Exam 13: The Solid State

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Above a substance's _____ temperature,it is not possible to compress the substance into the liquid phase.If enough pressure is applied the substance will become a supercritical fluid.

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On the phase diagram below,which point corresponds to conditions where only the gas phase exists? On the phase diagram below,which point corresponds to conditions where only the gas phase exists?

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Calcium sulfide has a face-centered cubic unit cell with calcium ions in octahedral holes.How many ions of each element are contained in each unit cell?

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A salt with a 1:1 ratio of anions to cations may pack in a face-centered cubic unit cell with the anions at the lattice points and the cations occupying one-half of the _____ holes.Zinc sulfide is an example of this structure.

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What process occurs when the temperature of a substance at Point A is increased (at constant pressure)until the substance is at Point B? What process occurs when the temperature of a substance at Point A is increased (at constant pressure)until the substance is at Point B?

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Magnesium sulfide (molar mass 56.37 g/mol)has a face-centered cubic unit cell with magnesium ions in octahedral holes.The ionic radii of magnesium ions and sulfide ions are 79 pm and 184 pm,respectively.What is the density of MgS (in g/cm3)?

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If an ionic compound with the formula MX2 forms a face-centered cubic unit cell with the cations (M2n+)at the lattice points,the anions (Xn-)will occupy:

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Which of the following elements might be used as a dopant in a silicon host to create a p-type semiconductor?

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A low-melting solid readily dissolves in water to produce a nonconducting solution.The solid is most likely a(n)_____.

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Nickel has a face-centered cubic cell,and its density is 8.90 g/cm3.What is the radius (in pm)of a nickel atom? (The molar mass of nickel is 58.69 g/mol)

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Lithium chloride crystallizes in a face-centered cubic unit cell with chloride ions occupying the lattice points and lithium ions occupying octahedral holes.How many chloride ions surround each lithium ion in LiCl?

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Polonium (atomic mass 209.0 g/mol)crystallizes in a primitive cubic unit cell.If the density of polonium is 9.15 g/cm3,what is the radius of a polonium atom (in pm)?

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What is the length of the diagonal (in atomic radii)along the face of a face-centered cubic unit cell?

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For a metal that crystallizes in a body-centered cubic unit cell,what percentage of the space in the cell is occupied by the metal atoms?

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Cesium bromide crystallizes in a primitive cubic unit cell with bromide ions at the lattice points.The cesium ions occupy cubic holes.How many bromide ions surround each cesium ion in cesium bromide?

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Gold (atomic mass 197 g/mol),with an atomic radius of 144.2 pm,crystallizes in a face-centered cubic lattice.What is the density of gold?

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Elements that have their highest energy electrons in a filled band of molecular orbitals,separated from the lowest empty band by an energy difference much too large for electrons to jump between bands,are called _____.

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Strontium oxide has a face centered cubic unit cell of oxide ions with the strontium ions in octahedral holes.If the radius of Sr2+ is 127 pm and the radius of O2- is 135 pm,what is the density of strontium ions oxide? (100 cm = 1 × 1012 pm)

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Which process requires the greatest endothermic change in enthalpy for water?

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Iron crystallizes in a body-centered cubic lattice.If the radius of iron is 126 pm,what is the unit cell edge length?

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