Exam 19: Electrochemistry

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Balance the following half-reaction occurring in acidic solution. ​ NO3-(aq)→ Balance the following half-reaction occurring in acidic solution. ​ NO<sub>3</sub><sup>-</sup>(aq)→

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When the following oxidation-reduction reaction in acidic solution is balanced,what is the lowest whole-number coefficient for H+,and on which side of the balanced equation should it appear? S2O82-(aq)+ NO(g)→ SO42-(aq)+ NO3-(aq)

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A fuel cell designed to react grain alcohol with oxygen has the following net reaction: C2H5OH(l)+ 3O2(g)→ 2CO2(g)+ 3H2O(l) The maximum work that 1 mol of alcohol can yield by this process is 1320 kJ.What is the theoretical maximum voltage that this cell can achieve?

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Given: Mn2+(aq)+ 2e- Given: Mn<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mn(s); E° = -1.18 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Cu(s); E° = 0.34 V Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq)+ 14H<sup>+</sup>(aq)+ 6e<sup>-</sup>   2Cr<sup>3+</sup>(aq)+ 7H<sub>2</sub>O(l); E° = 1.33 V Which of the following species is the strongest reducing agent? Mn(s); E° = -1.18 V Cu2+(aq)+ 2e- Given: Mn<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mn(s); E° = -1.18 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Cu(s); E° = 0.34 V Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq)+ 14H<sup>+</sup>(aq)+ 6e<sup>-</sup>   2Cr<sup>3+</sup>(aq)+ 7H<sub>2</sub>O(l); E° = 1.33 V Which of the following species is the strongest reducing agent? Cu(s); E° = 0.34 V Cr2O72-(aq)+ 14H+(aq)+ 6e- Given: Mn<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mn(s); E° = -1.18 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Cu(s); E° = 0.34 V Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq)+ 14H<sup>+</sup>(aq)+ 6e<sup>-</sup>   2Cr<sup>3+</sup>(aq)+ 7H<sub>2</sub>O(l); E° = 1.33 V Which of the following species is the strongest reducing agent? 2Cr3+(aq)+ 7H2O(l); E° = 1.33 V Which of the following species is the strongest reducing agent?

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For a galvanic cell using Fe | Fe2+(1.0 M)and Pb | Pb2+(1.0 M)half-cells,which of the following statements is correct? Fe2+(aq)+ 2e- → Fe(s); E° = -0.41 V Pb2+(aq)+ 2e- → Pb(s); E° = -0.13 V

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What is the cell reaction for the following voltaic cell? Cr(s)| Cr3+(aq)|| Br-(aq)| Br2(g)| Pt(s)

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A voltaic cell is made by placing an iron electrode in a compartment in which the Fe2+ concentration is 3.0 × 10-5 M and by placing a Pt electrode in the other compartment,in which the H+ concentration is 3.10 M and A voltaic cell is made by placing an iron electrode in a compartment in which the Fe<sup>2+</sup> concentration is 3.0 × 10<sup>-5</sup> M and by placing a Pt electrode in the other compartment,in which the H<sup>+</sup> concentration is 3.10 M and   = 1.00 atm.The Fe<sup>2+</sup>/Fe half-cell reduction potential is -0.41 V,and the H<sup>+</sup>/H<sub>2</sub> half-cell reduction potential is 0.00 V.What is E for the cell at 25<sup>o</sup>C? = 1.00 atm.The Fe2+/Fe half-cell reduction potential is -0.41 V,and the H+/H2 half-cell reduction potential is 0.00 V.What is E for the cell at 25oC?

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What is one of the major products in the electrolysis of a saturated aqueous sodium chloride solution? Reduction Half-Reaction E° (V) Na+(aq)+ e- What is one of the major products in the electrolysis of a saturated aqueous sodium chloride solution? Reduction Half-Reaction E° (V) Na<sup>+</sup>(aq)+ e<sup>-</sup>  Na(s) -2.71 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l)1.23 Cl<sub>2</sub>(g)+ 2e<sup>-</sup>  2Cl<sup>-</sup>(aq) 1.36Na(s) -2.71 Mg2+(aq)+ 2e- What is one of the major products in the electrolysis of a saturated aqueous sodium chloride solution? Reduction Half-Reaction E° (V) Na<sup>+</sup>(aq)+ e<sup>-</sup>  Na(s) -2.71 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l)1.23 Cl<sub>2</sub>(g)+ 2e<sup>-</sup>  2Cl<sup>-</sup>(aq) 1.36 Mg(s) -2.37 2H2O(l)+ 2e- What is one of the major products in the electrolysis of a saturated aqueous sodium chloride solution? Reduction Half-Reaction E° (V) Na<sup>+</sup>(aq)+ e<sup>-</sup>  Na(s) -2.71 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l)1.23 Cl<sub>2</sub>(g)+ 2e<sup>-</sup>  2Cl<sup>-</sup>(aq) 1.36H2(g)+ 2OH-(aq) -0.83 O2(g)+ 4H+(aq)+ 4e- What is one of the major products in the electrolysis of a saturated aqueous sodium chloride solution? Reduction Half-Reaction E° (V) Na<sup>+</sup>(aq)+ e<sup>-</sup>  Na(s) -2.71 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l)1.23 Cl<sub>2</sub>(g)+ 2e<sup>-</sup>  2Cl<sup>-</sup>(aq) 1.362H2O(l)1.23 Cl2(g)+ 2e- What is one of the major products in the electrolysis of a saturated aqueous sodium chloride solution? Reduction Half-Reaction E° (V) Na<sup>+</sup>(aq)+ e<sup>-</sup>  Na(s) -2.71 Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mg(s) -2.37 2H<sub>2</sub>O(l)+ 2e<sup>-</sup>  H<sub>2</sub>(g)+ 2OH<sup>-</sup>(aq) -0.83 O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>  2H<sub>2</sub>O(l)1.23 Cl<sub>2</sub>(g)+ 2e<sup>-</sup>  2Cl<sup>-</sup>(aq) 1.362Cl-(aq) 1.36

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Given: Li+(aq)+ e- Given: Li<sup>+</sup>(aq)+ e<sup>-</sup>  Li(s); E° = -3.04 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Fe<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Fe(s); E° = -0.41 V Ag<sup>+</sup>(aq)+ e<sup>-</sup>  Ag(s); E° = 0.80 V Br<sub>2</sub>(l)+ 2e<sup>-</sup>  2Br<sup>-</sup>(aq); E° = 1.07 V Which of the following species is the best oxidizing agent?Li(s); E° = -3.04 V Mg2+(aq)+ 2e- Given: Li<sup>+</sup>(aq)+ e<sup>-</sup>  Li(s); E° = -3.04 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Fe<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Fe(s); E° = -0.41 V Ag<sup>+</sup>(aq)+ e<sup>-</sup>  Ag(s); E° = 0.80 V Br<sub>2</sub>(l)+ 2e<sup>-</sup>  2Br<sup>-</sup>(aq); E° = 1.07 V Which of the following species is the best oxidizing agent?Mg(s); E° = -2.38 V Fe2+(aq)+ 2e- Given: Li<sup>+</sup>(aq)+ e<sup>-</sup>  Li(s); E° = -3.04 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Fe<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Fe(s); E° = -0.41 V Ag<sup>+</sup>(aq)+ e<sup>-</sup>  Ag(s); E° = 0.80 V Br<sub>2</sub>(l)+ 2e<sup>-</sup>  2Br<sup>-</sup>(aq); E° = 1.07 V Which of the following species is the best oxidizing agent?Fe(s); E° = -0.41 V Ag+(aq)+ e- Given: Li<sup>+</sup>(aq)+ e<sup>-</sup>  Li(s); E° = -3.04 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Fe<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Fe(s); E° = -0.41 V Ag<sup>+</sup>(aq)+ e<sup>-</sup>  Ag(s); E° = 0.80 V Br<sub>2</sub>(l)+ 2e<sup>-</sup>  2Br<sup>-</sup>(aq); E° = 1.07 V Which of the following species is the best oxidizing agent?Ag(s); E° = 0.80 V Br2(l)+ 2e- Given: Li<sup>+</sup>(aq)+ e<sup>-</sup>  Li(s); E° = -3.04 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Fe<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Fe(s); E° = -0.41 V Ag<sup>+</sup>(aq)+ e<sup>-</sup>  Ag(s); E° = 0.80 V Br<sub>2</sub>(l)+ 2e<sup>-</sup>  2Br<sup>-</sup>(aq); E° = 1.07 V Which of the following species is the best oxidizing agent?2Br-(aq); E° = 1.07 V Which of the following species is the best oxidizing agent?

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In the following electrochemical cell,what is the reduction half reaction? Mn(s)| Mn2+(aq)|| Fe3+(aq),Fe2+(aq)| Pt(s)

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The process of producing a chemical change in an electrolytic cell is called _____.

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What is the cell reaction for the following electrochemical cell? Zn | Zn2+(aq)|| Sc3+(aq)| Sc

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A piece of iron half-immersed in a sodium chloride solution will corrode more rapidly than a piece of iron half-immersed in pure water,because

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The cell potential of an electrochemical cell with the cell reaction 2Al(s)+ 3Zn2+(aq)→ 3Zn(s)+ 2Al3+(aq) Is 1.607 V.What is the maximum electrical work obtainable from this cell when 2.0 mol of Al is consumed?

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A voltaic cell is made by placing an iron electrode in a compartment in which the Fe2+ concentration is 2.0 × 10-5 M and by placing a Pt electrode in the other compartment,in which the H+ concentration is 3.4 M and A voltaic cell is made by placing an iron electrode in a compartment in which the Fe<sup>2+</sup> concentration is 2.0 × 10<sup>-5</sup> M and by placing a Pt electrode in the other compartment,in which the H<sup>+</sup> concentration is 3.4 M and   = 1.00 atm.The Fe<sup>2+</sup>/Fe half-cell reduction potential is -0.41 V,and the H<sup>+</sup>/H<sub>2</sub> half-cell reduction potential is 0.00 V.What is the value of E° for this cell,and which electrode is the anode? = 1.00 atm.The Fe2+/Fe half-cell reduction potential is -0.41 V,and the H+/H2 half-cell reduction potential is 0.00 V.What is the value of E° for this cell,and which electrode is the anode?

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An alkaline dry cell is similar to Leclanché cell,but it has _____ in place of ammonium chloride.

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If the cell is initially at standard-state conditions,which of the following statements is true? If the cell is initially at standard-state conditions,which of the following statements is true?   Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 V Zn2+(aq)+ 2e- If the cell is initially at standard-state conditions,which of the following statements is true?   Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 VZn(s); E° = -0.76 V Cu2+(aq)+ 2e- If the cell is initially at standard-state conditions,which of the following statements is true?   Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 VCu(s); E° = 0.34 V

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The _____ has zinc can as the anode; a graphite rod in the center,surrounded by a paste of manganese dioxide,ammonium and zinc chlorides,and carbon black,is the cathode.

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Given: W3+(aq)+ 3e- Given: W<sup>3+</sup>(aq)+ 3e<sup>-</sup>  W(s); E° = 2.72 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Ni<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Ni(s); E° = -0.23 V Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Under standard-state conditions,which of the following metals will reduce W<sup>3+</sup> to W but will not reduce Ni<sup>2+</sup> to Ni?W(s); E° = 2.72 V Pb2+(aq)+ 2e- Given: W<sup>3+</sup>(aq)+ 3e<sup>-</sup>  W(s); E° = 2.72 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Ni<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Ni(s); E° = -0.23 V Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Under standard-state conditions,which of the following metals will reduce W<sup>3+</sup> to W but will not reduce Ni<sup>2+</sup> to Ni?Pb(s); E° = -0.13 V Ni2+(aq)+ 2e- Given: W<sup>3+</sup>(aq)+ 3e<sup>-</sup>  W(s); E° = 2.72 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Ni<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Ni(s); E° = -0.23 V Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Under standard-state conditions,which of the following metals will reduce W<sup>3+</sup> to W but will not reduce Ni<sup>2+</sup> to Ni?Ni(s); E° = -0.23 V Cd2+(aq)+ 2e- Given: W<sup>3+</sup>(aq)+ 3e<sup>-</sup>  W(s); E° = 2.72 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Ni<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Ni(s); E° = -0.23 V Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Under standard-state conditions,which of the following metals will reduce W<sup>3+</sup> to W but will not reduce Ni<sup>2+</sup> to Ni?Cd(s); E° = -0.40 V Zn2+(aq)+ 2e- Given: W<sup>3+</sup>(aq)+ 3e<sup>-</sup>  W(s); E° = 2.72 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Ni<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Ni(s); E° = -0.23 V Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Under standard-state conditions,which of the following metals will reduce W<sup>3+</sup> to W but will not reduce Ni<sup>2+</sup> to Ni?Zn(s); E° = -0.76 V Al3+(aq)+ 3e- Given: W<sup>3+</sup>(aq)+ 3e<sup>-</sup>  W(s); E° = 2.72 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Ni<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Ni(s); E° = -0.23 V Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Under standard-state conditions,which of the following metals will reduce W<sup>3+</sup> to W but will not reduce Ni<sup>2+</sup> to Ni?Al(s); E° = -1.66 V Mg2+(aq)+ 2e- Given: W<sup>3+</sup>(aq)+ 3e<sup>-</sup>  W(s); E° = 2.72 V Pb<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Pb(s); E° = -0.13 V Ni<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Ni(s); E° = -0.23 V Cd<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cd(s); E° = -0.40 V Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>  Al(s); E° = -1.66 V Mg<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Mg(s); E° = -2.38 V Under standard-state conditions,which of the following metals will reduce W<sup>3+</sup> to W but will not reduce Ni<sup>2+</sup> to Ni?Mg(s); E° = -2.38 V Under standard-state conditions,which of the following metals will reduce W3+ to W but will not reduce Ni2+ to Ni?

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Given: Zn2+(aq)+ 2e- Given: Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 V Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq)+ 14H<sup>+</sup>(aq)+ 6e<sup>-</sup>  2Cr<sup>3+</sup>(aq)+ 7H<sub>2</sub>O(l); E° = 1.33 V Which of the following species is the strongest oxidizing agent?Zn(s); E° = -0.76 V Cu2+(aq)+ 2e- Given: Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 V Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq)+ 14H<sup>+</sup>(aq)+ 6e<sup>-</sup>  2Cr<sup>3+</sup>(aq)+ 7H<sub>2</sub>O(l); E° = 1.33 V Which of the following species is the strongest oxidizing agent?Cu(s); E° = 0.34 V Cr2O72-(aq)+ 14H+(aq)+ 6e- Given: Zn<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Zn(s); E° = -0.76 V Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>  Cu(s); E° = 0.34 V Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup>(aq)+ 14H<sup>+</sup>(aq)+ 6e<sup>-</sup>  2Cr<sup>3+</sup>(aq)+ 7H<sub>2</sub>O(l); E° = 1.33 V Which of the following species is the strongest oxidizing agent?2Cr3+(aq)+ 7H2O(l); E° = 1.33 V Which of the following species is the strongest oxidizing agent?

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