Exam 6: Thermochemistry

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What is the standard enthalpy change for the combustion of liquid cyclopentane,C5H10? 2C5H10(l)+ 15O2(g)→ 10CO2(g)+ 10H2O(l) Substance ΔH°f (kJ/mol) C5H10(l) -105.6 CO2(g) -393.5 H2O(l) -285.8

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The overall chemical equation resulting from the sum of the following three steps is 2C(s)+ 2H2O(g)→ 2CO(g)+ 2H2(g) CO(g)+ H2O(g)→ CO2(g)+ H2(g) CO(g)+ 3H2(g)→ CH4(g)+ H2O(g)

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Which substance has a standard enthalpy of formation equal to zero at 25°C?

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The reaction of iron with hydrochloric acid is represented by the following thermochemical equation. Fe(s)+ 2HCl(aq)→ FeCl2(aq)+ H2(g); ΔH° = -87.9 kJ If,in a particular experiment,1.56 kJ of heat was released at constant pressure,what volume of H2(g),measured at STP,was produced? (R = 0.0821 L • atm/(K • mol))

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Calculate ΔU of a gas for a process in which the gas absorbs 29 J of heat and does 31 J of work by expanding.

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If q = -96 kJ for a certain process,that process

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If q = 60 kJ and w = 96 kJ for a certain process,that process

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Which of the following processes will result in the lowest final temperature of the metal-water mixture at equilibrium?

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Combustion of 3.65 g of liquid benzene (C6H6)causes a temperature rise of 21.1°C in a constant-pressure calorimeter that has a heat capacity of 7.23 kJ/°C.What is ΔH for the following reaction? C6H6(l)+ Combustion of 3.65 g of liquid benzene (C<sub>6</sub>H<sub>6</sub>)causes a temperature rise of 21.1°C in a constant-pressure calorimeter that has a heat capacity of 7.23 kJ/°C.What is ΔH for the following reaction? C<sub>6</sub>H<sub>6</sub>(l)+  O<sub>2</sub>(g)→ 6CO<sub>2</sub>(g)+ 3H<sub>2</sub>O(l)O2(g)→ 6CO2(g)+ 3H2O(l)

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In a bomb calorimeter,reactions are carried out

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When 50.0 mL of 1.27 M of HCl(aq)is combined with 50.0 mL of 1.32 M of NaOH(aq)in a coffee-cup calorimeter,the temperature of the solution increases by 8°C.What is the change in enthalpy for this balanced reaction? HCl(aq)+ NaOH(aq)→ NaCl(aq)+ H2O(l) Assume that the solution density is 1.00 g/mL and the specific heat capacity of the solution is 4.18 J/g⋅°C.

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From the following information,determine ΔH°f of malonic acid,CH2(COOH)2(s). CH2(COOH)2(s)+ 2O2(g)→ 3CO2(g)+ 2H2O(l); ΔH° = -861.0 kJ Substance ΔH°f (kJ/mol) CO2(g) -393.5 H2O(l) -285.8

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When 0.0500 mol of HCl(aq)is reacted with 0.0500 mol of NaOH(aq)in 50.0 mL of water,the temperature of the solution increases by 5.99°C.What is the enthalpy of reaction for the following thermochemical equation? HCl(aq)+ NaOH(aq)→ NaCl(aq)+ H2O(l) Assume that the heat capacity of the solution and calorimeter is 465.4 J/°C.

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The units for heat capacity are

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The skydiver plunging to earth possesses what type(s)of energy?

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A 58.7-g sample of nickel (s = 0.443 J/(g ∙ °C)),initially at 147.4°C,is placed in an insulated vessel containing 184.0 g of water (s = 4.18 J/(g ∙ °C)),initially at 29.9°C.Once equilibrium is reached,what is the final temperature of the metal-water mixture? Neglect the heat capacity of the vessel.

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How much heat must be applied to a 40.2-g sample of gold (s = 0.129 J/(g ∙ °C))in order to raise its temperature from 28.2°C to 351.5°C?

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Under conditions of constant pressure,for which of the following reactions is the magnitude of pressure-volume work going to be greatest?

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Which of the following reactions corresponds to the thermochemical equation for the standard enthalpy of formation of N,N-diethyl-m-toluamide,C12H17NO(l),the active ingredient in some insect repellents?

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The reaction of iron with hydrochloric acid is represented by the following thermochemical equation. Fe(s)+ 2HCl(aq)→ FeCl2(aq)+ H2(g); ΔH° = -87.9 kJ In which of the following experiments would the temperature rise the most?

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