Exam 17: Additional Aspects of Acidbase Equilibria

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A pH 4.88 buffer was prepared by dissolving 0.10 mol of benzoic acid (Ka = 6.3 × 10-5)and 0.50 mol of sodium benzoate in sufficient pure water to form a 1.00 L solution.To a 70.0 mL aliquot of this solution was added 2.00 mL of 2.00 M aqueous HI solution.What was the pH of the new 72.0 mL solution?

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What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous hydrofluoric acid requires 30.00 mL of 0.400 mol L-1 NaOH(aq)? Ka = 6.76 × 10-4 for HF.

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What is the pH of a solution made by mixing 30.00 mL of 0.10 mol L-1 aqueous acetic acid (CH3COOH)with 50.00 mL of 0.100 mol L-1 KOH(aq)? Assume that the volumes of the solutions are additive.Ka = 1.8 × 10-5 for CH3COOH

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What volume of 5.00 × 10-3 mol L-1 HNO3(aq)is needed to titrate 80.00 mL of 5.00 × 10-3 mol L-1 Ca(OH)2(aq)to the equivalence point?

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A salt of a polyprotic acid such as NaHCO3 cannot act as a source of an acid.

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An aqueous solution has [HC7H5O2] = 0.100 M and [Ca(C7H5O2)2] = 0.200 M.Ka = 6.3 × 10-5 for HC7H5O2.The solution volume is 5.00 L.What is the pH of this solution after 5.00 mL 10.0 M HCl(aq)is added?

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A 25.0 mL sample of 0.150 mol L-1 aqueous hypochlorous acid is titrated with a 0.150 mol L-1 NaOH(aq)solution.What is the pH after 26.0 mL of base is added? The A 25.0 mL sample of 0.150 mol L<sup>-1</sup> aqueous hypochlorous acid is titrated with a 0.150 mol L<sup>-1</sup> NaOH(aq)solution.What is the pH after 26.0 mL of base is added? The   Of hypochlorous acid is 3.0 × 10<sup>-8</sup>. Of hypochlorous acid is 3.0 × 10-8.

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What is the pH of a buffer solution prepared by dissolving 25.5 g NaC2H3O2 in a sufficient volume of 0.550 M aqueous HC2H3O2 to make 500.0 mL of buffer?

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Determine the pH of the following aqueous solution.Initial concentrations are given. [NH3] = 1.20 M,[KOH] = 0.320 M,Kb for NH3= 1.8 × 10-5

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Determine the pH of the following aqueous solution.Initial concentrations are given. [HC2H3O2] = 0.250 M,[NaC2H3O2] = 0.120 M ,Ka ( acetic acid)= 1.8 × 10-5

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A 25.0 mL sample of 0.150 mol L-1 aqueous hydrofluoric acid is titrated with a 0.150 mol L-1 NaOH(aq)solution.What is the pH at the equivalence point? The A 25.0 mL sample of 0.150 mol L<sup>-1</sup> aqueous hydrofluoric acid is titrated with a 0.150 mol L<sup>-1</sup> NaOH(aq)solution.What is the pH at the equivalence point? The   Of hydrofluoric acid is 3.5 × 10<sup>-4</sup>. Of hydrofluoric acid is 3.5 × 10-4.

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A handbook states that to prepare a particular buffer solution mix 63.0 mL of 0.200 M aqueous HC2H3O2 with 37.0 mL of 0.200 M aqueous NaC2H3O2.What is the pH of this buffer? (Ka = 1.8 × 10-5)

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Choose the expression that gives the molar concentration of a H2SO4(aq)solution if 24.3 mL of a 0.105 M NaOH(aq)solution is required to titrate 60 mL of the acid.

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For an accurate titration,the end point needs to match the equivalence point.

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What is the change in pH after addition of 10.0 mL of 1.0 M aqueous sodium hydroxide to 90.0 mL of an aqueous 1.0 M NH3/1.0 M NH4+ buffer? (Kb for ammonia is 1.8 × 10-5)

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A pH 9.56 buffer was prepared by mixing 2.00 moles of ammonia (Kb for ammonia is 1.8 × 10-5)and 1.00 mol of ammonium chloride in water to form a solution with a volume of 1.00 L.To a 200.0 mL aliquot of this solution was added 10.0 mL of 10.0 M aqueous sodium hydroxide.What was the resulting pH?

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25 mL of 0.10 M aqueous acetic acid is titrated with 0.10 M NaOH(aq).What is the pH after 15 mL of NaOH(aq)have been added? Ka for acetic acid = 1.8 × 10-5.

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What is the pH of a buffer solution that is 0.255 mol L-1 in hypochlorous acid (HClO)and 0.333 mol L-1 in sodium hypochlorite (NaClO)? The What is the pH of a buffer solution that is 0.255 mol L<sup>-1</sup> in hypochlorous acid (HClO)and 0.333 mol L<sup>-1</sup> in sodium hypochlorite (NaClO)?  The   Of hypochlorous acid is 3.8 ×   . Of hypochlorous acid is 3.8 × What is the pH of a buffer solution that is 0.255 mol L<sup>-1</sup> in hypochlorous acid (HClO)and 0.333 mol L<sup>-1</sup> in sodium hypochlorite (NaClO)?  The   Of hypochlorous acid is 3.8 ×   . .

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An aqueous solution has [HC7H5O2] = 0.100 M and [Ca(C7H5O2)2] = 0.200 M.Ka = 6.3 × 10-5 for HC7H5O2.The solution volume is 5.00 L.What is the pH of the solution after 10.00 mL of 5.00 M NaOH is added?

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1.80 grams of an impure mixture containing sodium carbonate required 84.0 mL of 0.125 M H2SO4(aq)for complete neutralization.What percent of the mixture is sodium carbonate?

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