Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions
Exam 1: Basic Concepts of Chemistry40 Questions
Exam 2: Lets Review: The Tools of Quantitative Chemistry67 Questions
Exam 3: Atoms, molecules, and Ions101 Questions
Exam 4: Chemical Reactions72 Questions
Exam 5: Stoichiometry: Quantitative Information About Chemical Reactions77 Questions
Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions65 Questions
Exam 7: The Structure of Atoms65 Questions
Exam 8: The Structure of Atoms and Periodic Trends80 Questions
Exam 9: Bonding and Molecular Structure89 Questions
Exam 10: Bonding and Molecular Structure Orbital Hybridization and Molecular Orbitals63 Questions
Exam 11: Gases and Their Properties89 Questions
Exam 12: Intermolecular Forces and Liquids69 Questions
Exam 13: The Solid State62 Questions
Exam 14: Solutions and Their Behavior79 Questions
Exam 15: Chemical Kinetics: the Rates of Chemical Reactions72 Questions
Exam 16: Principles of Chemical Reactivity: Equilibria77 Questions
Exam 17: Principles of Chemical Reactivity: the Chemistry of Acids and Bases95 Questions
Exam 17: Principles of Chemical Reactivity: Other Aspects of Aqueous Equilibria86 Questions
Exam 19: Principles of Chemical Reactivity: Entropy and Free Energy66 Questions
Exam 20: Principles of Chemical Reactivity: Electron Transfer Reactions86 Questions
Exam 21: Environmental Chemistry: Earths Environment, energy, and Sustainability51 Questions
Exam 22: The Chemistry of the Main Group Elements82 Questions
Exam 23: The Chemistry of the Transition Elements79 Questions
Exam 24: Carbon: Not Just Another Element88 Questions
Exam 25: Biochemistry48 Questions
Exam 26: Nuclear Chemistry190 Questions
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Which of the following reactions corresponds to the thermochemical equation for the standard molar enthalpy of formation of solid zinc nitrate?
(Multiple Choice)
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The specific heat capacity of water(liquid)is 4.18 J/g⋅°C.What is the molar specific heat capacity of this substance? The molar mass of water is 18.01 g/mol.
(Multiple Choice)
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Many homes are heated using natural gas.The combustion of natural gas converts
(Multiple Choice)
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What is the change in internal energy of the system (ΔU)if 65 kJ of heat energy is evolved by the system and 62 kJ of work is done on the system for a certain process?
(Multiple Choice)
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CaO(s)reacts with water to form Ca(OH)2(aq).If 6.50 g CaO is combined with 99.70 g H2O in a coffee cup calorimeter,the temperature of the resulting solution increases from 21.7 °C to 43.1 °C.Calculate the enthalpy change for the reaction per mole of CaO.Assume that the specific heat capacity of the solution is 4.18 J/g⋅K.
(Multiple Choice)
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What is the overall chemical equation that results from the sum of the given steps?
2 C(s)+ 2 H2O(g)→ 2 CO(g)+ 2 H2(g)
CO(g)+ H2O(g)→ CO2(g)+ H2(g)
CO(g)+ 3 H2(g)→ CH4(g)+ H2O(g)
(Multiple Choice)
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When 1 mole of Fe2O3(s)reacts with H2(g)to form Fe(s)and H2O(g)by the following reaction,98.8 kJ of energy is absorbed. Fe2O3(s)+ 3 H2(g)→ 2 Fe(s)+ 3 H2O(g)
(A)
(B)
Is the reaction endothermic or exothermic,and which of the enthalpy diagrams above
Represents this reaction?


(Multiple Choice)
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How much energy is needed to convert 50.8 g of ice at 0.00 °C to liquid water at 75.0 °C? Specific heat capacity (ice)= 2.10 J/g °C
Specific heat capacity (liquid water)= 4.18 J/g °C
Heat of fusion = 333 J/g
Heat of vaporization = 2258 J/g
(Multiple Choice)
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Calculate the energy in the form of heat (in kJ)required to change 76.9 g of liquid water at 25.2 °C to ice at -15.2 °C.Assume that no energy in the form of heat is transferred to the environment.(Heat of fusion = 333 J/g; heat of vaporization = 2256 J/g; specific heat capacities: ice = 2.06 J/g⋅K,liquid water = 4.184 J/g⋅K)
(Multiple Choice)
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Which of the following has zero standard enthalpy of formation at 25 °C?
(Multiple Choice)
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Combustion of 2.14 g of liquid benzene (C6H6)causes a temperature rise of 16.2 °C in a constant-pressure calorimeter that has a heat capacity of 5.53 kJ/°C.What is ΔH for the following reaction? C6H6(l)+
O2(g)→ 6 CO2(g)+ 3 H2O(
)


(Multiple Choice)
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Determine the enthalpy change for the decomposition of calcium carbonate CaCO3(s)→ CaO(s)+ CO2(g)
Given the thermochemical equations below.
Ca(OH)2(s)→ CaO(s)+ H2O(
)
ΔrH° = 65.2 kJ/mol-rxn
Ca(OH)2(s)+ CO2(g)→ CaCO3(s)+ H2O(
)
ΔrH° = −113.8 kJ/mol-rxn
C(s)+ O2(g)→ CO2(g)
ΔrH° = −393.5 kJ/mol-rxn
2 Ca(s)+ O2(g)→ 2 CaO(s)
ΔrH° = −1270.2 kJ/mol-rxn


(Multiple Choice)
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How much heat is liberated at constant pressure if 0.515 g of calcium carbonate reacts with 32.7 mL of 0.498 M hydrochloric acid? CaCO3(s)+ 2HCl(aq)→ CaCl2(aq)+ H2O(l)+ CO2(g); ΔrH° = -15.2 kJ/mol-rxn
(Multiple Choice)
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Commercial cold packs consist of solid ammonium nitrate and water.NH4NO3 absorbs 25.69 kJ of heat per mole dissolved in water.In a coffee-cup calorimeter,5.60 g NH4NO3 is dissolved in 100.0 g of water at 22.0 °C.What is the final temperature of the solution? Assume that the solution has a specific heat capacity of 4.18 J/g⋅K.
(Multiple Choice)
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When 50.0 mL of 1.60 M of HCl(aq)is combined with 50.0 mL of 1.70 M of NaOH(aq)in a coffee-cup calorimeter,the temperature of the solution increases by 10.7°C.What is the change in enthalpy for this balanced reaction? HCl(aq)+ NaOH(aq)→ NaCl(aq)+ H2O(
)
Assume that the solution density is 1.00 g/mL and the specific heat capacity of the solution is 4.18 J/g⋅°C.

(Multiple Choice)
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The energy associated with a stretched spring is called _____.
(Multiple Choice)
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What quantity,in moles,of hydrogen is consumed when 179.6 kJ of energy is evolved from the combustion of a mixture of H2(g)and O2(g)? H2(g)+
O2(g)→ H2O(l); ΔrH° = -285.8 kJ/mol-rxn

(Multiple Choice)
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A 170.0-g sample of metal at 83.00°C is added to 170.0 g of H2O(l)at 15.00°C in an insulated container.The temperature rises to 18.16°C.Neglecting the heat capacity of the container,what is the specific heat capacity of the metal? The specific heat capacity of H2O(l)is 4.18 J/(g·°C).
(Multiple Choice)
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