Exam 1: Chemical Bonding and Chemical Structure

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Give the formal charge on the phosphorus atom in this structure. (Phosphorus is in group 5A directly under nitrogen in the periodic table.) Give the formal charge on the phosphorus atom in this structure. (Phosphorus is in group 5A directly under nitrogen in the periodic table.)

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Assume that the structure of BF3 (boron trifluoride, or trifluoroborane) is correctly predicted by the VSEPR rules. 1. What is the predicted structure? (Show all unpaired valence electrons.) 2. The B-F bond is exceptionally strong. This suggests that it has some double-bond character. Draw resonance structures for BF3 that show that the three B-F bonds share some double-bond character. Be sure to show formal charges and all unshared electrons. 3. What is the polarity of the B-F bond? (In which direction is the bond dipole?) How do you know?

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Consider this compound: Consider this compound:    1. Of the labeled bonds, the longest bond is ________________. 2. The most polar bond is ________________. 3. The bonding geometry at the silicon atoms is ________________. 4. The hybridization of the silicon atoms is ________________. 1. Of the labeled bonds, the longest bond is ________________. 2. The most polar bond is ________________. 3. The bonding geometry at the silicon atoms is ________________. 4. The hybridization of the silicon atoms is ________________.

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What is the C-N-O bond angle in the cyanate ion? What is the C-N-O bond angle in the cyanate ion?

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Which atomic orbital has two nodes?

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Consider this structure: H3CaCbCcCH=dCHeCH2fCH3\mathrm { H } _ { 3 } \mathrm { C } \stackrel { a } { - } \mathrm { C } \stackrel { b } { \equiv } \mathrm { C } \stackrel { c } { - } \mathrm { CH } \stackrel { d } { = } \mathrm { CH } \stackrel { e } { - } \mathrm { CH } _ { 2 } \stackrel { f } { - } \mathrm { CH } _ { 3 } Which bond represents an sp-sp2 carbon-carbon bond?

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