Exam 14: Chemical Equilibrium

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For the equilibrium N2O4(g) For the equilibrium N<sub>2</sub>O<sub>4</sub>(g)   2NO<sub>2</sub>(g),at 298 K,K<sub>p</sub> = 0.15.For this reaction system,it is found that the partial pressure of N<sub>2</sub>O<sub>4</sub> is 3.5 × 10<sup>-2</sup> atm at equilibrium.What is the partial pressure of NO<sub>2</sub> at equilibrium? (R = 0.0821 L ∙ atm/(K ∙ mol)) 2NO2(g),at 298 K,Kp = 0.15.For this reaction system,it is found that the partial pressure of N2O4 is 3.5 × 10-2 atm at equilibrium.What is the partial pressure of NO2 at equilibrium? (R = 0.0821 L ∙ atm/(K ∙ mol))

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What balanced equation is the following equilibrium expression derived from? What balanced equation is the following equilibrium expression derived from?

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For which of the following systems at equilibrium and at constant temperature will decreasing the volume cause the equilibrium to shift to the right?

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Consider the following equilibrium: 2NO(g)+ 3F2(g) Consider the following equilibrium: 2NO(g)+ 3F<sub>2</sub>(g)   2NOF<sub>3</sub>(g) Suppose 0.20 mol of NO and 0.30 mol of F<sub>2</sub> are added to a 5.0-L container.If x mol of NOF<sub>3</sub> is present at equilibrium,how many moles of fluorine are present at equilibrium? 2NOF3(g) Suppose 0.20 mol of NO and 0.30 mol of F2 are added to a 5.0-L container.If x mol of NOF3 is present at equilibrium,how many moles of fluorine are present at equilibrium?

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Which of the following equilibria would not be affected by pressure changes at constant temperature?

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What is the expression for Kc for the following equilibrium? CaSO3(s) What is the expression for K<sub>c</sub> for the following equilibrium? CaSO<sub>3</sub>(s)   CaO(s)+ SO<sub>2</sub>(g) CaO(s)+ SO2(g)

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One method for the decomposition of carbon dioxide proceeds as follows: 2CO2(g) One method for the decomposition of carbon dioxide proceeds as follows: 2CO<sub>2</sub>(g)   2CO(g)+ O<sub>2</sub>(g); ΔH = 559 kJ Which of the following changes will cause an increase in the equilibrium concentration of CO? 2CO(g)+ O2(g); ΔH = 559 kJ Which of the following changes will cause an increase in the equilibrium concentration of CO?

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Exactly 1.0 mol N2O4 is placed in an empty 1.0-L container and allowed to reach equilibrium described by the equation N2O4(g) Exactly 1.0 mol N<sub>2</sub>O<sub>4</sub> is placed in an empty 1.0-L container and allowed to reach equilibrium described by the equation N<sub>2</sub>O<sub>4</sub>(g)   2NO<sub>2</sub>(g). If at equilibrium the N<sub>2</sub>O<sub>4</sub> is 28.0% dissociated,what is the value of the equilibrium constant,K<sub>c</sub>,for the reaction under these conditions? 2NO2(g). If at equilibrium the N2O4 is 28.0% dissociated,what is the value of the equilibrium constant,Kc,for the reaction under these conditions?

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Which of the following equilibria would be affected by volume changes at constant temperature?

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Solid HgO,liquid Hg,and gaseous O2 are placed in a glass bulb and allowed to reach equilibrium. 2HgO(s) Solid HgO,liquid Hg,and gaseous O<sub>2</sub> are placed in a glass bulb and allowed to reach equilibrium. 2HgO(s)   2Hg(l)+ O<sub>2</sub>(g); ΔH = 181.6 kJ The amount of Hg(l)in the bulb could be increased 2Hg(l)+ O2(g); ΔH = 181.6 kJ The amount of Hg(l)in the bulb could be increased

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Which of the following statements is true in a reaction system at equilibrium?

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What is the balanced equation for the following equilibrium expression? What is the balanced equation for the following equilibrium expression?

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For which of the following values of the equilibrium constant does the reaction mixture contain mostly products?

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Consider the following system at equilibrium: N2(g)+ 3H2(g) Consider the following system at equilibrium: N<sub>2</sub>(g)+ 3H<sub>2</sub>(g)   2NH<sub>3</sub>(g); ΔH° = -92.94 kJ Which of the following changes will shift the equilibrium to the right? I.increasing the temperature II.decreasing the temperature III.increasing the volume IV.decreasing the volume V.removing some NH<sub>3</sub> VI.adding some NH<sub>3</sub> VII.removing some N<sub>2</sub> VIII.adding some N<sub>2</sub> 2NH3(g); ΔH° = -92.94 kJ Which of the following changes will shift the equilibrium to the right? I.increasing the temperature II.decreasing the temperature III.increasing the volume IV.decreasing the volume V.removing some NH3 VI.adding some NH3 VII.removing some N2 VIII.adding some N2

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The reaction quotient for a system is The reaction quotient for a system is   .If the equilibrium constant for the system is   ,what will happen as the reaction mixture approaches equilibrium? .If the equilibrium constant for the system is The reaction quotient for a system is   .If the equilibrium constant for the system is   ,what will happen as the reaction mixture approaches equilibrium? ,what will happen as the reaction mixture approaches equilibrium?

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Consider the reaction S2Cl2(l)+ CCl4(l) Consider the reaction S<sub>2</sub>Cl<sub>2</sub>(l)+ CCl<sub>4</sub>(l)   CS<sub>2</sub>(g)+ 3Cl<sub>2</sub>(g); ΔH° = 84.3 kJ If the above reactants and products are contained in a closed vessel and the reaction system is at equilibrium,the number of moles of CS<sub>2</sub> can be increased by CS2(g)+ 3Cl2(g); ΔH° = 84.3 kJ If the above reactants and products are contained in a closed vessel and the reaction system is at equilibrium,the number of moles of CS2 can be increased by

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Which expression correctly describes the equilibrium constant Kc for the following reaction? 2C2H2(g)+ 5O2(g) Which expression correctly describes the equilibrium constant K<sub>c</sub> for the following reaction? 2C<sub>2</sub>H<sub>2</sub>(g)+ 5O<sub>2</sub>(g)   4CO<sub>2</sub>(g)+ 2H<sub>2</sub>O(g) 4CO2(g)+ 2H2O(g)

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Consider the following equilibrium: 1/2N2O4(g) Consider the following equilibrium: 1/2N<sub>2</sub>O<sub>4</sub>(g)   NO<sub>2</sub>(g); K<sub>c</sub> = 3.3 at 100°C For which of the following equilibria is K<sub>c</sub> less than 3.3 at 100°C? NO2(g); Kc = 3.3 at 100°C For which of the following equilibria is Kc less than 3.3 at 100°C?

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At 298 K,the value of Kc for the reaction H2(g)+ Br2(g) At 298 K,the value of K<sub>c</sub> for the reaction H<sub>2</sub>(g)+ Br<sub>2</sub>(g)   2HBr(g)is 2.0 × 10<sup>19</sup>.What is K<sub>c</sub> for HBr(g)   1/2H<sub>2</sub>(g)+ 1/2Br<sub>2</sub>(g)? 2HBr(g)is 2.0 × 1019.What is Kc for HBr(g) At 298 K,the value of K<sub>c</sub> for the reaction H<sub>2</sub>(g)+ Br<sub>2</sub>(g)   2HBr(g)is 2.0 × 10<sup>19</sup>.What is K<sub>c</sub> for HBr(g)   1/2H<sub>2</sub>(g)+ 1/2Br<sub>2</sub>(g)? 1/2H2(g)+ 1/2Br2(g)?

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A(n)_____ is a substance that increases the rate of a reaction but is not consumed by it.

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