Exam 14: Thermodynamics: Spontaneous Processes, Entropy, and Free Energy

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Hydrochloric acid (HCl) reacts with sodium hydroxide (NaOH) to form sodium chloride (NaCl) and water. If H° = -56.13 kJ/mol and S° = 79.11 J/mol · K, what is G° for this reaction at 20°C?

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The dissolution of ammonium nitrate in water is a spontaneous endothermic process. It is spontaneous because the system undergoes __________

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The entropy change of the surroundings, Ssurr, is related to heat transfer q with respect to the system and temperature T by __________

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Indicate which one of the following reactions result in a positive Ssys.

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The heat of fusion for water is 333.6 J/g. What is the entropy change for the universe when 1.00 L of water at 0°C freezes at -5°C? Comment on the sign.

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Dinitrogen tetroxide (N2O4) decomposes to nitrogen dioxide (NO2). If H° = 58.02 kJ/mol and S° = 176.1 J/mol · K, at what temperature are reactants and products in their standard states at equilibrium?

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In a spontaneous process, the entropy of the universe ___________

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A reaction is at equilibrium at a given temperature and constant pressure when __________

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The gas above the liquid in a sealed bottle of soda is primarily carbon dioxide. Carbon dioxide is also dissolved in the soda. When the distribution of carbon dioxide between the gas and liquid is at equilibrium, molecules of carbon dioxide in the gas phase can still dissolve in the liquid phase if they strike the surface and are captured. Similarly molecules of carbon dioxide can escape from the liquid phase. What is the entropy change of the universe, "Suniv", for the dissolution of carbon dioxide under these conditions?

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At 0 K, the entropy of a perfect crystal is ___________

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If a reaction A B has G If a reaction A <font face=symbol></font> B has <font face=symbol></font>G   > 0, then when the reaction is at equilibrium there will be __________ > 0, then when the reaction is at equilibrium there will be __________

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Which of the following processes will lead to a decrease in the entropy of the system?

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In a spontaneous process, which of the following always increases?

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The entropy of vaporization of water is 109.0 J/mol · K. What is the enthalpy of vaporization of water at its normal boiling point?

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"Ssys" can be directly related to the heat q. Which of A-D is not true regarding this relationship? If all are true, select E.

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Determine the normal melting point of benzoic acid in degrees centigrade given the following data. H Determine the normal melting point of benzoic acid in degrees centigrade given the following data. <font face=symbol></font>H   = 18.02 kJ/mol <font face=symbol></font>S   = 45.56 J/mol · K = 18.02 kJ/mol S Determine the normal melting point of benzoic acid in degrees centigrade given the following data. <font face=symbol></font>H   = 18.02 kJ/mol <font face=symbol></font>S   = 45.56 J/mol · K = 45.56 J/mol · K

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The enthalpy of fusion for benzene is 127.40 kJ/kg, and its melting point is 5.5°C. What is the entropy change when 1 mole of benzene melts at 5.5°C?

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The heat of fusion for water is 333.6 J/g. What is the entropy change for the universe when 1.00 L of water at 0°C freezes at +5°C? Comment on the sign.

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A reaction with a low enthalpy of reaction value is not spontaneous at low temperature but becomes spontaneous at high temperature. What are the signs for H° and S°, respectively?

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The symbol G The symbol <font face=symbol></font>G   (CH<sub>4</sub>, g) refers to which of the following reactions? (CH4, g) refers to which of the following reactions?

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