Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions

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Which of the following reactions corresponds to the thermochemical equation for the standard molar enthalpy of formation of solid zinc nitrate?

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The specific heat capacity of water(liquid)is 4.18 J/g⋅°C.What is the molar specific heat capacity of this substance? The molar mass of water is 18.01 g/mol.

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Which one of the following statements is INCORRECT?

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Many homes are heated using natural gas.The combustion of natural gas converts

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What is the change in internal energy of the system (ΔU)if 65 kJ of heat energy is evolved by the system and 62 kJ of work is done on the system for a certain process?

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CaO(s)reacts with water to form Ca(OH)2(aq).If 6.50 g CaO is combined with 99.70 g H2O in a coffee cup calorimeter,the temperature of the resulting solution increases from 21.7 °C to 43.1 °C.Calculate the enthalpy change for the reaction per mole of CaO.Assume that the specific heat capacity of the solution is 4.18 J/g⋅K.

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What is the overall chemical equation that results from the sum of the given steps? ​ 2 C(s)+ 2 H2O(g)→ 2 CO(g)+ 2 H2(g) CO(g)+ H2O(g)→ CO2(g)+ H2(g) CO(g)+ 3 H2(g)→ CH4(g)+ H2O(g) ​

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When 1 mole of Fe2O3(s)reacts with H2(g)to form Fe(s)and H2O(g)by the following reaction,98.8 kJ of energy is absorbed. Fe2O3(s)+ 3 H2(g)→ 2 Fe(s)+ 3 H2O(g) When 1 mole of Fe<sub>2</sub>O<sub>3</sub>(s)reacts with H<sub>2</sub>(g)to form Fe(s)and H<sub>2</sub>O(g)by the following reaction,98.8 kJ of energy is absorbed. Fe<sub>2</sub>O<sub>3</sub>(s)+ 3 H<sub>2</sub>(g)→ 2 Fe(s)+ 3 H<sub>2</sub>O(g)     (A) (B) Is the reaction endothermic or exothermic,and which of the enthalpy diagrams above Represents this reaction? When 1 mole of Fe<sub>2</sub>O<sub>3</sub>(s)reacts with H<sub>2</sub>(g)to form Fe(s)and H<sub>2</sub>O(g)by the following reaction,98.8 kJ of energy is absorbed. Fe<sub>2</sub>O<sub>3</sub>(s)+ 3 H<sub>2</sub>(g)→ 2 Fe(s)+ 3 H<sub>2</sub>O(g)     (A) (B) Is the reaction endothermic or exothermic,and which of the enthalpy diagrams above Represents this reaction? (A) (B) Is the reaction endothermic or exothermic,and which of the enthalpy diagrams above Represents this reaction?

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Specific heat capacity is

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How much energy is needed to convert 50.8 g of ice at 0.00 °C to liquid water at 75.0 °C? Specific heat capacity (ice)= 2.10 J/g °C Specific heat capacity (liquid water)= 4.18 J/g °C Heat of fusion = 333 J/g Heat of vaporization = 2258 J/g

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Calculate the energy in the form of heat (in kJ)required to change 76.9 g of liquid water at 25.2 °C to ice at -15.2 °C.Assume that no energy in the form of heat is transferred to the environment.(Heat of fusion = 333 J/g; heat of vaporization = 2256 J/g; specific heat capacities: ice = 2.06 J/g⋅K,liquid water = 4.184 J/g⋅K)

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Which of the following has zero standard enthalpy of formation at 25 °C?

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Combustion of 2.14 g of liquid benzene (C6H6)causes a temperature rise of 16.2 °C in a constant-pressure calorimeter that has a heat capacity of 5.53 kJ/°C.What is ΔH for the following reaction? C6H6(l)+ Combustion of 2.14 g of liquid benzene (C<sub>6</sub>H<sub>6</sub>)causes a temperature rise of 16.2 °C in a constant-pressure calorimeter that has a heat capacity of 5.53 kJ/°C.What is ΔH for the following reaction? C<sub>6</sub>H<sub>6</sub>(l)+   O<sub>2</sub>(g)→ 6 CO<sub>2</sub>(g)+ 3 H<sub>2</sub>O(   ) O2(g)→ 6 CO2(g)+ 3 H2O( Combustion of 2.14 g of liquid benzene (C<sub>6</sub>H<sub>6</sub>)causes a temperature rise of 16.2 °C in a constant-pressure calorimeter that has a heat capacity of 5.53 kJ/°C.What is ΔH for the following reaction? C<sub>6</sub>H<sub>6</sub>(l)+   O<sub>2</sub>(g)→ 6 CO<sub>2</sub>(g)+ 3 H<sub>2</sub>O(   ) )

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Determine the enthalpy change for the decomposition of calcium carbonate CaCO3(s)→ CaO(s)+ CO2(g) Given the thermochemical equations below. Ca(OH)2(s)→ CaO(s)+ H2O( Determine the enthalpy change for the decomposition of calcium carbonate CaCO<sub>3</sub>(s)→ CaO(s)+ CO<sub>2</sub>(g) Given the thermochemical equations below. Ca(OH)<sub>2</sub>(s)→ CaO(s)+ H<sub>2</sub>O(   ) Δ<sub>r</sub>H° = 65.2 kJ/mol-rxn Ca(OH)<sub>2</sub>(s)+ CO<sub>2</sub>(g)→ CaCO<sub>3</sub>(s)+ H<sub>2</sub>O(   ) Δ<sub>r</sub>H° = −113.8 kJ/mol-rxn C(s)+ O<sub>2</sub>(g)→ CO<sub>2</sub>(g) Δ<sub>r</sub>H° = −393.5 kJ/mol-rxn 2 Ca(s)+ O<sub>2</sub>(g)→ 2 CaO(s) Δ<sub>r</sub>H° = −1270.2 kJ/mol-rxn ) ΔrH° = 65.2 kJ/mol-rxn Ca(OH)2(s)+ CO2(g)→ CaCO3(s)+ H2O( Determine the enthalpy change for the decomposition of calcium carbonate CaCO<sub>3</sub>(s)→ CaO(s)+ CO<sub>2</sub>(g) Given the thermochemical equations below. Ca(OH)<sub>2</sub>(s)→ CaO(s)+ H<sub>2</sub>O(   ) Δ<sub>r</sub>H° = 65.2 kJ/mol-rxn Ca(OH)<sub>2</sub>(s)+ CO<sub>2</sub>(g)→ CaCO<sub>3</sub>(s)+ H<sub>2</sub>O(   ) Δ<sub>r</sub>H° = −113.8 kJ/mol-rxn C(s)+ O<sub>2</sub>(g)→ CO<sub>2</sub>(g) Δ<sub>r</sub>H° = −393.5 kJ/mol-rxn 2 Ca(s)+ O<sub>2</sub>(g)→ 2 CaO(s) Δ<sub>r</sub>H° = −1270.2 kJ/mol-rxn ) ΔrH° = −113.8 kJ/mol-rxn C(s)+ O2(g)→ CO2(g) ΔrH° = −393.5 kJ/mol-rxn 2 Ca(s)+ O2(g)→ 2 CaO(s) ΔrH° = −1270.2 kJ/mol-rxn

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How much heat is liberated at constant pressure if 0.515 g of calcium carbonate reacts with 32.7 mL of 0.498 M hydrochloric acid? CaCO3(s)+ 2HCl(aq)→ CaCl2(aq)+ H2O(l)+ CO2(g); ΔrH° = -15.2 kJ/mol-rxn

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Commercial cold packs consist of solid ammonium nitrate and water.NH4NO3 absorbs 25.69 kJ of heat per mole dissolved in water.In a coffee-cup calorimeter,5.60 g NH4NO3 is dissolved in 100.0 g of water at 22.0 °C.What is the final temperature of the solution? Assume that the solution has a specific heat capacity of 4.18 J/g⋅K.

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When 50.0 mL of 1.60 M of HCl(aq)is combined with 50.0 mL of 1.70 M of NaOH(aq)in a coffee-cup calorimeter,the temperature of the solution increases by 10.7°C.What is the change in enthalpy for this balanced reaction? HCl(aq)+ NaOH(aq)→ NaCl(aq)+ H2O( When 50.0 mL of 1.60 M of HCl(aq)is combined with 50.0 mL of 1.70 M of NaOH(aq)in a coffee-cup calorimeter,the temperature of the solution increases by 10.7°C.What is the change in enthalpy for this balanced reaction? HCl(aq)+ NaOH(aq)→ NaCl(aq)+ H<sub>2</sub>O(   ) Assume that the solution density is 1.00 g/mL and the specific heat capacity of the solution is 4.18 J/g⋅°C. ) Assume that the solution density is 1.00 g/mL and the specific heat capacity of the solution is 4.18 J/g⋅°C.

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The energy associated with a stretched spring is called _____.

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What quantity,in moles,of hydrogen is consumed when 179.6 kJ of energy is evolved from the combustion of a mixture of H2(g)and O2(g)? H2(g)+ What quantity,in moles,of hydrogen is consumed when 179.6 kJ of energy is evolved from the combustion of a mixture of H<sub>2</sub>(g)and O<sub>2</sub>(g)? H<sub>2</sub>(g)+   O<sub>2</sub>(g)→ H<sub>2</sub>O(l); Δ<sub>r</sub>H° = -285.8 kJ/mol-rxn O2(g)→ H2O(l); ΔrH° = -285.8 kJ/mol-rxn

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A 170.0-g sample of metal at 83.00°C is added to 170.0 g of H2O(l)at 15.00°C in an insulated container.The temperature rises to 18.16°C.Neglecting the heat capacity of the container,what is the specific heat capacity of the metal? The specific heat capacity of H2O(l)is 4.18 J/(g·°C).

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