systems control pH in the range of 6.9 to 7.4.These buffer systems are H2CO3/HCO3- and _____.

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What is the maximum hydroxide-ion concentration that a 0.019 M MgCl2 solution could have without causing the precipitation of Mg(OH)2? For Mg(OH)2,Ksp = 1.8 × 10-11.

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What will be the pH of the solution when 0.10 mol of H+ ion is added to a 2.0 liter buffered solution composed of 0.45 M ammonia,NH3,and 0.26 M ammonium fluoride,NH4F? (Kb for ammonia = 1.8 × 10-5)

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The hydroxide ion concentration of a saturated solution of Fe(OH)2 is The hydroxide ion concentration of a saturated solution of Fe(OH)<sub>2</sub> is   M.What is the solubility product constant for Fe(OH)<sub>2</sub>? M.What is the solubility product constant for Fe(OH)2?

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What is the pH of a buffer that results when 0.50 mole of H3PO4 is mixed with 0.75 mole of NaOH and diluted with water to 1.00 L? (The acid dissociation constants of phosphoric acid are Ka1 = 7.5 × 10-3,Ka2 = 6.2 × 10-8,and Ka3 = 3.6 × 10-13)

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How many moles of solid NaF would have to be added to 1.0 L of 2.16 M HF solution to achieve a buffer of pH 3.35? Assume there is no volume change.(Ka for HF = 7.2 × 10-4)

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If 25 mL of 0.750 M HCl are added to 100.mL of 0.302 M NaOH,what is the final pH?

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If 20 mL of 0.10 M NaOH is added to 40 mL of 0.20 M HC2H3O2,what is the pH of the resulting solution at 25°C? Ka for HC2H3O2 is 1.8 × 10-5 at 25°C.

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What is the minimum mass of Na2CO3 (molar mass = 105.990 g/mol)that must be added to 43.4 mL of a 1.0 × 10-4 M AgNO3 solution in order for precipitation to occur? The Ksp of Ag2CO3 is 8.6 × 10-12.Assume no volume change occurs upon addition of Na2CO3.

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When a weak base is titrated with a strong acid,the pH at the equivalence point is _____.

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All of the following statements concerning acid-base buffers are true EXCEPT

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If 0.50 L of a buffer containing 1.0 mol H2PO4− and 1.0 mol HPO42 is diluted to a volume of 5.0 L,the pH

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If 500 mL of 1.4 × 10-6 M AgNO3 is mixed with 500 mL of 1.4 × 10-6 M NaBr,what will occur? For AgBr,Ksp = 5 × 10-13.

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Which of the following indicators is most suitable for the titration of a 25.00-mL sample of 0.140 M propionic acid,HC3H5O2,with strong base?

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