Exam 2: Acids and Bases; Functional Groups

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In the structure below, the sigma bond of the carbonyl is formed from the overlap of a(n) ________ atomic orbital of carbon and a(n) ________ atomic orbital of oxygen. In the structure below, the sigma bond of the carbonyl is formed from the overlap of a(n) ________ atomic orbital of carbon and a(n) ________ atomic orbital of oxygen.

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What is the approximate value of the CCC bond angle in CH3CH2CH2OH?

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What is the hybridization of the nitrogen atom in the molecule below? What is the hybridization of the nitrogen atom in the molecule below?

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What two hybrid atomic orbitals overlap to form the C-C σ bond in allene, H2C=C=CH2?

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Shown below is one of the sex pheremones from the butterfly family. How many sp3 hybridized carbon atoms are present? Shown below is one of the sex pheremones from the butterfly family. How many sp<sup>3 </sup>hybridized carbon atoms are present?

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Which of the molecules below has the higher boiling point? Briefly explain your choice. (CH3)3N or CH3CH2CH2NH2

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Which atomic orbital combination would result in a molecular sigma bond?

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Which compound is more soluble in water? Briefly explain your choice. CH3OCH3 or CH3CH2OH

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The electron density at any point is proportional to the ________ of the electron wave at that point.

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Which of the molecules below can hydrogen bond to another of the same compound?

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Triethylamine [(CH3CH2)3N] is a molecule in which the nitrogen atom is ________ hybridized and the CNC bond angle is ________.

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Which of the following does not contain a carbonyl group?

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Are the two compounds shown below best described as cis-trans isomers, constitutional isomers, or not isomeric? Are the two compounds shown below best described as cis-trans isomers, constitutional isomers, or not isomeric?

(Short Answer)
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Does 1,1-dichloroethene (Cl2C Does 1,1-dichloroethene (Cl<sub>2</sub>C    CH<sub>2</sub>) have a net molecular dipole moment? If it does, draw the molecule and indicate the direction of this molecular dipole moment. CH2) have a net molecular dipole moment? If it does, draw the molecule and indicate the direction of this molecular dipole moment.

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Use the following structure for the two questions below. Saquinavir Structure Use the following structure for the two questions below. Saquinavir Structure   -Which of the following functional groups is not present in the HIV protease inhibitor drug called Saquinavir? -Which of the following functional groups is not present in the HIV protease inhibitor drug called Saquinavir?

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Which is more soluble in water? Which is more soluble in water?

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How many σ bonds does the compound shown contain? How many σ bonds does the compound shown contain?

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Dopamine is shown below. What functional group, or structural element is not present in this compound? Dopamine is shown below. What functional group, or structural element is not present in this compound?

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The molecule shown below contains ________ sigma bonds and ________ pi bonds. The molecule shown below contains ________ sigma bonds and ________ pi bonds.

(Short Answer)
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What kind of molecular orbital (σ, σ*, π, or π*) results when the two atomic orbitals shown below interact in the manner indicated? What kind of molecular orbital (σ, σ<sup>*</sup>, π, or π<sup>*</sup>) results when the two atomic orbitals shown below interact in the manner indicated?

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