Exam 7: Thermochemistry

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Combine the reactions: P4(s)+ 6 Cl2(g)→ 4 PCl3(g)Δr298 = -1225.0 kJ/mol PCl3(g)+ 3 H2O(l)→ H3PO3(aq)+ 3 HCl(g)= -853.5 kJ/mol 2 H2(g)+ O2(g)→ 2 H2O(l)= -571.5 kJ/mol H2(g)+ Cl2(g)→ 2 HCl(g)= -184.9 kJ/mol To obtain the reaction: P4(s)+ 6 H2(g)+ 6 O2(g)→ 4 H3PO3(aq). What is the value of Δr298 for this reaction?

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B

A 12-inch diameter ball of pure cobalt metal at 225 °C was placed in 10.0 gal.of water at 15.0 °C.What is the final temperature of the water? Assume no heat is lost to the surroundings.(specific heat for cobalt is 0.421 J/g °C,density of cobalt = 8.862 g/cm3,1 gal.= 3.785 L,1 in = 2.54 cm,V(sphere)= 4/3 πr3)

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C

Calculate the enthalpy change for the following reaction at 25 °C.The value of ΔfH° in kJ/mol is given below each species: Calculate the enthalpy change for the following reaction at 25 °C.The value of Δ<sub>f</sub>H° in kJ/mol is given below each species:

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B

The standard heat of formation of solid ammonium bromide is -270.8 kJ/mol.Write the chemical equation for the reaction to which this value applies.

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A 50.0 g sample of liquid water at 25.0 °C is mixed with 23.0 g of water at 89.0 °C.The final temperature of the water is ________ °C.

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Enthalpy is defined as:

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An expansion of gas by a system means that the system does work.

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The complete combustion of 1 mole of nitrobenzene,C6H5NO2,in a bomb calorimeter liberates 3088 kJ of heat and increases the temperature of the calorimeter assembly by 140.0 °C.What is the heat capacity of this bomb calorimeter?

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The final temperature when 150 mL of water at 90.0 °C is added to 100.0 mL of water at 30.0 °C is around ________.

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Lead,water,sulfur and arsenic have specific heats of 0.128,4.18,0.706,and 0.329 J g-1 °C-1,respectively.Which of the following would need the smallest quantity of heat to change the temperature of 5 g by 10 °C?

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Calculate the standard enthalpy of formation of Cl-(aq),given the following thermochemical data at 1 atm,and knowing that the standard enthalpies of formation of H2(g)and H+(aq)are both zero. HCl(g)→ H+(aq)+ Cl-(aq)ΔrH° = -75.15 kJ/mol H2(g)+ Cl2(g)→ 2HCl(g)ΔrH° = -184.62 kJ/mol

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Heat is usually transferred from a cold object to a hot object.

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When 2.50 g of Ba(s)is added to 100.00 g of water in a container open to the atmosphere,the reaction shown below occurs and the temperature of the resulting solution rises from 22.00 °C to 40.32 °C.If the specific heat of the solution is 4.18 J g-1°C-1 ,calculate When 2.50 g of Ba(s)is added to 100.00 g of water in a container open to the atmosphere,the reaction shown below occurs and the temperature of the resulting solution rises from 22.00 °C to 40.32 °C.If the specific heat of the solution is 4.18 J g<sup>-1</sup>°C<sup>-1</sup> ,calculate    For the reaction,as written. Ba(s)+ 2 H<sub>2</sub>O(l)→ Ba(OH)<sub>2</sub>(aq)+ H<sub>2</sub>(g)     = ? For the reaction,as written. Ba(s)+ 2 H2O(l)→ Ba(OH)2(aq)+ H2(g) When 2.50 g of Ba(s)is added to 100.00 g of water in a container open to the atmosphere,the reaction shown below occurs and the temperature of the resulting solution rises from 22.00 °C to 40.32 °C.If the specific heat of the solution is 4.18 J g<sup>-1</sup>°C<sup>-1</sup> ,calculate    For the reaction,as written. Ba(s)+ 2 H<sub>2</sub>O(l)→ Ba(OH)<sub>2</sub>(aq)+ H<sub>2</sub>(g)     = ? = ?

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How much heat is absorbed/released when 40.00 g of NH3(g)reacts in the presence of excess O2(g) to produce NO(g)and H2O(l)according to the following chemical equation? 4 NH3(g)+ 5 O2(g)→ 4 NO(g)+ 6 H2O(l) How much heat is absorbed/released when 40.00 g of NH<sub>3</sub>(g)reacts in the presence of excess O<sub>2</sub>(g) to produce NO(g)and H<sub>2</sub>O(l)according to the following chemical equation? 4 NH<sub>3</sub>(g)+ 5 O<sub>2</sub>(g)→ 4 NO(g)+ 6 H<sub>2</sub>O(l)    H° = 1168 kJ H° = 1168 kJ

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What is the final temperature in the bomb calorimeter if 1.785 grams of benzoic acid (C6H5COOH)is combusted in a calorimeter with a heat capacity of 5.02 kJ/ °C and initial temperature of 24.62 °C? The heat of combustion of benzoic acid is -26.42 kJ/g.

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The combustion of titanium with oxygen produces titanium dioxide: Ti(s)+ O2(g)→TiO2 (s) When 2.060 g of titanium is combusted in a bomb calorimeter,the temperature of the calorimeter increases from 25.00 °C to 91.60 °C.In a separate experiment,the heat capacity of the calorimeter is measured to be 9.84 kJK-1 .The heat of reaction for the combustion of a mole of Ti in this calorimeter is ________ kJ mol-1.

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What is the work done in joules by the system when H2 expands against a constant pressure of 75 atm at 45.3 °C? The change in volume is 24.0 L.

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What is the reaction for the standard enthalpy of formation for HCl(g)?

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Calculate the amount of heat absorbed by a 40.0 g sample of water at 21 °C when the temperature is raised to 35 °C.

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When power was turned off to a 30.0 gal.water heater,the temperature of the water dropped from 75.0 °C to 22.5 °C.How much heat was lost to the surroundings?

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