Exam 10: An Introduction to Kinetics and Equilibrium

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The addition of I2(g) to a fixed volume container with I2(g), H2(g), and HI(g) at equilibrium at a given temperature would cause H2(g) + I2(g) The addition of I<sub>2</sub>(g) to a fixed volume container with I<sub>2</sub>(g), H<sub>2</sub>(g), and HI(g) at equilibrium at a given temperature would cause  H<sub>2</sub>(g) + I<sub>2</sub>(g)   2 HI(g) 2 HI(g)

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A solution is prepared in which the Ag+ ion concentration is 2.5 x 10-3 M and the Cl- ion concentration is 3.2 x 10-4 M. Which of the following statements is true given that the Ksp for AgCl is 1.8 x 10-10?

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Which of the following equations correctly describes the relationship between the concentrations of Pb2+ and Br- ions in a saturated solution of PbBr2(s)?

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Which of the following statements correctly describes the following reaction? 2 NH3(g)  Which of the following statements correctly describes the following reaction? 2 NH<sub>3</sub>(g)   N<sub>2</sub>(g) + 3 H<sub>2</sub>(g)     \Delta  H = 92.2 kJ N2(g) + 3 H2(g)   Δ\Delta H = 92.2 kJ

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A solution is 0.10 M in Ca(NO3)2. What would the concentration of NaOH need to be for a precipitate of Ca(OH)2 to form? Ksp Ca(OH)2 = 5.5 x 10-6.

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What would be the effect of decreasing the pressure on the following reaction after it reaches equilibrium? 2 NO2(g) What would be the effect of decreasing the pressure on the following reaction after it reaches equilibrium?  2 NO<sub>2</sub>(g)   2 NO(g) + O<sub>2</sub>(g) 2 NO(g) + O2(g)

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Assume that the reaction quotient, Qc, for the following reaction at 25°C is 1.0 x 10-8 2 NO2(g) Assume that the reaction quotient, Q<sub>c</sub>, for the following reaction at 25°C is 1.0 x 10<sup>-8</sup> 2 NO<sub>2</sub>(g)   2 NO(g) + O<sub>2</sub>(g)     K<sub>c</sub> = 7.4 x 10<sup>-16</sup> (at 25°C) From this we can conclude: 2 NO(g) + O2(g)     Kc = 7.4 x 10-16 (at 25°C) From this we can conclude:

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What is the Ksp of PbBr2 if the concentration of PbBr2(aq) in a saturated solution is 1.3 x 10-2 moles/L?

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What would happen if O2 were removed from the following system at equilibrium at 25°C? 2 NO2(g) What would happen if O<sub>2</sub> were removed from the following system at equilibrium at 25°C?  2 NO<sub>2</sub>(g)   2 NO(g) + O<sub>2</sub>(g)   K<sub>c</sub> = 7.4 x 10<sup>-1</sup> at 25<sup>o</sup>C 2 NO(g) + O2(g)   Kc = 7.4 x 10-1 at 25oC

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Of the compounds in the table below, _______ is the  least \underline{\text{ least }} soluble.  Of the compounds in the table below, _______ is the   \underline{\text{ least  }}  soluble.

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Which one of the following graphs best represents the relationship between the concentration of reactants and products with respect to time for the following chemical reaction? 2 NO2(g) Which one of the following graphs best represents the relationship between the concentration of reactants and products with respect to time for the following chemical reaction?  2 NO<sub>2</sub>(g)   2 NO(g) + O<sub>2</sub>(g) 2 NO(g) + O2(g)

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Approximately how many grams of Ag2CO3 will dissolve in 1.0 liter of a solution that is 0.10 M in Na2CO3? The Ksp of Ag2CO3 is 6.2 x 10-12.

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Ag2SO4(s) is in equilibrium with silver and sulfate ions in solution: Ag2SO4(s) Ag<sub>2</sub>SO<sub>4</sub>(s) is in equilibrium with silver and sulfate ions in solution:  Ag<sub>2</sub>SO<sub>4</sub>(s)   2Ag<sup>+</sup>(aq) + SO<sub>4</sub><sup>2-</sup>(aq) Which of the following will not increase the amount of solid Ag<sub>2</sub>SO<sub>4</sub>(s) present? 2Ag+(aq) + SO42-(aq) Which of the following will not increase the amount of solid Ag2SO4(s) present?

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If a solution has a Mg2+ ion concentration of 5.0 x 10-3 M and an OH- concentration of 0.010 M, will a precipitate form? Ksp Mg(OH)2 = 1.7 x 10-6.

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     -Which of the following will be true concerning the K<sub>c</sub> of the reaction described by the graph above? -Which of the following will be true concerning the Kc of the reaction described by the graph above?

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Which of the following equilibria would not be affected by changes in pressure?

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The following reaction was carried out: Ni(CO)4 + PPh3(g) \rightarrow PPh3Ni(CO)3 + CO Over 200 seconds, the concentration of Ni(CO)4 dropped from 10 M to 2.5 M. What is the average rate of the reaction in M/s over this time period?

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Which of the following equations describes the relationship between the solubility product for AgCl and the solubility of this compound?

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What is the solubility in moles per liter of AgBr in water given that the Ksp is 5.0 x 10-13?

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Describe the relationship between the rate constants kf and kr for the following one step reaction at equilibrium. Describe the relationship between the rate constants k<sub>f</sub> and k<sub>r</sub> for the following one step reaction at equilibrium.

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