Exam 17: Additional Aspects of Acidbase Equilibria
Exam 1: Matter: Its Properties and Measurement136 Questions
Exam 2: Atoms and the Atomic Theory119 Questions
Exam 3: Chemical Compounds152 Questions
Exam 4: Chemical Reactions170 Questions
Exam 5: Introduction to Reactions in Aqueous Solutions124 Questions
Exam 6: Gases113 Questions
Exam 7: Thermochemistry125 Questions
Exam 8: Electrons in Atoms123 Questions
Exam 9: The Periodic Table and Some Atomic Properties93 Questions
Exam 10: Chemical Bonding I: Basic Concepts107 Questions
Exam 11: Chemical Bonding Ii: Valence Bond and Molecular Orbital Theories104 Questions
Exam 12: Intermolecular Forces: Liquids and Solids121 Questions
Exam 13: Spontaneous Change: Entropy and Gibbs Energy123 Questions
Exam 14: Solutions and Their Physical Properties132 Questions
Exam 15: Principles of Chemical Equilibrium118 Questions
Exam 16: Acids and Bases137 Questions
Exam 17: Additional Aspects of Acidbase Equilibria130 Questions
Exam 18: Solubility and Complex-Ion Equilibria104 Questions
Exam 19: Electrochemistry127 Questions
Exam 20: Chemical Kinetics124 Questions
Exam 21: Chemistry of the Main-Group Elements I: Groups 1,2,13,and 14116 Questions
Exam 22: Chemistry of the Main-Group Elements Ii: Groups 18,17,16,15,and Hydrogen100 Questions
Exam 23: The Transition Elements108 Questions
Exam 24: Complex Ions and Coordination Compounds104 Questions
Exam 25: Nuclear Chemistry116 Questions
Exam 26: Structures of Organic Compounds99 Questions
Exam 27: Reactions of Organic Compounds94 Questions
Exam 28: Chemistry of the Living State104 Questions
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For the following titration,determine whether the solution at the equivalence point is acidic,basic or neutral and why:
HCl(aq)is titrated with NH3(aq)
(Multiple Choice)
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What is the pH of a buffer that is 0.88 M HCN(aq)and 0.53 M NaCN(aq)? The Ka of HCN is 6.2 × 10-10.
(Multiple Choice)
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Formic acid (HCOOH,Ka = 1.8 × 10-4)is the principal component in the venom of stinging ants.What is the molarity of a formic acid solution if 25.00 mL of the aqueous formic acid solution requires 29.80 mL of 0.0567 mol L-1 NaOH(aq)to reach the equivalence point?
(Multiple Choice)
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For the following titration,determine whether the solution at the equivalence point is acidic,basic or neutral and why:
KOH(aq)is titrated with HI(aq)
(Multiple Choice)
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How will addition of sodium acetate to an aqueous acetic acid solution affect the pH?
(Multiple Choice)
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Determine the pH of the following aqueous solution.Initial concentrations are given.
[HF] = 1.296 M,[NaF] = 1.045 M,Ka for HF is 6.6 × 10-4
(Multiple Choice)
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The Henderson-Hasselbach equation,used to calculate the pH of simple conjugate-pair buffer systems,would be expressed for an ammonia/ammonium chloride buffer,for which Kb(NH3)is 1.8 × 10-5,as:
(Multiple Choice)
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Calculate the percent ionization of nitrous acid in an aqueous solution that is 0.266 mol L-1 in nitrous acid
And 0.112 mol L-1 in potassium nitrite (
).The acid dissociation constant of nitrous acid is 



(Multiple Choice)
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Acid-base indicators have two forms: an acid of one color and a base of another color.
(True/False)
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An aqueous solution is prepared by dissolving 0.23 mol of nitrous acid and 0.27 mol of sodium nitrite in water sufficient to yield 1.00 L of solution.The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly.The pH does not decrease drastically because the HCl reacts with the ________ present in the buffer solution.The
Of nitrous acid is 1.36 × 10-3.

(Multiple Choice)
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The buffer capacity of a solution may be defined as the number of moles of H+ that will change the pH of 1.00 L of the buffer by 1.00 pH units.What is the buffer capacity of an aqueous solution which is 0.10 M in acetic acid (Ka = 1.8 × 10-5)and 0.30 M in sodium acetate,in units of mol (H+)per liter?
(Multiple Choice)
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Twenty-five milliliters of 0.10 M HCl(aq)is titrated with 0.10 M NaOH(aq).What is the pH before any NaOH(aq)is added?
(Multiple Choice)
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Which of the following can act as buffer solutions?
I.0.1 M HC2H3O2/0.1 M NaC2H3O2
II.0.1 M NH3/0.1 M NH4Cl
III.0.1 M HNO3/0.1 M NaNO3
IV.0.1 M H2SO3/0.1 M NaHSO3
V.0.1 M KHSO4/ 0.1 M H2SO4
(Multiple Choice)
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What will the pH at the neutralization point of 0.00812 M Ba(OH)2(aq)be when titrated with HCl(aq)?
(Multiple Choice)
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A buffer was prepared by adding 2.4 g of ammonium nitrate to 100.0 mL of 0.30 M aqueous ammonia (Kb = 1.8 × 10-5).To this solution was then added 10.0 mL of 0.30 M aqueous sodium hydroxide,which caused a pH change of ________.
(Multiple Choice)
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An aqueous solution containing equimolar amounts of a weak acid with Ka = 10-5 and its sodium salt has:
(Multiple Choice)
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25 mL of 0.10 M aqueous acetic acid is titrated with 0.10 M NaOH(aq).What is the pH after 30 mL of NaOH have been added? Ka for acetic acid = 1.8 × 10-5.
(Multiple Choice)
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If 30.0 mmol HCl(g)is added to 1.00 L of a buffer that is 0.340 M NH3(aq)and 0.290 M NH4Cl(aq),what are the final concentrations of NH3(aq)and NH4Cl(aq),respectively? Assume no volume change.
(Multiple Choice)
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What is the hydronium ion concentration in an aqueous solution prepared by mixing 50.00 mL of 0.10 mol L-1 HCN with 50.00 mL of 0.010 mol L-1 NaCN? Assume that the volumes of the solutions are additive and that Ka = 

(Multiple Choice)
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For HClO2,Ka = 1.2 × 10-2.What is the pH of an aqueous solution in which [NaClO2] = 0.193 M and [HClO2] = 0.203 M?
(Multiple Choice)
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