Exam 17: Solubility and Complex-Ion Equilibria
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Figures I-IV represent ionic compounds formed upon the mixing of an aqueous solution containing cation C with an aqueous solution containing anion A.Identify the figure(s)that represent(s)products for which Ksp = 108s5,where s is the molar solubility of the ionic compound. 

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(Multiple Choice)
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Correct Answer:
C
To 1.0 L of water,1.5 × 10-6 mol of Pb(NO3)2,6.5 × 10-6 mol of K2CrO4,and 1.0 mol of NaCl are added.What will happen?
Salt
Ksp
PbCrO4
1)8 × 10-14
PbCl2
1)6 × 10-5
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Correct Answer:
B
For which of the following salts would the addition of nitric acid increase its solubility?
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Correct Answer:
D
The figure below represents the results of adding a strong acid to a saturated solution of an ionic compound.Which of the following could be the ionic compound? 

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Which of the following substances will increase the molar solubility of nickel(II)phosphate in a saturated solution?
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What is the solubility (in g/L)of silver(I)chloride at 25°C? The solubility product constant for silver(I)chloride is 1.8 × 10-10 at 25°C.
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For which pair of cations would the addition of dilute hydrobromic acid precipitate one but not the other?
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What will happen if 50.0 mL of 0.032 M Na2S2O3,50.0 mL of 0.010 M AgNO3,and 50.0 mL of 0.047 M KCl are mixed together? For AgCl,Ksp = 1.8 × 10-10; for Ag(S2O3)23-,Kf = 2.9 × 1013.
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A solution contains 0.018 mol each of I-,Br-,and Cl-.When the solution is mixed with 200 mL of 0.24 M AgNO3,how much AgCl(s)precipitates out?
Ksp
AgI
= 1)5 × 10-16
Ksp
AgBr
= 5)0 × 10-13
Ksp
AgCl
= 1)6 × 10-10
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What is the minimum concentration of Pb2+ required to begin precipitating Pb(OH)2(s)in a solution of pH 10.78? For Pb(OH)2,Ksp = 1.4 × 10-20.
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What is the solubility (in g/L)of aluminum hydroxide at 25°C? The solubility product constant for aluminum hydroxide is 4.6× 10-33 at 25°C.
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A 5.0 × 10-4 M solution of MnSO4 is gradually made more basic by adding NaOH.At what pH will manganese(II)hydroxide begin to precipitate? For Mn(OH)2,Ksp = 2.0 × 10-13.
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What is the concentration of Cd2+ in a 0.012 M Cd(NO3)2 solution that is also 1.0 M NH3? For Cd(NH3)42+,Kf = 1.0 × 107.
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A saturated solution of which of the following salts will have the greatest molar concentration of silver ion?
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If 500 mL of 1.3 × 10-6 M AgNO3 is mixed with 500 mL of 1.3 × 10-6 M NaBr,what will occur? For AgBr,Ksp = 5 × 10-13.
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What is the correct mathematical expression for finding the molar solubility (s)of Sn(OH)2?
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Figures I-IV represent ionic compounds formed upon the mixing of an aqueous solution containing cation C with an aqueous solution containing anion A.Identify the figure(s)that represent(s)products for which Ksp = s2,where s is the molar solubility of the ionic compound. 

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Which of the following insoluble salts will dissolve upon reaction with excess ammonia?
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What is the molar solubility of nickel(II)sulfide in 0.091 M KCN? For NiS,Ksp = 3.0 × 10-19; for Ni(CN)42-,Kf = 1.0 × 1031.
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Cation C and anion A form an ionic compound for which Ksp = 4s3,where s is the molar solubility of the ionic compound.Which of Figures I-III represent(s)possible results of the mixing of an aqueous solution containing cation C with an aqueous solution containing anion A? 

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