Exam 17: Additional Aspects of Acidbase Equilibria

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For the following titration,determine whether the solution at the equivalence point is acidic,basic or neutral and why: HCl(aq)is titrated with NH3(aq)

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What is the pH of a buffer that is 0.88 M HCN(aq)and 0.53 M NaCN(aq)? The Ka of HCN is 6.2 × 10-10.

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Formic acid (HCOOH,Ka = 1.8 × 10-4)is the principal component in the venom of stinging ants.What is the molarity of a formic acid solution if 25.00 mL of the aqueous formic acid solution requires 29.80 mL of 0.0567 mol L-1 NaOH(aq)to reach the equivalence point?

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For the following titration,determine whether the solution at the equivalence point is acidic,basic or neutral and why: KOH(aq)is titrated with HI(aq)

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How will addition of sodium acetate to an aqueous acetic acid solution affect the pH?

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Determine the pH of the following aqueous solution.Initial concentrations are given. [HF] = 1.296 M,[NaF] = 1.045 M,Ka for HF is 6.6 × 10-4

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The Henderson-Hasselbach equation,used to calculate the pH of simple conjugate-pair buffer systems,would be expressed for an ammonia/ammonium chloride buffer,for which Kb(NH3)is 1.8 × 10-5,as:

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Calculate the percent ionization of nitrous acid in an aqueous solution that is 0.266 mol L-1 in nitrous acid Calculate the percent ionization of nitrous acid in an aqueous solution that is 0.266 mol L<sup>-1</sup> in nitrous acid   And 0.112 mol L<sup>-1</sup> in potassium nitrite (   ).The acid dissociation constant of nitrous acid is  And 0.112 mol L-1 in potassium nitrite ( Calculate the percent ionization of nitrous acid in an aqueous solution that is 0.266 mol L<sup>-1</sup> in nitrous acid   And 0.112 mol L<sup>-1</sup> in potassium nitrite (   ).The acid dissociation constant of nitrous acid is  ).The acid dissociation constant of nitrous acid is Calculate the percent ionization of nitrous acid in an aqueous solution that is 0.266 mol L<sup>-1</sup> in nitrous acid   And 0.112 mol L<sup>-1</sup> in potassium nitrite (   ).The acid dissociation constant of nitrous acid is

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Acid-base indicators have two forms: an acid of one color and a base of another color.

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An aqueous solution is prepared by dissolving 0.23 mol of nitrous acid and 0.27 mol of sodium nitrite in water sufficient to yield 1.00 L of solution.The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly.The pH does not decrease drastically because the HCl reacts with the ________ present in the buffer solution.The An aqueous solution is prepared by dissolving 0.23 mol of nitrous acid and 0.27 mol of sodium nitrite in water sufficient to yield 1.00 L of solution.The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly.The pH does not decrease drastically because the HCl reacts with the ________ present in the buffer solution.The   Of nitrous acid is 1.36 × 10<sup>-3</sup>. Of nitrous acid is 1.36 × 10-3.

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The buffer capacity of a solution may be defined as the number of moles of H+ that will change the pH of 1.00 L of the buffer by 1.00 pH units.What is the buffer capacity of an aqueous solution which is 0.10 M in acetic acid (Ka = 1.8 × 10-5)and 0.30 M in sodium acetate,in units of mol (H+)per liter?

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Twenty-five milliliters of 0.10 M HCl(aq)is titrated with 0.10 M NaOH(aq).What is the pH before any NaOH(aq)is added?

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Which of the following can act as buffer solutions? I.0.1 M HC2H3O2/0.1 M NaC2H3O2 II.0.1 M NH3/0.1 M NH4Cl III.0.1 M HNO3/0.1 M NaNO3 IV.0.1 M H2SO3/0.1 M NaHSO3 V.0.1 M KHSO4/ 0.1 M H2SO4

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What will the pH at the neutralization point of 0.00812 M Ba(OH)2(aq)be when titrated with HCl(aq)?

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A buffer was prepared by adding 2.4 g of ammonium nitrate to 100.0 mL of 0.30 M aqueous ammonia (Kb = 1.8 × 10-5).To this solution was then added 10.0 mL of 0.30 M aqueous sodium hydroxide,which caused a pH change of ________.

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An aqueous solution containing equimolar amounts of a weak acid with Ka = 10-5 and its sodium salt has:

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25 mL of 0.10 M aqueous acetic acid is titrated with 0.10 M NaOH(aq).What is the pH after 30 mL of NaOH have been added? Ka for acetic acid = 1.8 × 10-5.

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If 30.0 mmol HCl(g)is added to 1.00 L of a buffer that is 0.340 M NH3(aq)and 0.290 M NH4Cl(aq),what are the final concentrations of NH3(aq)and NH4Cl(aq),respectively? Assume no volume change.

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What is the hydronium ion concentration in an aqueous solution prepared by mixing 50.00 mL of 0.10 mol L-1 HCN with 50.00 mL of 0.010 mol L-1 NaCN? Assume that the volumes of the solutions are additive and that Ka = What is the hydronium ion concentration in an aqueous solution prepared by mixing 50.00 mL of 0.10 mol L<sup>-1</sup> HCN with 50.00 mL of 0.010 mol L<sup>-1</sup> NaCN? Assume that the volumes of the solutions are additive and that K<sub>a</sub> =

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For HClO2,Ka = 1.2 × 10-2.What is the pH of an aqueous solution in which [NaClO2] = 0.193 M and [HClO2] = 0.203 M?

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