Exam 17: Additional Aspects of Acidbase Equilibria

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What mass of sodium acetate should be dissolved in 250.0 mL of 0.30 M aqueous acetic acid to form a buffer of pH 5.0? (Ka for acetic acid is 1.8 × 10-5)

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What is the pH of a buffer system prepared by dissolving 10.70 grams of NH4Cl and 25.00 mL of 12 mol L-1 NH3 in enough water to make 1.000 L of solution? Kb = 1.80 × 10-5 for NH3.

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25 mL of 0.10 M aqueous acetic acid is titrated with 0.10 M NaOH(aq).What is the pH at the equivalence point? Ka for acetic acid = 1.8 × 10-5.

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Why do we avoid titrating ammonia with acetic acid?

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In the titration of 50.0 mL of 0.0200 M C6H5COOH(aq)with 0.100 M NaOH(aq),what is/are the major species in the solution after the addition of 5.0 mL of NaOH(aq)?

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What is the pH of the resulting solution if 45 mL of 0.432 mol L-1 aqueous methylamine,CH3NH2,is added to 15 mL of 0.234 mol L-1 HCl(aq)? Assume that the volumes of the solutions are additive.Ka = 2.70 × 10-11 for CH3NH3+.

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Calculate the pH of a 1.00 L solution of 0.100 M NH3(aq)after the addition of 0.010 mol NH4Cl(s).For NH3,pKb = 4.74.

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If 25 mL of 0.20 M NaOH(aq)is added to 50 mL of 0.10 M aqueous HC2H3O2 (Ka = 1.8 × 10-5),what is the pH?

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An acid has a Ka = 1 × 10-6.At what pH would this acid and its corresponding salt make a good buffer?

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What is the pH of an aqueous solution prepared by mixing 50.00 mL of 0.10 mol L-1 NH3 with 5.00 mL of 0.10 mol L-1 NH4Cl? Assume that the volume of the solutions are additive and that Kb = 1.8 × 10-5 for NH3.

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What is the [CH3COO-]/[CH3COOH] ratio necessary to make an aqueous buffer solution with a pH of 4.34? Ka = 1.8 × 10-5 for CH3COOH.

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Which among the following pairs is inefficient as buffer pair?

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Twenty-five milliliters of 0.10 M HCl(aq)is titrated with 0.10 M NaOH(aq).What is the pH when 30 mL of NaOH(aq)have been added?

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Calculate the pH of an aqueous solution that is 0.210 mol L-1 in nitrous acid ( Calculate the pH of an aqueous solution that is 0.210 mol L<sup>-1</sup> in nitrous acid (   ) and 0.290 mol L<sup>-1</sup> in potassium nitrite (   ).The acid dissociation constant of nitrous acid is 4.50 ×   . ) and 0.290 mol L-1 in potassium nitrite ( Calculate the pH of an aqueous solution that is 0.210 mol L<sup>-1</sup> in nitrous acid (   ) and 0.290 mol L<sup>-1</sup> in potassium nitrite (   ).The acid dissociation constant of nitrous acid is 4.50 ×   . ).The acid dissociation constant of nitrous acid is 4.50 × Calculate the pH of an aqueous solution that is 0.210 mol L<sup>-1</sup> in nitrous acid (   ) and 0.290 mol L<sup>-1</sup> in potassium nitrite (   ).The acid dissociation constant of nitrous acid is 4.50 ×   . .

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Determine the [F-] of the following aqueous solution.Initial concentrations are given. [HF] = 1.296 M,[NaF] = 1.045 M,Ka for HF is 6.6 × 10-4

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The pH of a buffer solution changes only slightly with addition of a small amount of acid or base.

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How will addition of sodium chloride affect the pH of a HCl(aq)solution?

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What is the pH of a 0.30 M aqueous trisodium phosphate solution? Ka for monohydrogen phosphate ion is 4.2 × 10-13

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Which of the following statements correctly describe a typical titration curve for the titration of a strong acid by a strong base? I.The beginning pH is low. II.The pH change is slow until near the equivalence point. III.At the equivalence point,pH changes by a large value. IV.Beyond the equivalence point,pH rises rapidly. V.The equivalence point would be at a pH less than 3.5.

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Calculate the pH of an aqueous solution that is 1.0 M Na2CO3.Ka2 for H2CO3 is 4.7 × 10-11.

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