Exam 13: Spontaneous Change: Entropy and Gibbs Energy

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The value of ΔfG at 100.0 °C for the formation of phosphorus trichloride from its constituent elements, The value of Δ<sub>f</sub>G at 100.0 °C for the formation of phosphorus trichloride from its constituent elements,   (g)+   (g)→   (g) Is ________ kJ mol<sup>-1</sup>.At 25.0 °C for this reaction,Δ<sub>f</sub>H° is -720.5 kJ mol<sup>-1</sup> and   Is  . (g)+ The value of Δ<sub>f</sub>G at 100.0 °C for the formation of phosphorus trichloride from its constituent elements,   (g)+   (g)→   (g) Is ________ kJ mol<sup>-1</sup>.At 25.0 °C for this reaction,Δ<sub>f</sub>H° is -720.5 kJ mol<sup>-1</sup> and   Is  . (g)→ The value of Δ<sub>f</sub>G at 100.0 °C for the formation of phosphorus trichloride from its constituent elements,   (g)+   (g)→   (g) Is ________ kJ mol<sup>-1</sup>.At 25.0 °C for this reaction,Δ<sub>f</sub>H° is -720.5 kJ mol<sup>-1</sup> and   Is  . (g) Is ________ kJ mol-1.At 25.0 °C for this reaction,ΔfH° is -720.5 kJ mol-1 and The value of Δ<sub>f</sub>G at 100.0 °C for the formation of phosphorus trichloride from its constituent elements,   (g)+   (g)→   (g) Is ________ kJ mol<sup>-1</sup>.At 25.0 °C for this reaction,Δ<sub>f</sub>H° is -720.5 kJ mol<sup>-1</sup> and   Is  . Is The value of Δ<sub>f</sub>G at 100.0 °C for the formation of phosphorus trichloride from its constituent elements,   (g)+   (g)→   (g) Is ________ kJ mol<sup>-1</sup>.At 25.0 °C for this reaction,Δ<sub>f</sub>H° is -720.5 kJ mol<sup>-1</sup> and   Is  ..

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Calculate the entropy change for methanol at its normal boiling point of 64.5 °C.ΔrH° = 38.0 kJ/mol.

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Consider the following reaction: Consider the following reaction:   What is K<sub>eq</sub> for this reaction at 25 °C? What is Keq for this reaction at 25 °C?

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For the reaction SO2(g)+ Cl2(g)→ SO2Cl2(g)Keq = 0.377 at 25 °C,what is ΔrG° for the reaction?

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Consider the reaction: AB(g)? A(g)+ B(g) Consider the reaction: AB(g)? A(g)+ B(g)   What is K<sub>eq</sub> for this reaction at 425 K? What is Keq for this reaction at 425 K?

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What is ΔrG° at 25 °C? CO2(g)→ CO2(aq)ΔrH° = -19.4 kJ ΔrS° = 92.3 J/K

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Consider the following reaction: Consider the following reaction:   What is Δ<sub>r</sub>S° for the above reaction in J/mol K? What is ΔrS° for the above reaction in J/mol K?

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For the reaction PCl5(g)→ PCl3(g)+ Cl2(g)at 298 K,Keq = 1.87 × 10-7rS° = 181.92 J/mol K.Compute ΔrH° for this reaction.

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The change in Gibbs energy for a reaction:

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A zero ΔG means the system is at equilibrium.

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If a process is spontaneous,the reverse process is non spontaneous.

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For a given reaction,ΔrH = -26.6 kJ mol-1 and ΔrS = -77.0 J K-1 mol-1.The reaction is spontaneous ________.Assume that ΔrH and ΔrS do not vary with temperature.

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What is ΔrG°? What is Δ<sub>r</sub>G°?

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Which material has the largest entropy?

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What is ΔrG° at 25 °C? N2O4(g)→ 2 NO2(g)ΔrH° = 58.03 kJ ΔrS° = 176.7 J/K

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For CdO(s)+ SO3(g)→ CdSO4(s),ΔrH° = -279.4 kJ/mol,and ΔrS° = -118.4 J/mol ∙ K.What is the temperature at which Keq is 1.0 × 104?

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For CO(g)+ H2(g)→ H2CO(g),ΔrH° = -5.36 kJ/mol,and ΔrS° = -109.8 J/mol K.What is ΔrG° in kJ/mol at 300 K?

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In a sealed container,the rate of dissolving is equal to the rate of crystallization.Therefore we would expect:

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Which of the following has the largest molar entropy?

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Order the following by increasing entropy. CO(g),COCl2(g),CO2(g),CaO(s)

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