Exam 13: Spontaneous Change: Entropy and Gibbs Energy
Exam 1: Matter: Its Properties and Measurement136 Questions
Exam 2: Atoms and the Atomic Theory119 Questions
Exam 3: Chemical Compounds152 Questions
Exam 4: Chemical Reactions170 Questions
Exam 5: Introduction to Reactions in Aqueous Solutions124 Questions
Exam 6: Gases113 Questions
Exam 7: Thermochemistry125 Questions
Exam 8: Electrons in Atoms123 Questions
Exam 9: The Periodic Table and Some Atomic Properties93 Questions
Exam 10: Chemical Bonding I: Basic Concepts107 Questions
Exam 11: Chemical Bonding Ii: Valence Bond and Molecular Orbital Theories104 Questions
Exam 12: Intermolecular Forces: Liquids and Solids121 Questions
Exam 13: Spontaneous Change: Entropy and Gibbs Energy123 Questions
Exam 14: Solutions and Their Physical Properties132 Questions
Exam 15: Principles of Chemical Equilibrium118 Questions
Exam 16: Acids and Bases137 Questions
Exam 17: Additional Aspects of Acidbase Equilibria130 Questions
Exam 18: Solubility and Complex-Ion Equilibria104 Questions
Exam 19: Electrochemistry127 Questions
Exam 20: Chemical Kinetics124 Questions
Exam 21: Chemistry of the Main-Group Elements I: Groups 1,2,13,and 14116 Questions
Exam 22: Chemistry of the Main-Group Elements Ii: Groups 18,17,16,15,and Hydrogen100 Questions
Exam 23: The Transition Elements108 Questions
Exam 24: Complex Ions and Coordination Compounds104 Questions
Exam 25: Nuclear Chemistry116 Questions
Exam 26: Structures of Organic Compounds99 Questions
Exam 27: Reactions of Organic Compounds94 Questions
Exam 28: Chemistry of the Living State104 Questions
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The value of ΔfG at 100.0 °C for the formation of phosphorus trichloride from its constituent elements,
(g)+
(g)→
(g)
Is ________ kJ mol-1.At 25.0 °C for this reaction,ΔfH° is -720.5 kJ mol-1 and
Is
.





(Multiple Choice)
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Calculate the entropy change for methanol at its normal boiling point of 64.5 °C.ΔrH° = 38.0 kJ/mol.
(Multiple Choice)
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Consider the following reaction:
What is Keq for this reaction at 25 °C?

(Multiple Choice)
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For the reaction SO2(g)+ Cl2(g)→ SO2Cl2(g)Keq = 0.377 at 25 °C,what is ΔrG° for the reaction?
(Multiple Choice)
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Consider the reaction: AB(g)? A(g)+ B(g)
What is Keq for this reaction at 425 K?

(Multiple Choice)
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What is ΔrG° at 25 °C?
CO2(g)→ CO2(aq)ΔrH° = -19.4 kJ ΔrS° = 92.3 J/K
(Multiple Choice)
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Consider the following reaction:
What is ΔrS° for the above reaction in J/mol K?

(Multiple Choice)
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For the reaction PCl5(g)→ PCl3(g)+ Cl2(g)at 298 K,Keq = 1.87 × 10-7,ΔrS° = 181.92 J/mol K.Compute ΔrH° for this reaction.
(Multiple Choice)
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If a process is spontaneous,the reverse process is non spontaneous.
(True/False)
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For a given reaction,ΔrH = -26.6 kJ mol-1 and ΔrS = -77.0 J K-1 mol-1.The reaction is spontaneous ________.Assume that ΔrH and ΔrS do not vary with temperature.
(Multiple Choice)
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What is ΔrG° at 25 °C?
N2O4(g)→ 2 NO2(g)ΔrH° = 58.03 kJ ΔrS° = 176.7 J/K
(Multiple Choice)
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For CdO(s)+ SO3(g)→ CdSO4(s),ΔrH° = -279.4 kJ/mol,and ΔrS° = -118.4 J/mol ∙ K.What is the temperature at which Keq is 1.0 × 104?
(Multiple Choice)
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For CO(g)+ H2(g)→ H2CO(g),ΔrH° = -5.36 kJ/mol,and ΔrS° = -109.8 J/mol K.What is ΔrG° in kJ/mol at 300 K?
(Multiple Choice)
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In a sealed container,the rate of dissolving is equal to the rate of crystallization.Therefore we would expect:
(Multiple Choice)
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Order the following by increasing entropy.
CO(g),COCl2(g),CO2(g),CaO(s)
(Multiple Choice)
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