Exam 12: Solutions

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Consider the following gas-aqueous liquid equilibrium for a closed system at a constant temperature. O2(g) Consider the following gas-aqueous liquid equilibrium for a closed system at a constant temperature. O<sub>2</sub>(g)  O<sub>2</sub>(aq) What is the effect on the equilibrium composition of the liquid when the partial pressure of O<sub>2</sub> gas above the liquid is decreased?O2(aq) What is the effect on the equilibrium composition of the liquid when the partial pressure of O2 gas above the liquid is decreased?

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To determine the molar mass of a small protein in the range of 20,000-40,000 g/mol,it would be best to measure

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If the solubility of O2 at 0.160 bar and 25°C is 6.65 g/100 g H2O,what is the solubility of O2 at a pressure of 1.84 bar and 25°C?

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A solution consisting of 0.276 mol of methylbenzene,C6H5CH3,in 242 g of nitrobenzene,C6H5NO2,freezes at -2.0 °C.Pure nitrobenzene freezes at 6.0°C.What is the freezing-point depression constant of nitrobenzene?

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Which of the following sets of conditions favors maximum solubility of an ionic solute in water?

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Benzene,C6H6,and toluene,C6H5CH3,form ideal solutions.At 35°C the vapor pressure of benzene is 160.torr and that of toluene is 50.0 torr.In an experiment,3.9 mol of benzene and 5.7 mol of toluene are placed in a closed container at 35°C and allowed to come to equilibrium.What is the mole fraction of toluene in the vapor phase?

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Which of the following sets of conditions favors maximum solubility of solute in solvent?

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A red blood cell placed in pure water will swell because

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When 1 mol of a nonvolatile nonelectrolyte is dissolved in 3 mol of a solvent,the vapor pressure of the solution compared with that of the pure solvent is

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Which of the following statements best describes what happens when a small amount of solid rubidium chloride is dissolved in water?

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What is the mole fraction of urea in a solution that contains 2.7 mol of urea and 4.6 mol of water?

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A 3.140 molal solution of NaCl is prepared.How many grams of NaCl are present in a sample containing 2.692 kg of water?

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What is the percent Na2CO3 by mass in a 1.92 molal aqueous solution?

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Which of the following solutes in aqueous solution would be expected to exhibit the smallest freezing-point lowering (assuming ideal behavior)?

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The molal boiling-point constant for water is 0.51°C/molal.The boiling point of a 1.00 m solution of Ca(NO3)2 should be increased by

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A liquid-liquid solution is called an ideal solution if I.it obeys PV = nRT. II.it obeys Raoult's law. III.solute-solute,solvent-solvent,and solute-solvent interactions are very similar. IV.solute-solute,solvent-solvent,and solute-solvent interactions are quite different.

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The fact that the boiling point of a pure solvent is lower than the boiling point of a solution of the same solvent is a direct consequence of the

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What is the vapor pressure at 20°C of an ideal solution prepared by the addition of 1.36 g of the nonvolatile solute urea,CO(NH2)2,to 24.1 g of methanol,CH3OH? The vapor pressure of pure methanol at 20°C is 89.0 mmHg.

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Calculate the molecular weight of a small protein if a 0.25-g sample dissolved in 180 mL of water has an osmotic pressure of 9.2 mmHg at 25°C.(R = 0.0821 L · atm/(K · mol))

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A concentrated hydrofluoric acid solution is 49.0% HF by mass and has a density of 1.3406 g/mL at 25°C.What is the mass of HF per L of solution?

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